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51.
The determination of pesticide residues in food matrices is a formidable challenge mainly because of the small quantities of analytes and large amounts of interfering substances which can be co-extracted with analytes and, in most cases, adversely affect the results of an analysis. However, safety concerns require that pesticides of the wide range of chemical properties (including acidic, basic and neutral) should be monitored. Because of the wide variety of food matrices, the sample must initially be cleaned up before final analysis. That is why the analytical chemist is faced with the need to devise new methodologies for determining such residues to be determined in a single analytical run. To accomplish the goal, QuEChERS methodology has been developed. It is a streamlined and effective extraction and cleanup approach for the analysis of diverse analyte residues in food matrices. So far, there have been achieved promising results by liquid or gas chromatography analysis, including pesticides, but also acrylamide, pharmaceuticals and veterinary drugs. 相似文献
52.
A process of plasma‐initiated grafting of acrylic acid on commercial porous polypropylene membrane was studied. The influence of parameters of the plasma (power, gas pressure, time plasma‐sample distance, sample arrangement) and grafting (solvent composition, monomer concentration, time, inhibitor presence) on the degree of grafting, amount of homopolymer produced and surface electrical resistance was determined. A degree of grafting up to 18 mmol/g was obtained, which resulted in sample resistance as low as 30 mΩ cm2. The molecular weight of AAc homopolymer that can be assumed as equal to the MW of grafted chains, ranged from 25,000 to 50,000,000 da. SEM and water permeability measurements show that grafting causes filling of the pores, which, however, does not stop K+ ions from penetrating the membrane. The performance of nickel‐cadmium cells with acrylic acid grafted membranes as separator is also presented. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
53.
A convenient synthetic procedure for preparing nickel carboxylated phthalocyanine is reported. Upon further hydroxylation, such metal phthalocyanine moieties are incorporated into several melamine-based polyester high-solids systems and the structure—property correlations are examined. Molecular level spectroscopic FTIR analysis and mechanical testing are correlated in an effort to establish structure—property relations in these coatings. It is found that the presence of metal phthalocyanine macrocycle as a cross-linking agent enhances such properties as adhesion, hardness, and impact resistance. © 1993 John Wiley & Sons, Inc. 相似文献
54.
Kazimierz MroczekSylwester Kalisz Marek PronobisJózef So?tys 《Fuel Processing Technology》2011,92(5):845-855
The paper presents results of investigations on using halloysite as an additive in biomass-fired boilers. It has been shown that in the case of a few different agricultural biomasses the halloysite addition increased the ash sintering temperature to the values noted for coals. This is an effect of bonding sodium and potassium in the form of chlorides and other compounds. In practical terms the halloysite additive may reduce slagging and fouling of boiler heating surfaces as well as deteriorate the agglomeration processes in fluidized beds. Moreover, addition of halloysite reduces the amount of KCl and NaCl present in ash (and therefore in ash deposits) thus decreasing the rate of high temperature corrosion. 相似文献
55.
Lucjan Chmielarz Piotr Kuśtrowski Marek Drozdek Małgorzata Rutkowska Roman Dziembaj Marek Michalik Pegie Cool Etienne F. Vansant 《Journal of Porous Materials》2011,18(4):483-491
SBA-15 mesoporous silicas modified with rhodium were studied as catalysts for the N2O decomposition reaction. Rhodium was deposited on SBA-15 by the Molecular Designed Dispersion (MDD) method using Rh(acac)3 as a precursor of active phase. The same method was used for the deposition of Cu, Fe, Al and Ti. The SBA-15 support modified
with metals were characterized with respect to metal loading (EPMA), structure (XRD), texture (BET), morphology (SEM), Rh
dispersion (oxygen chemisorption), surface acidity (pyridine adsorption) and chemical nature of introduced copper and iron
species (UV–vis-DRS). The rhodium-containing SBA-15 samples were found to be active catalysts for the N2O decomposition reaction. Deposition of Al on the Rh-loaded catalyst increased its activity. An opposite effect was observed
for the samples modified with Cu and Fe. 相似文献
56.
57.
Marek Berezowski 《化学工程与技术》2020,43(12):2523-2529
The first and second Lyapunov methods were adapted to analyze the stability of a tubular chemical reactor with recycle. The criterion of local stability in the form of inequalities was derived using Lyapunov's first method. It is an explicit algebraic form, despite the fact that the mathematical model of the reactor is a partial differential problem with a boundary condition. As part of the second Lyapunov method, a mathematical criterion for non-local stability was derived in the form of an increase of Lyapunov's function. Both criteria are presented on graphs. 相似文献
58.
Effect of the structure of polymer inclusion membranes on zn(II) transport from chloride aqueous solutions 下载免费PDF全文
This article presents application of polymer inclusion membranes (PIM) containing polymer matrices: cellulose triacetate (CTA) or poly(vinyl) chloride (PVC), o‐nitrophenyloctyl ether (NPOE) as a plasticizer and phosphonium ionic liquids, i.e., trihexyltetradecylphosphonium chloride (Cyphos IL 101), bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL 104) and tributyltetradecylphosphonium chloride (Cyphos IL 167), as carriers for Zn(II) transport from chloride medium. Cyphos IL167 application as an ion carrier in PIMs is reported for the first time. The membrane composition is found to affect Zn(II) transport significantly. SEM and AFM images show the differences in the surface morphology of PVC and CTA based membranes. Better transport abilities of CTA membranes (Zn(II) recovery factors exceed 80%) compared with those of PVC, indicate that the structural differences between the two polymers play a crucial role for the membrane permeability. The best initial flux and permeability coefficient are obtained for the membranes with Cyphos IL 101 and Cyphos IL 104 as carriers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42319. 相似文献
59.
60.
The hydrosilylation of cyclohexanone and acetone with triethysilane and diphenysilane catalyzed by polymer‐supported Rh(I) complex has been investigated. Two terpolymers of styrene, divinylbenzene, and 1‐vinylimidazole (S/DVB/VI) or N‐vinylpyrrolidinone (S/DVB/NVP) were used as the catalysts supports. Physical characterization of these materials has involved the measurements of the structural parameters in the dry and swollen states by DSC, the nitrogen BET adsorption method and inverse steric exclusion chromatography ISEC. From these results it can be concluded that the original polymer structure has been changed during the complex attachment giving rise to materials of higher porosity. X‐ray photoelectron spectroscopy XPS, IR, and AAS spectroscopy were used to characterization of heterogeneous complexes before and after use. The effect of the morphology of the support on the catalytic properties of the polymer‐supported Rh(I) species was tested in the hydrosilylation of ketones and correlated with the reaction mechanism. It was demonstrated that the high selectivity of homogeneous rhodium complex toward the silyl ethers can be partially reversed to the dehydrogenative silylation products by a proper choice of polymer support with favorable microporous structure. Recycling tests demonstrated high stability of the supported catalysts during prolonged use. The constant selectivity of the supported catalysts demonstrated during recycling experiments showed that they could be useful for practical application. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献