Long-term storage stability of selected potato starch – Non-starchy hydrocolloid binary gels

All 3, 4 and 5% potato starch gels containing either κ-carrageenan, guar gum or xanthan gum were prepared and their stability in terms of rheological and textural properties was checked on 30 day storage. It was shown that rheology of these binary potato starch – non-starchy hydrocolloid mixtures could be controlled by anionic character of the admixed hydrocolloid. Depending on the hydrocolloid added, gels made of the tuber starch can either retain their pattern typical for tuber starches or turn into that typical for gels of cereal starches. Hydrocolloids added plasticity to the binary gels but it was lost to a significant extent within the first day of storage. Resulting gels with dominating elastic character are rheologically and texturally fairly stable for subsequent 30 days of storage. Generally, hydrocolloids stabilized potato starch gel on long-time storage to the extent dependent on the gel concentration.     

Methods for determining pesticides and polychlorinated biphenyls in food samples--problems and challenges

Determination of residual amounts of pesticides and polychlorinated biphenyls (PCBs) in food samples requires the use of specific techniques regarding sample preparation as well as instrumental analysis which should be characterized by a very low detection limit. A problem associated with the use of pesticides and PCBs is the need for controlling their residues in the environment, particularly in food, as these chemicals show a propensity to accumulate. The analysis of food samples for the presence of pesticides and PCBs brings on many difficulties because of the specificity of sample preparation consisting of multistep purification procedures of samples that contain trace amounts of an analyte. Concentration determinations of pollutants that easily dissolve in complex matrices, particularly in the presence of a large apportionment of interfering substances, pose a big challenge. Therefore, the basic step in food analysis for the presence of pesticides and PCBs is sample preparation which mainly consists of analyte enrichment and the removal of interfering substances. But all steps of the analytical procedure that include sample collection and preparation, extraction of analytes from matrix, extract purification, and final determination, are very significant; their precision and correct application have a decisive effect on the final result.     

Bio‐composites for structural applications: Poly‐l‐lactide reinforced with long sisal fiber bundles

Fully bio‐based and biodegradable composites were compression molded from unidirectionally aligned sisal fiber bundles and a polylactide polymer matrix (PLLA). Caustic soda treatment was employed to modify the strength of sisal fibers and to improve fiber to matrix adhesion. Mechanical properties of PLLA/sisal fiber composites improved with caustic soda treatment: the mean flexural strength and modulus increased from 279 MPa and 19.4 GPa respectively to 286 MPa and 22 GPa at a fiber volume fraction of V_f = 0.6. The glass transition temperature decreased with increasing fiber content in composites reinforced with untreated sisal fibers due to interfacial friction. The damping at the caustic soda‐treated fibers‐PLLA interface was reduced due to the presence of transcrystalline morphology at the fiber to matrix interface. It was demonstrated that high strength, high modulus sisal‐PLLA composites can be produced with effective stress transfer at well‐bonded fiber to matrix interfaces. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40999.     

Properties of Light MMCs Modified with Cordierite Synthesized from Fly Ash

This paper presents novel opportunities for management of fly ash by synthesizing the material into cordierite ceramics and using it as a reinforcing phase for light metal alloys. Metal matrix composites (based on magnesium alloy and aluminum alloy) were produced by squeeze casting. The magnesium matrix composites with a suitably selected reinforcing phase content (2 wt.%) exhibited much better strength properties than the unmodified alloy (AM60). It was also demonstrated that the wettability (or the lack thereof) in the metal-ceramic system is critical to successful production of the composites based on the AK7 alloy with cordierite. Light alloy matrix composites reinforced with cordierite ceramics particles are innovative materials that combine high strength with low weight, which may be a key factor of merit for numerous applications of the composite in various branches of industries.     

Integrated material flow and radioactivity distribution methodology within the calculation tool for evaluation of parameters for decommissioning of nuclear installations

Decommissioning of nuclear facilities becomes an important issue in all areas of nuclear technology, mainly in their energetic applications. Decommissioning process has to be planned in the safe, ecological and economic manner. It determines the requirements on appropriate evaluation of needed technologies, media, amount of solid materials released into the environment, radioactivity of effluents, amount of radioactive waste for disposal, number and exposure of personnel and finally the financial demands. A detailed evaluation of these parameters may be done by analytical calculation approach. This approach models a real process of decommissioning with its individual basic activities. The methodology of integrated material flow and radioactivity distribution within this calculation evaluation tool is applied and implemented to describe the real decommissioning activities and their mutual relations to obtain more accurate outputs.     

Long-Term Changes in Ovarian Follicles of Gilts Exposed Neonatally to Methoxychlor: Effects on Oocyte-Derived Factors,Anti-Müllerian Hormone,Follicle-Stimulating Hormone,and Cognate Receptors

In this paper, we investigated the effects of neonatal exposure to methoxychlor (MXC), a synthetic organochlorine used as an insecticide with estrogenic, antiestrogenic, and antiandrogenic activities on ovarian follicles of adult pigs. Piglets were injected with MXC (20 μg/kg body weight) or corn oil (controls) from postnatal Day 1 to Day 10 (n = 5 per group). Then, mRNA expression, protein abundance and immunolocalization of growth and differentiation factor 9 (GDF9), bone morphogenetic protein 15 (BMP15), anti-Müllerian hormone (AMH) and cognate receptors (ACVR1, BMPR1A, BMPR1B, TGFBR1, BMPR2, and AMHR2), as well as FSH receptor (FSHR) were examined in preantral and small antral ovarian follicles of sexually mature gilts. The plasma AMH and FSH levels were also assessed. In preantral follicles, neonatal exposure to MXC increased GDF9, BMPR1B, TGFBR1, and BMPR2 mRNAs, while the levels of AMH and BMP15 mRNAs decreased. In addition, MXC also decreased BMP15 and BMPR1B protein abundance. Regarding small antral follicles, neonatal exposure to MXC upregulated mRNAs for BMPR1B, BMPR2, and AMHR2 and downregulated mRNAs for AMH, BMPR1A, and FSHR. MXC decreased the protein abundance of AMH, and all examined receptors in small antral follicles. GDF9 and BMP15 were immunolocalized in oocytes and granulosa cells of preantral follicles of control and treated ovaries. All analyzed receptors were detected in the oocytes and granulosa cells of preantral follicles, and in the granulosa and theca cells of small antral follicles. The exception, however, was FSHR, which was detected only in the granulosa cells of small antral follicles. In addition, MXC decreased the plasma AMH and FSH concentrations. In conclusion, the present study may indicate long-term effects of neonatal MXC exposure on GDF9, BMP15, AMH, and FSH signaling in ovaries of adult pigs. However, the MXC effects varied at different stages of follicular development. It seems that neonatal MXC exposure may result in accelerated initial recruitment of ovarian follicles and impaired cyclic recruitment of antral follicles.     

Energy recovery and economy aspects of steam-explosion pretreatment in waste phytomass management

Steam-explosion pretreatment allows lowering of the natural resistance of plant material to subsequent biodegrading processes, such as anaerobic fermentation. This is achieved by a complex of cavitation forces that disintegrate rigid lignocellulose structures and liberate labile organic matter during a quick release of phytomass from a steam-pressurized reactor back to the atmospheric pressure. Hydrolyzing reactants or catalysts may increase the effect; however, the management of chemicals raises financial and environmental concerns. The current state of knowledge was reviewed to identify promising designs and reengineering that would enable subsequent transfer into the commercial scale in order to reverse the current trend of phytomass waste management – landfilling. In an effort to achieve profitability, it has been concluded that further development should focus on a deeper interconnection of the apparatus with associated technology units, reuse of waste heat from the subsequent biogas combustion, widening the range of processing parameters, reuse of nutrients, and utilization of the ballast organic matter.     

Technological aspects of sunflower biomass and brown coal co-firing

The technological problems occurring in the co-firing of biomass and brown coal (lignite) prompted this research project. During the fuel preparation, accidental self-ignition and explosions were several times reported by power plants operators. The aim of this study was to evaluate brown coal, sunflower husks and sunflower husk pellets as fuels for co-firing in energetic boilers. Sunflower husk had a lower ash content and calorific value than the pellets. The range of the combustion temperatures of the biomass (200–300 °C) was narrower than that of brown coal (200–800 °C). The formation of highly alkaline ash from the biomass resulted in the formation in boiler of agglomerates of ash. The elemental composition, thermogravimetric and biological analyses suggested that the pellets contained synthetic additives difficult to identify. The biological method was proposed for evaluating biomass additives. The use of additional agents in the pelletizing process may influence on the combustion parameters. Mixing biomass with brown coal may occasionally result in self-ignition in the logistic chain. Plastic additives and biological activity may contribute to self-ignition.     

The Effect of Implanted Al and/or Y on the Scale Formation on Low-Al Fe20Cr2Al Alloy

The very early stages of the oxidation of an Fe20Cr2Al alloy, unmodified and ion-implanted by aluminium, yttrium and a combination of both elements, Al and Y, were studied at 1100 °C in oxygen using two-stage-oxidation exposures with ¹⁸O₂ as a tracer and subsequent characterisation of the scales using SIMS analyses of distribution of oxygen isotopes and oxide-related negative ion clusters, SEM observations of the surface morphology and photoluminescence spectroscopy analysis of the phase composition. The scales formed in all cases, except for the Al-implanted alloy, exhibited layered structures, with the outer part comprising Fe- and Cr-rich oxide, and the inner part being Al₂O₃, which grew due to a mixed outward–inward mechanism . The alumina sub-layers contained the transient oxides and α-Al₂O₃. Implanted Al significantly affected the mechanism of the scale growth, providing that the scale consisted essentially of α-Al₂O₃, and grew via a mixed inward-outward mechanism typical for scales on alumina formers.     

Application of Lyapunov's Methods for Analyzing the Stability of a Tubular Chemical Reactor with Recycle

The first and second Lyapunov methods were adapted to analyze the stability of a tubular chemical reactor with recycle. The criterion of local stability in the form of inequalities was derived using Lyapunov's first method. It is an explicit algebraic form, despite the fact that the mathematical model of the reactor is a partial differential problem with a boundary condition. As part of the second Lyapunov method, a mathematical criterion for non-local stability was derived in the form of an increase of Lyapunov's function. Both criteria are presented on graphs.