Synthesis,Characterization, and Application of Mesoporous Silica Functionalized with Alkyl‐Hydroperoxides

A variety of alkyl hydroperoxides such as tert‐butyl‐, tert‐octyl‐, 1‐cyclopentyl‐, 1‐cyclohexyl‐, 3,4‐disubstituted‐1‐cyclohexyl‐, n‐propyl, and n‐undecyl‐hydroperoxides have been functionalized onto ordered mesoporous silica, SBA‐15, from the corresponding covalently anchored synthons. All the tert‐hydroperoxides are prepared by autoxidation using molecular O₂ and an initiator, whereas other hydroperoxides are obtained by reaction with H₂O₂. For autoxidation, the use of a combination of an azoinitiator (AIBN) and N‐hydroxyphthalimide increased the hydroperoxide yield compared with using the azoinitiator alone. Synthons containing two or more tert‐ and sec‐hydrogens lead to higher peroxide yield compared to synthons with a single reactive site. Oxidation of Si–OH (silanol groups) with acidic H₂O₂ at low temperature produces Si–OOH. Reusability of these alkyl hydroperoxides is carried out by oxidation of alcohols obtained from the corresponding alkyl hydroperoxides using H₂O₂. Both the covalently anchored synthons and the resulting hydroperoxides are thoroughly characterized by powder X‐ray diffraction, ¹³C cross‐polarized magic angle spinning NMR, TG/DTA, Fourier transform IR spectroscopy, sorption, and surface area measurements. The quantification of the amount of alkyl hydroperoxide was carried out by iodometric titration using a thio solution. The hydroperoxides exhibit high activity for the epoxidation of styrene to styrene oxide and exhibit reasonably high efficiency for oxygen transfer.     

Novel phthalocyanine/polyol high-solids coatings: Structure—property relationships

A convenient synthetic procedure for preparing nickel carboxylated phthalocyanine is reported. Upon further hydroxylation, such metal phthalocyanine moieties are incorporated into several melamine-based polyester high-solids systems and the structure—property correlations are examined. Molecular level spectroscopic FTIR analysis and mechanical testing are correlated in an effort to establish structure—property relations in these coatings. It is found that the presence of metal phthalocyanine macrocycle as a cross-linking agent enhances such properties as adhesion, hardness, and impact resistance. © 1993 John Wiley & Sons, Inc.     

Gas recycling as a means of controlling the operation of cyclones

A method is proposed for increasing the dedusting efficiency of cyclones. The method, which is based on the introduction of the gas undergoing purification into a recycle loop, is of considerable practical importance as it enables the process to be controlled so as to maintain a constant efficiency of dust removal.     

Sealed NiCd cells: The temperature behaviour of electrodes in excess of electrolyte

The temperature behaviour of both cadmium and nickel oxide electrodes of the sintered type (as used in sealed NiCd cells) has been investigated     

Numerical limit analysis of perforated plates

Full limit analysis is preseted of a thin plate under plane stress, perforated with circular holes arranged in a regular penetration pattern. The material is assumed to be elastic–perfectly plastic and to obey the Huber–Mises yield condition together with its associated flow law. The finite element tangential stiffness method is employed. Triangular constant-strain elements are used, the load being generated by means of constant edge displacements at the periphery of a suitably selected subregion. Load-displacement diagrams are obtained for various edge displacement programs and then an interaction curve is constructed for the perforated plate considered. Each computational step is associated with a certain plastic zone which develops until the limit state configuration is reached. The plate is provided with equilateral triangular configuration of holes with arbitrary cutout coefficients. The interaction curves are plotted against the Huber–Mises yield condition for the plate without openings.     

Dielectric properties of /Agl-xKx/NbO3 solid solutions

The possibility of the occurrence of critical point in /Ag_l-xK_x/NbO₃ solid solutions is discussed.     

Physiologically based modeling of 3-D vascular networks and CT scan angiography

In this paper, a model-based approach to medical image analysis is presented. It is aimed at understanding the influence of the physiological (related to tissue) and physical (related to image modality) processes underlying the image content. This methodology is exemplified by modeling first, the liver and its vascular network, and second, the standard computed tomography (CT) scan acquisition. After a brief survey on vascular modeling literature, a new method, aimed at the generation of growing three-dimensional vascular structures perfusing the tissue, is described. A solution is proposed in order to avoid intersections among vessels belonging to arterial and/or venous trees, which are physiologically connected. Then it is shown how the propagation of contrast material leads to simulate time-dependent sequences of enhanced liver CT slices.