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51.
In this paper, we show that large connected slip patches (hydrophobic patches) are a necessity to induce macroscopic slip effects of water flow in microchannels. For this purpose, the 2D fluid flow between a planar stationary surface with alternating stick and slip patches and a parallel planar surface moving with a constant relative velocity has been studied by computer simulations based on Navier–Stokes equations. A slip patch is defined as the slipping length in a 2D system or a slip area of the surface in a 3D system. The simulations reveal that the ratio (size of each slip patch)/(distance between the two parallel interfaces) has profound effect on the viscous stress on the moving surface when this ratio is around and above one. However, when the ratio is much below one, the effect of the slip patches are minor, even if the area fraction of slip patches are higher than 50 %. Obviously, the stick patches adjacent to the slip patches act as effective barriers, preventing the fluid velocity to increase near the surface with alternating stick and slip patches. The obtained results are scalable and applicable on all length scales, with an exception for narrow channels in the subnano regime, i.e. <1 nm where specific effects as the atomistic composition and the nanostructure of the wall as well as the interactions between the wall and the water molecules have an effect. 相似文献
52.
Pontus Johnson Maria Eugenia Iacob Margus Välja Marten van Sinderen Christer Magnusson Tobias Ladhe 《Information Systems and E-Business Management》2014,12(4):567-593
In the design phase of business collaboration, it is desirable to be able to predict the profitability of the business-to-be. Therefore, techniques to assess qualities such as costs, revenues, risks, and profitability have been previously proposed. However, they do not allow the modeler to properly manage uncertainty with respect to the design of the considered business collaboration. In many real collaboration projects today, uncertainty regarding the business’ present or future characteristics is so significant that ignoring it becomes problematic. In this paper, we propose an approach based on the predictive, probabilistic architecture modeling framework (P2AMF), capable of advanced and probabilistically sound reasoning about profitability risks. The P2AMF-based approach for profitability risk prediction is also based on the e3-value modeling language and on the object constraint language. The paper introduces the prediction and modeling approach, and a supporting software tool. The use of the approach is illustrated by means of a case study originated from the Stockholm Royal Seaport smart city project. 相似文献
53.
Isidoro Izquierdo Cubero Maria T. Plaza López-Espinosa Rafael Acuña Castillo 《Journal of chemical ecology》1991,17(8):1529-1541
The synthesis of the title compound13 has been carried out through the preparation of its precursor, (3R,4R,5S,6R)-3,4,5-trihydroxy-1,7-dioxaspiro[5.5]undecane (6), obtained fromd-fructose using Wittig's methodology, reduction, and spiroketalation. Compound6 was transformed into13 by a Barton deoxygenation at C-5 followed by a Corey dideoxygenation at C-3,4 of the appropriately protected derivatives.Enantiospecific synthesis of spiroacetals. Part II. For Part I, see Izquierdo and Plaza (1990). 相似文献
54.
The effect of Mg-doping and Li overstoichiometry on the structural stability of LiCoO2 powders has been investigated with emphasis to voltammetric properties. Microparticle cyclic voltammetry (CV) conducted in caustic NaOH to best simulate a non-aqueous electrolyte shows a marked improvement of the structure stability of doped LiCoO2. In contrast to the unsubstituted LiCoO2 sample which shows voltammetric peaks associated to the well-known two-phase domain and monoclinic distortion reactions, in Li1.08Mg0.06CoO2, LiMg0.06CoO2 and Li1.08CoO2 samples these peaks are strongly suppressed providing direct evidence for the existence of a stable solid solution with negligible phase transitions in the reversible intercalation region (3.8-4.2 V vs. Li) as well as in the overcharged region. The effect is higher with Mg-doping, irrespective of the Li overstoichiometry. However, the concomitant presence of Mg and Li excess in the structure is important for obtaining small particle sizes. Since Mg-doping induces a quasi metallic behavior in the samples, whereas the Li excess may provide an higher initial capacity, it is suggested that the Li1.08Mg0.06CoO2 composition may be of interest as positive cathode for advanced Li-ion batteries. 相似文献
55.
The effect of oral administration, for 24 or 48 hr, of different octadeca fatty acids containing a 9,12-dienoic structure
on the fatty acid composition and Δ9 desaturation activity of liver microsomes of rat fed a fat-free diet was studied. The
ethyl esters of linoelaidic and γ-linolenic acids, the methyl ester of linoleic acid and free columbinic acid were administered
to rats maintained on a fat-free diet. The supplementation of the fat-free diet with linoelaidate produced no relevant changes
in the fatty acid composition pattern of liver microsomes and did not modify the percentage of conversion of palmitic to palmitoleic
acid. The addition of linoleate or γ-linolenate to the fat-free diet returned liver microsome Δ9 desaturation activity toward
the control and partially restored the liver microsome fatty acid spectrum found in the fat-free diet. Columbinic acid (5-trans-9-cis,12-cis-18∶3), which cannot be transformed into arachidonic acid, also decreased the Δ9 desaturation activity enhanced by the fat-free
diet and evoked changes in the microsomal fatty acid composition similar to those produced by the ω6 fatty acids. These results
suggest that the modulation of Δ9 desaturase activity evoked by dietary administration of unsaturated acids of ω6 series would
depend on thecis double bond configuration of these acids. 相似文献
56.
Prior to fertilization, mammalian sperm must undergo the acrosome reaction, which involves modifications of the plasma and
outer acrosomal membranes followed by vesiculation and release of the membranes. The membrane fraction that was released from
caudal boar sperm undergoing an in vitro acrosome-like reaction was isolated and characterized with respect to density, marker
enzymes and lipid composition. This membrane had a lower phospholipid/protein ratio (mg/mg) than the sperm plasma membrane,
whereas both membranes had similar molar sterol/phospholipid ratios. The major phospholipid was sphingomyelin, followed by
phosphatidylethanolamine and phosphatidylcholine, whereas in the plasma membrane the order was reversed; the two major phosphoglycerides
contained alkylacyl and alkenylacyl species in addition to the diacyl species. The released membrane also contained lower
amounts of cholesterol sulfate and unsaturated fatty acids than the plasma membranes. These results, in combination with our
studies on the changes of the sperm membranes during maturation and acrosome reaction, will allow a better understanding of
the mechanism of the sperm acrosome reaction. 相似文献
57.
de Almeida Jhony Luiz Comunello Eros Sobieranski Antonio da Rocha Fernandes Anita Maria Cardoso Gabriel Schade 《Pattern Analysis & Applications》2021,24(3):907-914
Pattern Analysis and Applications - Digital holography is an imaging process able to recreate three-dimensional representations of objects from recording pattern interference among distinct waves.... 相似文献
58.
59.
Ilaria Bartolini Vincenzo Moscato Ruggero G. Pensa Antonio Penta Antonio Picariello Carlo Sansone Maria Luisa Sapino 《Multimedia Tools and Applications》2016,75(7):3813-3842
The valorization and promotion of worldwide Cultural Heritage by the adoption of Information and Communication Technologies represent nowadays some of the most important research issues with a large variety of potential applications. This challenge is particularly perceived in the Italian scenario, where the artistic patrimony is one of the most diverse and rich of the world, able to attract millions of visitors every year to monuments, archaeological sites and museums. In this paper, we present a general recommendation framework able to uniformly manage heterogeneous multimedia data coming from several web repositories and to provide context-aware recommendation techniques supporting intelligent multimedia services for the users—i.e. dynamic visiting paths for a given environment. Specific applications of our system within the cultural heritage domain are proposed by means of real case studies in the mobile environment related both to an outdoor and indoor scenario, together with some results on user’s satisfaction and system accuracy. 相似文献
60.
Maxim Shishmarev Christopher Mears Guido Tack Maria Garcia de la Banda 《Constraints》2016,21(1):77-94
Understanding how the search space is explored for a given constraint problem – and how it changes for different models, solvers or search strategies – is crucial for efficient solving. Yet programmers often have to rely on the crude aggregate measures of the search that are provided by solvers, or on visualisation tools that can show the search tree, but do not offer sophisticated ways to navigate and analyse it, particularly for large trees. We present an architecture for profiling a constraint programming search that is based on a lightweight instrumentation of the solver. The architecture combines a visualisation of the search tree with various tools for convenient navigation and analysis of the search. These include identifying repeated subtrees, high-level abstraction and navigation of the tree, and the comparison of two search trees. The resulting system is akin to a traditional program profiler, which helps the user to focus on the parts of the execution where an improvement to their program would have the greatest effect. 相似文献