Transition metal cations extraction by ester and ketone derivatives of chromogenic azocalix[4]arenes

The molecule of azocalix[n]arene is a macrocyclic used effectively in the complexation of the heavy metal pollutants (like silver and mercury). In this work, our main aim is to prepare new chromogenic azocalix[n]arene molecules to elaborate an extractant with high extractant selectivity for metal ions able to detect this type of pollutant. The solvent extraction properties of four acetyls, four methyl ketones and four benzoyls derivatives from azocalix[4]arenes which were prepared by linking 4-ethyl, 4-n-butyl, 4-acetamid anilin and 2-aminothiazol to calix[4]arene through a diazo-coupling reaction, the alkaline earth (Sr2+) and the transition (Ag+, Hg2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Cr3+) metal cations have been determined by extraction studies with metal picrates. Both ketones are better extractants than esters, and show a strong preference for Ag+, while Cu2+ and Cr3+ are the most extracted cation with the esters. Both acetyl and benzoyl esters are good carriers for Ag+ and Hg2+.     

Compact Modules for Wireless Communication Systems in the E-Band (71–76 GHz)

The millimeter-wave spectrum above 70 GHz provides a cost-effective solution to increase the wireless communications data rates by increasing the carrier wave frequencies. We report on the development of two key components of a wireless transmission system, a high-speed photodiode (HS-PD) and a Schottky Barrier Diode (SBD). Both components operate uncooled, a key issue in the development of compact modules. On the transmitter side, an improved design of the HS-PD allows it to deliver an output RF power exceeding 0 dBm (1 mW). On the receiver side, we present the design process and achieved results on the development of a compact direct envelope detection receiver based on a quasi-optical SDB module. Different resonant (meander dipole) and broadband (Log-Spiral and Log-Periodic) planar antenna solutions are designed, matching the antenna and Schottky diode impedances at high frequency. Impedance matching at baseband is also provided by means of an impedance transition to a 50 Ohm output. From this comparison, we demonstrate the excellent performance of the broadband antennas over the entire E-band by setting up a short-range wireless link transmitting a 1 Gbps data signal.     

DFC++ Processing Framework Concept

Development of modern Software Defined Radio (SDR) based communication systems can be accelerated significantly by the use of processing frameworks. The evolution of SDR and the involved departure from digital representations of classical radio architecture towards more abstract software systems raises new requirements of increased flexibility and versatility. The proposed Data Flow Control for C++ (DFC++) processing framework concept addresses those requirements by employing modern programming techniques and flow control mechanisms to allow for variable data rates, dynamic paths, and flexible component designs. Another important trend is the integration of various embedded platforms in the software radio domain. The rapidly increasing performance and efficiency of embedded processors enables the deployment of SDR systems in more space and power constrained environments. Therefore covering a heterogeneous hardware selection becomes increasingly important for processing frameworks. By relying exclusively on C++ and minimizing external dependencies, DFC++ is specifically aiming for excellent portability and adaptability to support a wide range of current and future software radio projects while maintaining high performance and ease of use. This paper introduces the key aspects of the DFC++ concept and implementation with focus on the reference pointer based data transport mechanisms responsible for the propagation of user data between different processing components.     

New current-mode current-controlled universal filter with single input and three outputs

In this study, a new current-mode current-controlled universal filter with single input and three outputs is presented. The proposed circuit uses single-output current controlled conveyors (CCCIIs) and can simultaneously realize lowpass, bandpass and highpass filter functions all at high impedance outputs. Realization of notch and allpass responses does not require additional active elements. The circuit enjoys independent current-control of the parameters ω₀ and ω₀/Q without disturbing the gains of the lowpass, bandpass and highpass filters. Both its active and passive sensitivities are low.     

A new concept of planar self-reconfigurable modular robot for conveying microparts

Modularity and self-healing are two interesting properties that could help to design more flexible conveyors of micro-objects. In the Smart Blocks project, we propose to design a 2D modular and self-reconfigurable robot composed of centimeter-scale sliding blocks that embed their own actuators and control electronics. This article presents a proof-of-concept of the linkage and of the traveling system as well as an algorithm able to reconfigure a set of blocks from a spatial configuration to another one. Prototype blocks have been realized using electro-permanent magnets which show a good motion speed while saving power consumption during the linkage. Our reconfiguration algorithm is implemented in a simulator software showing in real-time the reconfiguration of the robot.     

Vectorcardiographic loop alignment and the measurement of morphologic beat-to-beat variability in noisy signals

The measurement of subtle morphologic beat-to-beat variability in the electrocardiogram (ECG)/vectorcardiogram (VCG) is complicated by the presence of noise which is caused by, e.g., respiration and muscular activity. A method was recently presented which reduces the influence of such noise by performing spatial and temporal alignment of VCG loops. The alignment is performed in terms of scaling, rotation and time synchronization of the loops. Using an ECG simulation model based on propagation of action potentials in cardiac tissue, the ability of the method to separate morphologic variability of physiological origin from respiratory activity was studied. Morphologic variability was created by introducing a random variation in action potential propagation between different compartments. The results indicate that the separation of these two activities can be done accurately at low to moderate noise levels (less than 10 microV). At high noise levels, the estimation of the rotation angles was found to break down in an abrupt manner. It was also shown that the breakdown noise level is strongly dependent on loop morphology; a planar loop corresponds to a lower breakdown noise level than does a nonplanar loop.     

Study of the growth and structural properties of InMnAs dots grown on high-index surfaces by MOVPE

The growth of InMnAs quantum dots by low pressure MOVPE technique on patterned (1 0 0) GaAs substrates was studied. The patterning in the form of ridges with sidewalls having (2 1 1) and (3 1 1) facets was prepared by wet chemical etching via a GaAs/AlAs sacrificial etching mask structure. AFM studies showed that the dots formation and distribution were very similar for both types of facets under study. InMnAs dot density on the (3 1 1) plane is about 5–7 times lower in comparison to that on the (1 0 0) planar substrate. The dots on sidewalls are larger in comparison to average dots formatted on planar GaAs (1 0 0) substrate. The lateral dimensions of these dots are in the interval 100–180 nm. In addition, dot distribution along the sidewall (from top to bottom) is not uniform. A higher dot concentration was observed close to the intersection of (3 1 1) facets with concave bottom part of the valleys between ridges. Finally, no dots were grown on the (1 0 0) plane created by self-faceting on the top of the triangular ridges. This is probably a consequence of the high quality of the (1 0 0) facet formed by lateral overgrowth.     

Revised stratigraphy of the Tertiary deposits of Istanbul and their engineering properties

For over 50 years, the Upper Oligocene–Upper Miocene sedimentary sequence in Istanbul has been considered to be formed of two distinct sequences separated by an unconformity. However, recent field observations and an analysis of numerous borehole data indicate the Gürp?nar, Çukurçe?me and Güngören Formations are in fact a single sequence of alternating clay–sand/sandstone beds/lenses, here named the Avc?lar Formation. The Bak?rköy Formation, which is typically composed of carbonate rocks, conformably overlies the Avc?lar Formation. The paper provides the geotechnical parameters of the units within the Avc?lar Formation which it is hoped will facilitate selecting suitable geotechnical and engineering geological parameters to represent the deposits and minimize errors in the interpretation/evaluation of in-situ conditions.