Subsecond thermophysics research at the Boris Kidrich Institute Vincha

In the early eighties, at the Boris Kidrich Institute Vincha, a method for measuring specific heat and electrical resistivity of electrical conductors in the millisecond resolution range was developed for measurements from room temperature to 1900 K. Over a period of nearly 10 years, the method was applied to different materials, including pure metals, ferrous, and nickel/ chromium alloys, and to the characterization of candidate materials for thermophysical property reference standards. This paper describes the method and reviews the results obtained in specific heat and electrical resistivity studies of ferromagnetic and other materials. The paper also demonstrates capabilities of the method for describing phase transitions or anomalies in pure metals (Fe, Co, Ni) or alloys (Nichrome, austenitic stainless steel).Paper presented at the Second Workshop on Subsecond Thermophysics, September 20–21, 1990, Torino, Italy.     

Application of substituted N-arylpyrroles in the corrosion protection of aluminium in hydrochloric acid

The inhibiting action of N-arylpyrroles on aluminium in 0.17 mol dm^–3 hydrochloric acid solution, in the temperature range 20–60 °C, was studied using potentiodynamic and electrochemical impedence spectroscopy techniques. The inhibiting efficiency of both investigated compounds 1-(2-fluorophenyl)-2,5-dimethylpyrrole (compound A) and 1-(2-fluorophenyl)-2,5-dimethylpyrrole-3-carbaldehyde (compound B) slightly increases with increasing temperature of the corrosive solution. Inhibitor adsorption on the elecrode surface decreases the apparent activation energy of the hydrogen evolution reaction. Compound A follows the Temkin adsorption isotherm, while its carbaldehyde derivative follows the Langmuir isotherm. The results of the apparent energy of activation and the standard free energy of adsorption point to stronger chemisorption of the compound A. However, due to additional condensation of molecules with carbaldehyde groups on the electrode surface, the carbaldehyde derivative exhibits even better inhibiting efficiency than compound A. The kinetic corrosion parameters, analysed in terms of the impedance data, show a satisfactory agreement with those obtained by the potentiodynamic method.     

On some interval methods for algebraic,exponential and trigonometric polynomials

New inclusion methods for the simultaneous determination of the zeros of algebraic, exponential and trigonometric polynomials are presented. These methods are realized in real interval arithmetic and do not use any derivatives. Using Weierstrass' correction some modified methods with the increased convergence rate are constructed. Convergence analysis and numerical example are included.     

Altered ligand dissociation rates in thyrotropin-releasing hormone receptors mutated in glutamine 105 of transmembrane helix III

Glutamine 105 in the third transmembrane helix of the thyrotropin-releasing hormone receptor (TRH-R) occupies a position equivalent to a conserved negatively charged residue in receptors for biogenic amines where it acts as counterion interacting with the cationic amine moiety of the ligand. Maximum levels of response to TRH in oocytes expressing wild-type TRH-Rs were indistinguishable from those of oocytes expressing receptors mutated to Glu, Asn, or Asp in position 105. However, the EC50 values for activation of oocyte responses increased more than 500 times in oocytes expressing mutant Glu105 receptors, in which the amido group of Gln105 has been removed by site-directed mutagenesis. Charge effects do not seem to be involved in the huge effect of mutating Gln105 to Glu, since mutation of Gln105 to Asp induces only a 15-fold increase in EC50. Furthermore, no change in EC50 is observed after mutation of Asn110 to Asp. The affinity shift (identified by changes in EC50 values for systems of comparable efficacy) in Glu105 mutant receptors was partially recovered in oocytes expressing Asn105 mutant receptors. These results and those obtained after substitution of Lys, Leu, Tyr, and Ser for Gln105 suggest that the presence and the correct position of the Gln hydrogen bond-donor amido group are important for normal functionality of the receptor. In wild type or Asp105 mutant receptors showing the same maximal responses, decreases in affinity with TRH and methyl-histidyl-TRH correlated with increased dissociation rates of hormone from the receptor. Rapid dilution experiments following subsecond stimulation indicate that the TRH-R is converted rapidly from a form showing fast dissociation kinetics to a form from which the hormone dissociates slowly. Mutation of residue 105 impairs the receptor shift between these two forms. This effect was demonstrated in a direct way by comparing [3H]methyl-histidyl-TRH dissociation rates in COS-7 cells transfected with either wild type or Asp105 mutant TRH-Rs. Thus, residues located in transmembrane helix III positions equivalent to those of the counterions for biogenic amines, regulate hormone-receptor interactions in the TRH receptor (and perhaps other receptors). Furthermore, the nature of the amino acid in these positions may also play a role, directly or indirectly, in conformational changes leading to receptor activation, and hence to signal transduction.     

大爆炸宇宙学模型一些主要观测事实及其讨论

本文用近代物理学有关理论讨论了大爆炸宇宙学模型的一些主要观测事实，如哈勃定律，宇宙微波背景辐射、氦的丰度等问题，尝试对大爆炸宇宙学模型双观测事实到理论作一个初步地描述。     

An approach to emulating separable graphs

A technique foremulating multicomputer interconnection networks that are based onseparable graphs (graphs having bounded degree and sublinear multicolor recursive bisectors) is presented. Efficient emulations among interconnection networks are necessary for porting programs designed for one network to another.Emulations are formalized asgraph embeddings, where the nodes (processors) of theguest graph (emulated network) are assigned to nodes of thehost graph (emulator), while the edges (communication links) of the guest are routed via paths in the host. The communication slowdown in an emulation depens on thedilation (length of the longest routing path) and thecongestion (number of paths that contend for a host edge) of the embedding. Theexpansion of the embedding (the ratio of the sizes of the host to guest) determines the inefficiency of processor utilization. Cell trees are introduced as interconnection networks whose special communication properties enable them to serve as intermediate devices in these emulations. Nodes in cell trees are organized into equinumerous parts calledcells; the cells are labeled by nodes of a complete binary tree. Communication in cell trees is restricted to two specific and distinct primitives:cell communication is confined within cells, whiletransfer communication occurs between adjacent cells. Rather than solved directly, the emulation problem for the original guest-host pair is decomposed into two independent parts: emulating the guest by the cell tree, and emulating the cell tree by the host.In emulations of separable graphs by cell trees, the node assignment that ensures small dilation is derived from the separator-based decomposition of guest graphs. The congestion-free edge routing is achieved by coordinatingglobal andlocal phases, which are based on two characteristic cell-tree communication primitives.The technique is instantiated by emulating cell trees on specific host graphs. Withshuffle-like hypercube-derivative networks as hosts new constant-expansion emulations are obtained that have both dilation and congestion logarithmic in the size of the multicolor bisector of guest graphs. These emulations are the first such to have optimal (up to constants)congestion; they provide the firstoptimal algorithm for emulating arbitrary separable graphs on shuffle-like networks. The application of the technique tohypercubes as hosts also produces optimal emulations that differ from those previously known by having smaller expansion constants.This research was supported in part by NSF Grants CCR-88-12567 and CCR-90-13184, and by the University of Massachusetts Graduate School Fellowship for the academic year 1991-92. A preliminary version of this paper was presented at the 3rd ACM Symposium on Parallel Algorithms and Architectures, July 22–24, 1991, in Hilton Head, South Carolina, USA.     

Scientometric analysis of the research activities of chemists from the “Rugjer Bošković” Institute (Yugoslavia), 1976–1985

The research activity of chemists from the Rugjer Bokovi Institute (RBI, Zagreb, Yugoslavia) was analyzed for the period 1976–1985, covering 2018 research years of scientific work, and 1149 SCI registered papers (0.57 publications per research year). At the average, one paper was published by 3.05 scientists. The papers were published in 235 different journals, most frequently is the nationalCroatica Chemica Acta (171 papers). The publications were divided into two groups: for the periods 1976–1980 and 1981–1985, and for each paper citations were collected in the respective time period. An average publication had 2.58 citations. Chemical papers from the second period had 2.73 citations per paper, which is 85% of the expected value, and this was considerably more than for Yugoslav papers (66%) in general. The papers were classified according to the subfields used in theJournal Citation Reports, and the results compared with the data published bySchubert, Glänzel andBraun. The distribution of citations was also analyzed.     

Frequency dependence of the spin-fluctuation spectrum in Pd: Calculations within the finite bandwidth model

The frequency dependence of the electron-paramagnon spectrumP() in Pd is calculated within the finite bandwidth model. It is found that for an almost full band, the magnitude, the range, and the position of the peak frequency inP() are dramatically reduced compared to their values in the usual paramagnon theory. Also, we find that the frequency dependence of the spin-fluctuation contribution to the electron self-energy is strongly affected by a close proximity of the Fermi level to the top of the band. We speculate that an unusually large value of the Coulomb pseudopotential is probably partially responsible for the absence of superconductivity in Pd.     

An XPS and reduction study of PrCoO3

The perovskite-type oxide PrCoO₃ has been studied by means of X-ray photoelectron spectroscopy (XPS), reduction in H₂ and X-ray diffraction. Two types of oxygen were detected: lattice oxygen (binding energy = 528.4 eV) and adsorbed oxygen (binding energy = 530.9 eV). The increase in relative intensity of the peak corresponding to the latter species after reduction of PrCo0₃ to 3e^– per molecule is assigned to the formation of hydroxyl groups. Temperature-programmed reduction (TPR) results showed two reduction steps: to 1 e^– per molecule (Co^3.1 Co²⁺) at 475 to 635 K, and to 3e^– per molecule (Co²¹ Co⁰) at 725 to 815 K. Reduction in the first and second steps occurs according to the contracting sphere model and the nucleation mechanism, respectively. Reduction of Co³⁺ to Co²⁺ causes minimal structural changes in the perovskite. Reduction to 3e^– per molecule yielded Pr₂O₃ and metallic cobalt. After this reduction and reoxidation at 973 K, the perovskite structure was regained. By XPS and TPR it was shown that PrCo0₃ is more easily reducible than LaCo0₃. It is concluded that the cation in the A position of the structure plays a significant role in the bulk and surface properties of LnCo0₃ (Ln, lanthanide elements) oxides.