Studies on Effective Utilization of SOFC Exhaust Heat Using Thermoelectric Power Generation Technology

Solid oxide fuel cells (SOFCs) are being researched around the world. In Japan, a compact SOFC system with rated alternative current (AC) power of 700 W has become available on the market, since the base load electricity demand for a standard home is said to be less than 700 W AC. To improve the generating efficiency of SOFC systems in the 700-W class, we focused on thermoelectric generation (TEG) technology, since there are a lot of temperature gradients in the system. Analysis based on simulations indicated the possibility of introducing thermoelectric generation at the air preheater, steam generator, and exhaust outlet. Among these options, incorporating a TEG heat exchanger comprising multiple CoSb₃/SiGe-based TEG modules into the air preheater had potential to produce additional output of 37.5 W and an improvement in generating efficiency from 46% to 48.5%. Furthermore, by introducing thermoelectric generation at the other two locations, an increase in maximum output of more than 50 W and generating efficiency of 50% can be anticipated.     

Dispersion slope equaliser using bend-induced positive dispersionslope in coiled pure-silica fibre

The dispersion slope of a dispersion-shifted fibre has been successfully equalised by using a bend-induced positive dispersion slope in a singlemode fibre. We realised the bent fibre dispersion slope equaliser by using a 1.3 μm zero-dispersion pure silica core fibre (PSM). This equaliser provides a dispersion slope of -12.54 ps/nm² /km in the 1.5 μm region     

Constant-ratio-coupled multi-grain digital synchronizer with flexible input-output delay selection for versatility in low-power applications

The constant-ratio-coupled multi-grain digital synchronizer (CRC-MGsynchronizer) is proposed as a means for making high-speed connections with very low power consumption, both among multiple chips such as processors, controllers, and storage devices, and among on-chip modules. The synchronizer not only provides a wide range of operating frequencies, but is fast locking and only occupies a small area on chip. Therefore, it contributes to large reductions in power consumption and costs. It is suitable for use in various low-power systems (e.g., battery-hungry mobile appliances and low-cost consumer electronic products). Three major techniques were applied to the design: 1)a multi-grain structure for the delay elements, which greatly reduces the number of gates while facilitating locking in a very small number of clock cycles;2) constant-ratio-coupled (CRC) delay lines (measurement versus generation)for flexible selection of the input-output delay; and 3) a new lock stage decision circuit (LSDC) scheme, conferring excellent testability. Moreover,the architecture is all-digital, and thus it has high process portability. By applying these techniques to a DDR memory interface circuit for a mobile application processor fabricated in 130-nm technology, we were able to reduce power consumption by 42% and chip area by 65% compared with a conventional implementation. Furthermore, the novel design spans a frequency range covering 12 times the minimum frequency.     

A Water‐Soluble Mechanochromic Luminescent Pyrene Derivative Exhibiting Recovery of the Initial Photoluminescence Color in a High‐Humidity Environment

Switching of the luminescence properties of molecular materials in response to mechanical stimulation is of fundamental interest and also has a range of potential applications. Herein, a water‐soluble mechanochromic luminescent pyrene derivative having two hydrophilic dendrons is reported. This pyrene derivative is the first example of a mechanochromic luminescent organic compound that responds to relative humidity. Mechanical stimulation (grinding) of this pyrene derivative in the solid state results in a change of the photoluminescence from yellow to green. Subsequent exposure to water vapor induces recovery of the initial yellow photoluminescence. The color change is reversible through at least ten cycles. It is also demonstrated that this compound can be applied as a mechano‐sensing material in frictional wear testing for grease, owing to its immiscibility in non‐polar solvents and its non‐crystalline behavior. Transmission electron microscope and atomic force microscope observations of samples prepared from dilute aqueous solutions of the pyrene derivative on suitable substrates, together with dynamic light scattering measurements for the compound in aqueous solution, indicate that this amphiphilic dumbbell‐shaped molecule forms micelles in water.     

Theatre in the Sky: a ubiquitous broadband multimedia‐on‐demand service over a novel constellation composed of quasi‐geostationary satellites

To meet an ever‐growing demand for wideband multimedia services and electronic connectivity across the world, development of ubiquitous broadband multimedia systems is gaining a tremendous interest at both commercial and academic levels. Satellite networks will play an indispensable role in the deployment of such systems. A significant number of satellite communication constellations have been thus proposed using Geostationary (GEO), Medium Earth Orbit (MEO), or Low Earth Orbit (LEO) satellites. These constellations, however, either require a potential number of satellites or are unable to provide data transmission with high elevation angles. This paper proposes a new satellite constellation composed of Quasi‐GeoStationary Orbit (Quasi‐GSO) satellites. The main advantage of the constellation is in its ability to provide global coverage with a significantly small number of satellites while, at the same time, maintaining high elevation angles. Based on a combination of this Quasi‐GSO satellites constellation and terrestrial networks, the paper proposes also an architecture for building a global, large‐scale, and efficient Video‐on‐Demand (VoD) system. The entire architecture is referred to as a ‘Theatre in the Sky’. Copyright © 2006 John Wiley & Sons, Ltd.     

Thermal performance of a packed bed reactor for a high‐temperature chemical heat pump

The thermal performance of a chemical heat pump that uses the reaction system of calcium oxide/lead oxide/carbon dioxide, which is developed for utilization of high‐temperature heat above 800°C, is studied experimentally. The thermal performance of a packed‐bed reactor of a calcium oxide/carbon dioxide reaction system, which stores and transforms a high‐temperature heat source in the heat pump operation, is examined under various heat pump operation conditions. The energy analysis based on the experiment shows that it is possible to utilize high‐temperature heat with this heat pump. This heat pump can store heat above 850°C and then transform it into a heat above 900°C under an approximate atmospheric pressure. An applied system that combines the heat pump and a high‐temperature process is proposed for high‐efficiency heat utilization. The scale of the heat pump in the combined system is estimated from the experimental results. Copyright © 2001 John Wiley & Sons, Ltd.     

Low-loss laser diode module using a molded aspheric glass lens

The fabrication and characteristics of a 1.3-μm laser diode (LD) module for single-mode fiber using a molded aspheric glass lens is discussed. An average coupling loss of 2.2 dB with a standard deviation of less than 0.5 dB after thermal heat cycling tests was achieved. The average assembly loss was 0.24 dB. The LD module demonstrated stability during thermal and heat cycling tests from -10 to 60°C     

Contribution of high p34cdc2 kinase activity to premature chromosome condensation of injected somatic cell nuclei in rat oocytes

The present study was undertaken to clarify the relationship between the p34cdc2 kinase activity of in vitro-aged or enucleated rat oocytes and the premature chromosome condensation (PCC) of microinjected cumulus cell nuclei. Wistar rat oocytes were placed in vitro up to 120 min after the animal was killed. The p34cdc2 kinase activity of the oocytes decreased in a time-dependent manner. The incidence of PCC was higher when nuclear injection into intact oocytes was completed in 15-45 min rather than 46-120 min. When rat oocytes were enucleated for subsequent nuclear injection, the p34cdc2 kinase activity transiently increased soon after enucleation but drastically decreased after 30 min. Removal of the cytoplasm instead of the meta-phase-plate did not affect the p34cdc2 kinase activity even after 60 min. PCC occurred in intact and cytoplasm-removed oocytes but not in enucleated oocytes. In contrast, oocytes from BDF1 mice exhibited a p34cdc2 kinase level twice that of rat oocytes and supported PCC despite enucleation. The p34cdc2 kinase level of intact rat oocytes was reduced to the equivalent level of aged (120 min) or enucleated (+60 min) oocytes by a 45 min treatment with roscovitine, an inhibitor of p34cdc2 kinase. None of the roscovitine-treated oocytes supported PCC while half of the control oocytes did. When rat oocytes were treated with MG132, a proteasome inhibitor, delayed inactivation of the p34cdc2 kinase was observed in the MG132-treated oocytes. A significantly higher proportion of the MG132-treated oocytes supported PCC when compared with the control oocytes. Moreover, a higher proportion of MG132-treated and enucleated oocytes carried two pseudo-pronuclei after cumulus cell injection and developed to the two-cell stage when compared with the enucleated oocytes at the telophase-II stage. These results suggest that the decreased level of p34cdc2 kinase activity in aged or enucleated rat oocytes is responsible for their inability to support PCC of microinjected donor cell nuclei and that inhibition of p34cdc2 kinase inactivation by chemicals such as MG132 is in part effective for rat oocytes to promote PCC and further development.     

Proposals for wastewater treatment by applying flocculating activity of cross-linked poly-gamma-glutamic acid

Cross-linked poly-gamma-glutamic acid (C-L gamma-PGA) markedly purified polluted water collected from rivers and ponds by flocculation and precipitation. This effect of C-L gamma-PGA occasionally required pretreatment with polyaluminum chloride (PAC). Components of polluted water in rivers or ponds are generally thought to be clay minerals, microorganisms and chemical compounds. In this study, the flocculating activities of C-L gamma-PGA against suspensions of bentonite, diatomaceous earth, Escherichia coli and Mycrocystis aeruginosa, and against solutions of crystal violet and bisphenol A were investigated. The mode of action of C-L gamma-PGA is thought to be based on electrostatic interaction between flocculants, C-L gamma-PGA and PAC, and the surface of polluted water components, which may lead to neutralization of the zeta-potential of those components.