Structural correlations in nickel(II)–thiodiacetato complexes: molecular and crystal structures and properties of [Ni(tda)(H2O)3]

Triaqua(thiodiacetato)nickel(II) has been synthesized and studied by X-ray crystallography, thermal, spectral and magnetic methods. The compound crystallizes in the triclinic system, space group , in contrast to the related compound [Ni(tda)(H₂O)₃] · H₂O (orthorhombic) reported long time ago. As in other four Ni–tda derivatives, the metal atom exhibits an octahedral coordination and tda ligand adopts a fac-tridentate chelating role. The studied compound is closely related to [Zn(tda)(H₂O)₃]. In addition, a structural comparison of the binary and ternary Ni–tda derivatives reveals that auxiliary N-donor ligands bind the metal atom using the trans-positions towards the Ni–O(carboxylato) bonds, but not in trans to the Ni–S(thioether) bond.     

Should dialysate calcium be varied in proportion to the amount of ultrafiltration in peritoneal dialysis dwells? Directions from a computer simulation

Patellar metastases are very rare. There have been approximately 20 cases reported in the literature. We have also noted two other reports of patellar metastasis from lung carcinoma as the first manifestation of lung cancer in our literature review. We present a case of patellar metastasis as the first manifestation of lung epidermoid carcinoma in a patient who was a smoker for 33 years.     

Are aldehydes in heat-sterilized peritoneal dialysis fluids toxic in vitro?

OBJECTIVE: Chemical analysis of several brands of peritoneal dialysis fluids (PD fluids) has revealed the presence of 2-furaldehyde, 5-HMF (5-hydroxymethylfuraldehyde), acetaldehyde, formaldehyde, glyoxal, and methylglyoxal. The aim of this study was to investigate if the in vitro side effects caused by glucose degradation products, mainly formed during heat sterilization, are due to any of these recently identified aldehydes. DESIGN: Cell growth media or sterile filtered PD fluids were spiked with different concentrations of thealdehydes. MEASUREMENTS: In vitro side effects were determined as the inhibition of cell growth of cultured mouse fibroblasts or stimulated superoxide radical release from human peritoneal cells. RESULTS: Our results demonstrate that the occurrences of 2-furaldehyde, 5-HMF, acetaldehyde, formaldehyde, glyoxal, or methylglyoxal in heat-sterilized PD fluids are probably not the direct cause of in vitro side effects. In order to induce the same magnitude of cell growth inhibition as the heat-sterilized PD fluids, the concentrations of 2-furaldehyde, glyoxal, and 5-HMF had to be 50 to 350 times higher than those quantified in the PD fluids. The concentrations of acetaldehyde, formaldehyde, and methylglyoxal observed in the heat-sterilized PD fluids were closer to the cytotoxic concentrations although still 3 to 7 times lower. CONCLUSION: Since none of these aldehydes caused in vitro toxicity at the tested concentrations, the toxicity found in PD fluids is likely to be due to another glucose degradation product, not yet identified. However, it is possible that these aldehydes may still have adverse effects for patients on peritoneal dialysis.     

A QoE handover architecture for converged heterogeneous wireless networks

The convergence of real-time multimedia applications, the increasing coverage of heterogeneous wireless networks and the ever-growing popularity of mobile devices are leading to an era of mobile human-centric multimedia services. In this scenario, heterogeneous communications will co-exist and ensure that the end-user is always best connected. The rigorous networking demands of wireless multimedia systems, beyond quality-oriented control strategies, are necessary to guarantee the best user experience over time. Therefore, the Quality of Experience (QoE) support, especially for 2D or 3D videos in multi-operator environments, remains a significant challenge and is crucial for the success of multimedia systems. This paper proposes a QoE Handover Architecture for Converged Heterogeneous Wireless Networks, called QoEHand. QoEHand extends the Media Independent Handover (MIH)/IEEE 802.21 with QoE-awareness, seamless mobility and video adaptation by integrating a set of QoE-based decision-making modules into MIH, namely a video quality estimator, a dynamic class of service mapping and content adaptation schemes. The QoEHand video estimator, mapping and adaptation components operate by coordinating information about video characteristics, available wireless resources in IEEE 802.11e and IEEE 802.16e service classes, and QoE-aware human experience. The video quality estimator works without the need for any decoding, which saves time and minimises processing overheads. Simulations were carried out to show the benefits of QoEHand and its impact on user perception by using objective and subjective QoE metrics.     

Onto scalable wireless ad hoc networks: Adaptive and location-aware clustering

Clustering is a widely used solution to provide routing scalability in wireless ad hoc networks. In the literature, clustering schemes feature different characteristics and purposes, however few schemes are context-aware. This work proposes a new solution called Distributed and Location-aware Clustering (DiLoC), a clustering scheme designed to operate in indoor environments, providing mechanisms to gather context location information in order to ease the maintenance of clusters, thus resulting in a stabler network topology in order to provide a scalable network topology for an efficient routing. DiLoC considers three distinct approaches, regarding the characteristics of the deployment environment, aiming to cover infrastructure-less, infrastructure and hybrid network scenarios. DiLoC was evaluated and compared with a similar clustering scheme, featuring the stability, amount of clustered nodes and network load. Included results demonstrate a scalable algorithm with a significant high stability.     

Influence of zirconia surface treatments on resin cement bonding and phase transformation

It evaluated the effects of different zirconia surface treatments on the bond strength of a resin cement to Y-TZP (yttria-stabilized tetragonal zirconia) ceramics, as well as their phase-transformations. 75 blocks (5 mm × 5 mm × 4 mm) of Y-TZP were assigned into five groups (n = 15): (tribochemical silica coating - TBS) zirconia surface was abraded by silica coated alumina particles followed by silanization; (GLZ₁) zirconia surface received the application of a thin layer of low-fusing porcelain glaze, followed by hydrofluoric acid (HF) etching for 1 min; (GLZ₅) glaze application + HF etching by 5 min; (GLZ₁₀) glaze application + HF etching by 10 min; (GLZ₁₅) glaze application + HF etching by 15 min. After etching, all the specimens were washed, dried and silanized. Cylinders of composites (diameter: 3.25 mm; height: 3 mm) were cemented to the Y-TZP blocks using a resin cement. All the specimens were subjected to aging (10,000 thermal cycles and 90 days storage), tested under shear conditions, and finally analyzed by a stereomicroscope (failure analysis). In addition, we also performed topographical and phase transformation analyses of the treated zirconia surfaces. The TBS group presented the highest bond strength value (23.34 MPa). The glazed groups presented low bond values and high prevalences of pretest failures. X-ray diffraction analysis showed a phase transformation for the TBS group (13.14%); however, there was no clear phase change observed for the GLZ groups. From our results, we concluded that tribochemical silica coating is the main Y-TZP surface conditioning for resin bond improvements.     

Shielding video streaming against packet losses over VANETs

Vehicular ad-hoc networks (VANETs) are being widely adopted in the last few years. This type of network enables the utilization of a large diversity of distributed applications, such as road and traffic alerts, autonomous driving capabilities and video distribution. Video applications can be considered one of the most demanding services because it needs a steady and continuous flow of information. This presents a set of challenges to VANETs considering their scarce network resources due to the vehicle movement and time-varying wireless channels. Considering the above mentioned issues, an adaptive quality of experience (QoE)-driven mechanism is needed to provide live transmission capabilities to video-equipped vehicles. This mechanism has to overcome the challenges to grant a high-quality video transmission without adding any unnecessary network overhead. To this end, a forward error correction (FEC) technique can be adapted to enhance the video distribution, leading to higher QoE for end users. The proposed self-adaptive FEC-based mechanism (SHIELD) uses several video characteristics and specific VANETs details to safeguard real-time video streams against packet losses. One of the main contributions of this work is the combined used of network density, signal-to-noise ratio, packet loss rate, and the vehicle’s position. This allows SHIELD to better protect the video sequences and enhance the QoE. In doing that, we are able to improve the user experience, while saving network resources. The advantages and drawbacks of the proposed mechanism are demonstrated through extensive experiments and assessed with QoE metrics, proving that it outperforms both adaptive and non-adaptive mechanisms.