Strategies to obtain pattern fidelity in nanowire growth from large-area surfaces patterned using nanoimprint lithography

Position controlled nanowire growth is important for nanowire-based optoelectronic components which rely on light emission or light absorption. For solar energy harvesting applications, dense arrays of nanowires are needed; however, a major obstacle to obtaining dense nanowire arrays is seed particle displacement and coalescing during the annealing stage prior to nanowire growth. Here, we explore three different strategies to improve pattern preservation of large-area catalyst particle arrays defined by nanoimprint lithography for nanowire growth. First, we see that heat treating the growth substrate prior to nanoimprint lithography improves pattern preservation. Second, we explore the possibility of improving pattern preservation by fixing the seed particles in place prior to annealing by modifying the growth procedure. And third, we show that a SiN _x growth mask can fully prevent seed particle displacement. We show how these strategies allow us to greatly improve the pattern fidelity of grown InP nanowire arrays with dimensions suitable for solar cell applications, ultimately achieving 100% pattern preservation over the sampled area. The generic nature of these strategies is supported through the synthesis of GaAs and GaP nanowires.

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Conformance testing in systems with semicontrollable interfaces

In a conformance testing environment, an implementation under test (iut) communicates with multiple entities. A tester may have differing degrees of control on the interactions between these entities and the iut : directly controllable, semicontrollable, or uncontrollable. Semi-controllable inputs most likely render portions of an IUT untestable. In addition, multiple communicating entities may create race conditions during testing. This paper presents a test generation methodology for systems where the semicontrollable inputs can be generated indirectly. The test sequences obtained from the converted graph fully utilize the semicontrollable inputs (where possible) while avoiding the race conditions. Although, for the most general case, the graph conversion results in a exponentially large number of nodes, practical considerations make the converted graph size feasible. This approach is used to generate tests for mil-std 188-220B. By applying the proposed graph conversion and the race condition elimination techniques, the number of testable state transitions increased from approximately 200 to over 700, which represents a coverage of 95% of the transitions defined in the specification.     

A New Analyzer Based on Pellistor Sensor with Neural Network Data Postprocessing for Measurement of Hydrocarbons in Lower Explosive Limit Range

We present the results of a first stage of development work on a new type of analyzer for hydrogen and C₁–C₃ hydrocarbons concentration measurements in the lower explosive limit range, based on single pellistor sensor with artificial neural network data postprocessing.     

Terminal Mannose Residues in Seminal Plasma Glycoproteins of Infertile Men Compared to Fertile Donors

The impact of seminal plasma components on the fertilization outcomes in humans is still under question. The increasing number of couples facing problems with conception raises the need for predictive biomarkers. Detailed understanding of the molecular mechanisms accompanying fertilization remains another challenge. Carbohydrate–protein recognition may be of key importance in this complex field. In this study, we analyzed the unique glycosylation pattern of seminal plasma proteins, the display of high-mannose and hybrid-type oligosaccharides, by means of their reactivity with mannose-specific Galanthus nivalis lectin. Normozoospermic infertile subjects presented decreased amounts of lectin-reactive glycoepitopes compared to fertile donors and infertile patients with abnormal semen parameters. Glycoproteins containing unveiled mannose were isolated in affinity chromatography, and 17 glycoproteins were identified in liquid chromatography-tandem mass spectrometry with electrospray ionization. The N-glycome of the isolated glycoproteins was examined in matrix-assisted laser desorption ionization mass spectrometry. Eleven out of 27 identified oligosaccharides expressed terminal mannose residues, responsible for lectin binding. We suggest that lowered content of high-mannose and hybrid type glycans in normozoospermic infertile patients may be associated with impaired sperm protection from preterm capacitation and should be considered in the search for new infertility markers.     

Modification of physicochemical properties of actin filaments suppresses cell fragmentation in the execution phase of staurosporine-induced apoptotic processes

Effects of jasplakinolide (JSP), a stabilizer of F-actin, and latrunculin A (LTA), a destabilizer of F-actin, on a series of events occurring in the execution phase of staurosporine (STS)-induced apoptotic processes were studied using human osteosarcoma 143B cells. Time-dependent apparent increases of the population of cells with collapsed membrane potential of mitochondria (Delta Psi(m)) caused by STS treatment were not due to actual decreases in the Delta Psi(m) per cell, but due to the fragmentation of cells resulting in decreases in the number of active mitochondria per cell. Decreases in the Delta Psi(m) in fragmented cells occurred late in the execution phase. Both JSP and LAT failed to prevent STS-induced release of cytochrome c from mitochondria followed by the activation of caspases 3 and 9, the cleavage of poly (ADP-ribose) polymerase (PARP) and apoptotic nuclear fragmentation. However, both drugs prevented STS-induced apoptotic cell fragmentation and decreases in the Delta Psi(m). These results indicate that physicochemical states of actin filaments play a certain role in the execution phase of STS-induced apoptotic processes.     

Influence of aluminium electrode preparation on PCE values of polymeric solar cells based on P3HT and PCBM

The main goal of the paper was investigation of influence of aluminum electrode preparation via thermal evaporation (TE) and the magnetron sputtering (MS) on power conversion efficiency (PCE) of polymeric solar cells. The photovoltaic properties of such three kinds devices based on poly(3-hexylthiophene-2,5-diyl) (P3HT) as ITO/P3HT/Al, ITO/P3HT:PCBM (1:1, w/w)/Al and ITO/PEDOT:PSS/P3HT:PCBM (1:1, w/w)/Al were investigated. For the constructed devices impedance spectroscopy were analyzed. For devices lack of PEDOT:PSS layer or lack of PCBM, photovoltaic parameters were very low and similar to the parameters obtained for device with Al electrode prepared by magnetron sputtering. The devices comprising PEDOT:PSS with P3HT:PCBM showed the best photovoltaic parameters such as a V_OC of 0.60 V, J_SC of 4.61 mA/cm², FF of 0.21, and PCE of 5.7 × 10^?1%.     

A Photoexcited Porphyrin System as a Biomimetic Catalyst for D-limonene Biotransformation

A photoexcited porphyrin system has been found to be an efficient catalyst for D-limonene biotransformation. The catalyst showed high selectivity in hydroxylation of D-limonene. The best catalyst for limonene biotransformation was 5,10,15,20-Tetraphenylporphyrin (H₂TPP), which gave the highest accumulation of carvone and an unknown product with a verbenone-like mass spectrum. The highest conversion yield of these products was favoured at 1:2 molar ratio of H₂TPP to limonene. Some factors affecting the biotransformation yield were also investigated. Maximal yield of carvone was obtained in the medium containing 90% of the substrate, within the period of 18–36 h. Mechanism involved in limonene biotransformation catalysed by H₂TPP is also discussed.     

Time dependence of bioactive compounds and antioxidant capacity during germination of different cultivars of broccoli and radish seeds

Optimisation of the germination process of different cultivars of broccoli (Brassica oleracea var. italica cv. Lucky, cv. Tiburon and cv. Belstar) and radish (Raphanus sativus cv. Rebel and cv. Bolide) seeds in relation to the content of glucosinolates (GLS), vitamin C and total antioxidant capacity was carried out in order to maximise the health-promoting properties of Brassica sprouts. The content of total and individual GLS varied between species, among cultivars, and germination time. Glucoraphanin in broccoli and glucoraphenin in radish were the predominant GLS in raw seeds (61–77 and 63–129 μmol/g DM, respectively) and, although their content decreased during germination, they were maintained in rather large proportions in sprouts. Vitamin C was not detected in raw seeds and its content increased sharply in broccoli and radish sprouts (162–350 and 84–113 mg/100 g DM, respectively). Raw brassica seeds are an excellent source of antioxidant capacity (64–90 and 103–162 μmol Trolox/g DM in broccoli and radish, respectively) and germination led to a sharp increase. Germination of broccoli cv. Belstar and radish cv. Rebel for 4 days provided the largest glucoraphanin and glucoraphenin content, respectively, and also brought about large amounts of vitamin C and antioxidant capacity.     

Comparison of approaches to the numerical modelling of pure metals solidification using the control volume method

The thermal processes proceeding in the casting-mould system are analysed. Solidification process can be described in the different ways. One of them consists in the application of the Fourier–Kirchhoff equation in which the source function controlling the phase change is introduced. In this paper, two approaches to the modelling of pure metals solidification, i.e. the solidification proceeding at the constant temperature and in the artificially introduced interval of temperature are considered. Numerical model used at the stage of computations is constructed using the Control Volume Method in which the principle of conservation of energy (taking also into account the release of latent heat of solidification) is applied to each control volume ensuring the correctness of the model. The use of Voronoi/Thiessen tessellation to the discretization of the casting-mould system can accurately reproduce the shape of each sub-domain. In the final part of the paper, the examples of computations are shown.