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131.
The macroscopic mechanical properties of colloidal particle gels strongly depend on the local arrangement of the powder particles. Experiments have shown that more heterogeneous microstructures exhibit up to one order of magnitude higher elastic properties than their more homogeneous counterparts at equal volume fraction. In this paper, packings of spherical particles are used as model structures to computationally investigate the elastic properties of coagulated particle gels as a function of their degree of heterogeneity. The discrete element model comprises a linear elastic contact law, particle bonding and damping. The simulation parameters were calibrated using a homogeneous and a heterogeneous microstructure originating from earlier Brownian dynamics simulations. A systematic study of the elastic properties as a function of the degree of heterogeneity was performed using two sets of microstructures obtained from Brownian dynamics simulation and from the void expansion method. Both sets cover a broad and to a large extent overlapping range of degrees of heterogeneity. The simulations have shown that the elastic properties as a function of the degree of heterogeneity are independent of the structure generation algorithm and that the relation between the shear modulus and the degree of heterogeneity can be well described by a power law. This suggests the presence of a critical degree of heterogeneity and, therefore, a phase transition between a phase with finite and one with zero elastic properties.  相似文献   
132.
The objective of this study was to evaluate the influence of two different vacuum ageing times (7 and 14 days) and the impact of the modified atmosphere packaging (MAP) configuration (gas/product ratios: 0.5 and 1 and gas composition: 70% O2 + 30% CO2 and 40% O2 + 30% CO2 + 30% N2) on the quality of fresh beef during subsequent storage at 4 °C. For this purpose, three separate experiments were performed. For each experiment, two different muscles (Longissimus dorsi and Biceps femoris) were sampled from four double‐muscled Belgian Blue beef carcasses. Next to colour, also the evolution in microbial load, pH, O2 and CO2 in the headspace and lipid oxidation at the meat surface were evaluated. A vacuum ageing for 14 days compared with 7 days resulted in a higher initial microbial load on the day of MAP packaging, which resulted finally in a significantly shorter shelf life. This ageing effect was less pronounced on the colour stability and lipid oxidation of the meat samples. No significant influence of the packaging configuration on any of the analysed parameters (colour, microbial load, pH and lipid oxidation at the meat surface) was observed.  相似文献   
133.
The requirements concerning the technical availability as part of the overall equipment effectiveness increase constantly in production nowadays. Unplanned downtimes have to be prevented via efficient methods. Predictive, condition-based maintenance represents a valuable approach for fulfilling these demands, but precise models for state estimation are missing. From the manufacturers’ point of view the challenge consists in wear models with the capability of specifying the correct component’s state as well as providing reliable failure forecasts. Unfortunately, nowadays creation of wear models is based on specific stress tests or design of experiments from the manufacturer. The integration of the production phase or even data feedback and user knowledge does not take place. New potential is promised by cross-cutting technologies from ICT like cloud technologies—in general virtual platform concepts—or approaches of machine learning as enabling technologies. The objective of this paper is to adopt existing algorithms to the new application of condition monitoring in order to evaluate the applicability for automated training of robust wear models. In that context the most commonly used algorithms are described and the reader gets an impression what challenges have to be met when dealing with machine learning. A selection of about ten algorithms with 45 variants is evaluated for four different features within a packaging machine. In the outlook the embedding of the trained model in a cloud architecture is presented.  相似文献   
134.
The identification of plant-wide faults is a very important topic as it enables plant operators to decrease rejections or to increase the product quality. This paper shows a fault propagation approach for this field of interest based on time delay estimation. Due to the fact that the estimation of time delays in multiple-input single-output systems or nonlinear systems is either impossible or very difficult with known methods, a new method based on k nearest neighbor imputation was developed and is validated in this paper theoretically. The effectiveness of the identification algorithm is demonstrated on several simulations and on an industrial hydrocracker plant.  相似文献   
135.
In the last eight decades, considerable modelling and computational efforts have been made to predict the strain rate during cutting with the aim of optimizing machining processes. However, the validation of these modelling approaches on a local scale remains excessively limited due to the lack of in-situ measurements and the faulty existing quick-stop tests. This work presents the in-process analysis of the strain rate and strain in the primary shear zone using high speed Digital Image Correlation (DIC) techniques. The comparison of measured and computed results shows the suitability of the DIC techniques and the robustness of the modelling approaches.  相似文献   
136.
Frameworks of environmental regulations are fundamental yet problematic factors in achieving climate mitigation and adaptation policy goals. Recent theoretical arguments claim the value of general legal frameworks to enable experimentation and contextual adaptation of policies. However, empirical research regarding the effects of both general and specific norms in the practice of urban intervention remains limited. In this article we empirically discern how city governments deal with the tension between control and flexibility in the implementation of urban climate change goals. We argue that policies of adaptation/mitigation face two types of implementation problems: non-adaptive implementation and non-implementation. The first stems from an excessively constraining use of rules, while the second derives from a too general and undefined regulatory framework. Analysing two empirical cases in Amsterdam, Netherlands and Boston, MA, USA, we conclude that there are three elements that affect the way actors deal with these deficits: the level of scale at which regulations are established, the degree of land ownership which provides margin of manoeuvre to public authorities, and the sense of political urgency behind mitigation and adaptation policies.  相似文献   
137.
Dispersal of species is a fundamental ecological process in the evolution and maintenance of biodiversity. Limited control over ecological parameters has hindered progress in understanding of what enables species to colonize new areas, as well as the importance of interspecies interactions. Such control is necessary to construct reliable mathematical models of ecosystems. In our work, we studied dispersal in the context of bacterial range expansions and identified the major determinants of species coexistence for a bacterial model system of three Escherichia coli strains (toxin-producing, sensitive and resistant). Genetic engineering allowed us to tune strain growth rates and to design different ecological scenarios (cyclic and hierarchical). We found that coexistence of all strains depended on three strongly interdependent factors: composition of inoculum, relative strain growth rates and effective toxin range. Robust agreement between our experiments and a thoroughly calibrated computational model enabled us to extrapolate these intricate interdependencies in terms of phenomenological biodiversity laws. Our mathematical analysis also suggested that cyclic dominance between strains is not a prerequisite for coexistence in competitive range expansions. Instead, robust three-strain coexistence required a balance between growth rates and either a reduced initial ratio of the toxin-producing strain, or a sufficiently short toxin range.  相似文献   
138.
We report efficient and bright organic light-emitting devices operated by capacitive energy coupling. In this approach, the organic layers are enclosed between sputter-deposited hafnium dioxide layers to prevent charge carrier injection. When a sinusoidal voltage signal is applied to the electrodes, the devices emit bright green light whereas no detectable emission is generated upon application of a constant voltage. The efficiency of the process depends heavily on the frequency of the applied voltage signal. By optimizing the driving scheme, a record luminous efficacy for AC driven OLEDs of 2.7 lm/W at 500 cd/m2 is achieved.  相似文献   
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