Quantification of Entrainment Using an Optical Inline Probe

In distillation and absorption processes, entrainment above trays or packings reduces stage and column efficiency. A modified version of the optical multimode online probe enables a seminal insight and, thus, quantification of entrained droplets on various axial and radial positions. A purging mechanism inhibits precipitation of droplets on the front lenses, while telecentric optics and illumination provide distance‐independent and precise imaging of entrained droplets between two valve trays. Experiments were performed in a DN 450 cold flow (air‐water) test rig. The results were compared with noninvasive phase Doppler anemometry data.     

Anelastic reorganisation of fibre-reinforced biological tissues

In this work, we contribute to the study of the structural reorganisation of biological tissues in response to mechanical stimuli. We specialise our investigation to a class of hydrated soft tissues, whose internal structure features reinforcing fibres. These are oriented statistically within the tissue, and their pattern of orientation is such that, at each material point, the tissue is anisotropic. From its natural, stress-free state, the tissue can be distorted anelastically into a global reference configuration, and then deformed under the action of external mechanical loads. The anelastic distortions are responsible for changing irreversibly the internal structure of the tissue, which, in the present context, occurs through both the rearrangement of the bonds among the tissue cells and the deformation-driven reorientation of the fibres. The anelastic strains, in addition, are assumed to model the onset and evolution of microcracks in the tissue, which may be triggered by the mechanical loads applied to the tissue in the case of traumatic events, or diseases. For our purposes, we formulate an anisotropic model of remodelling and we consider a fully isotropic model of structural reorganisation for comparison, with the aim to study if, how, and to what extent the evolution of anelastic distortions is influenced by the tissue’s anisotropy.

     

The effect of cognitive and affective aspects on usability

Studies on customer’s needs, desires and preferences have become highly important in the product design and development process. One consideration in usability is the cognitive aspect, which is related to the accommodation and evaluation of human cognitive capabilities, limitations and tendencies. In addition to the cognitive aspect, a recent study has shown that the affective aspect has been considered in the evaluation of product usability. Thus, both cognitive and affective aspects are deemed to be important for product design and the development process. Inherently, both aspects deliver complete human and product interaction and experience. However, studies that consider the affective process as a complement to the cognitive process for usability are relatively rare. To address this gap, this study discusses how an integrative framework of the cognitive and affective aspects can be applied to a product for usability assessment via empirical studies on e-commerce and e-learning platforms. The sample involved 230 respondents, using purposive sampling. The result shows that both cognitive and affective aspects have a significant effect, although with different weights. The affective aspect has been shown to improve product usability and user’s acceptance.     

On‐surface polymerization – a versatile synthetic route to two‐dimensional polymers

Two‐dimensional (2D) polymers are novel covalent sheet materials with promising properties, but also great synthetic challenges. The inadequacy of traditional wet chemical synthesis calls for new synthetic paradigms. In this respect, employing surfaces as inherently 2D reaction venues appears an adequate choice and has recently already yielded encouraging results. Polymerization at air ? liquid and liquid ? liquid interfaces has been reported from time to time over the last decades, whereas recent efforts on solid surfaces are less traditional. In either case, both movement and coupling of monomers are already confined in two dimensions at interfaces or on surfaces. Accordingly, this approach naturally affords low‐dimensional reaction products. To achieve 2D reticulation, monomers are functionalized with multiple reactive groups of the same or a different kind, whereby their number and stereochemical arrangement predefines the ideal structure of the resulting 2D polymer. This perspective article exemplifies different approaches, i.e. types of surfaces, coupling chemistry and activation schemes, to employ surfaces for novel synthetic routes for the bottom‐up synthesis of 2D polymers. © 2015 Society of Chemical Industry     

Media,Technologies, Cooperation – Rethinking Publics and Publicness in the MENA Region

Computer Supported Cooperative Work (CSCW) -     

Influence of Methanol on Prion Reduction during High Temperature and High Pressure Oleochemical Processes

Prion‐reduction in standard biodiesel processes is caused by acidic and alkaline conditions. In the alternative RepCat biodiesel process, efficient prion‐reduction can be achieved by high‐temperature/pressure. However, a possible increase in thermostability of prions in the presence of methanol during these conditions has not previously been investigated, and is verified in this work. Samples are spiked with prions, treated with methanol, and incubated at 220 °C at 80 bar for 30 min. No traces of protease‐resistant prion protein (as proxy for prions) are detected in tallow or glycerine (as the final by‐product) after treatment. Serial dilutions of spiked prions show at least 6 log₁₀ prion reduction. More importantly, similar effects are detected using milder conditions of 200 °C at 70 bar for 15 min, representing the worst‐case conditions of the process. In conclusion, this study shows that methanol does not increase the thermostability of prions and the RepCat process can efficiently eliminate prions and is therefore safe for the usage of category 1 tallow. Practical Applications: The study further supports the applicability of RepCat process in reducing prion‐contamination in the presence of methanol. Furthermore, the conditions leads to a considerable reduction of prions in glycerine obtained as by‐product.     

Electrochemical Characterization of Isolated Nitrogenase Cofactors from Azotobacter vinelandii

The nitrogenase cofactors are structurally and functionally unique in biological chemistry. Despite a substantial amount of spectroscopic characterization of protein-bound and isolated nitrogenase cofactors, electrochemical characterization of these cofactors and their related species is far from complete. Herein we present voltammetric studies of three isolated nitrogenase cofactor species: the iron–molybdenum cofactor (M-cluster), iron–vanadium cofactor (V-cluster), and a homologue to the iron–iron cofactor (L-cluster). We observe two reductive events in the redox profiles of all three cofactors. Of the three, the V-cluster is the most reducing. The reduction potentials of the isolated cofactors are significantly more negative than previously measured values within the molybdenum–iron and vanadium–iron proteins. The outcome of this study provides insight into the importance of the heterometal identity, the overall ligation of the cluster, and the impact of the protein scaffolds on the overall electronic structures of the cofactors.