Transparent monolithic zirconia gels: effects of acetylacetone content on gelation

Transparent yttria-stabilized zirconia monolithic gels were synthesized under controlled conditions for hydrolysis and chemical polymerization. The influence of acetylacetone on the previous chemical reactions was explored, and a plausible explanation was proposed concerning the outstanding role of this additive during the gelation process. Small-angle X-ray scattering was used to estimate the size of the polymeric species and to investigate the influence of acetylacetone on the structure of the gels prepared.     

A simple one-cycle power supply for approach to saturation studiesin soft magnetic polycrystalline toroidal samples

The ring shape is a good solution to the study of the magnetization processes of magnetic materials because demagnetizing fields are easily avoided. However, when small samples are investigated, the magnitude of the field applied is necessarily limited by the low number of primary winding turns, and by the cross section of the wire itself. The use of sequential-type techniques for high current supply allows this problem to be avoided. One-cycle power production from the 50 Hz AC-line voltage is a simple example of such techniques. An electronic device designed around a commercial integrated circuit is described. A full period of current of 20-ms duration is applied to the load with a magnitude ranging from 0 to 100 A. Magnetization parameters of soft polycrystalline ring ceramics approaching the saturation region are studied as an application. The fitness to measure such characteristic parameters as saturation magnetization and magnetic hardness is shown     

On the stationary distribution of speed and location of random waypoint

In "Stationary distributions for the random waypoint mobility model" (TMC, Vol. 3, No, 1), Navidi and Camp find the stationary distribution of the random waypoint model, with or without pause on a rectangular area. In this short note, we show that, under the stationary regime, speed and location are independent.     

An integrated system to remote monitor and control anaerobic wastewater treatment plants through the internet.

The TELEMAC project brings new methodologies from the Information and Science Technologies field to the world of water treatment. TELEMAC offers an advanced remote management system which adapts to most of the anaerobic wastewater treatment plants that do not benefit from a local expert in wastewater treatment. The TELEMAC system takes advantage of new sensors to better monitor the process dynamics and to run automatic controllers that stabilise the treatment plant, meet the depollution requirements and provide a biogas quality suitable for cogeneration. If the automatic system detects a failure which cannot be solved automatically or locally by a technician, then an expert from the TELEMAC Control Centre is contacted via the internet and manages the problem.     

Making polyurethane foams from microemulsions

A remarkable correlation exists between the degree of expansion of polyurethane foams and the structure of the reacting premixes. Polyurethane foams obtained from reacting premixes containing microemulsions are highly expanded. The expansion rate is proportional to the volume fraction of microemulsion in the premix. The stability of premixes with and without microemulsion is completely different suggesting distinct creaming mechanisms. We apply this idea to synthesize polyurethane foams from microemulsions successfully. This approach can be used to rationalize the design of polyurethane formulations leading to highly expanded foams.     

Synthesis, characterization and devitrification behaviour of an yttrium containing boroaluminate glass

The glass forming region in the B₂O₃-Al₂O₃-Y₂O₃ composition diagram has been determined by a melting and quenching procedure at temperatures up to 1800°C. Different physical characteristics (density, coefficient of thermal expansion, glass transition and crystallization peak temperatures) have been determined for a 35B₂O₃-40Al₂O₃-25Y₂O₃ glass composition (in mol.%). By using a predictive model and some NMR structural data, different elastic moduli (Young's modulus, bulk modulus, shear modulus and Poisson's ratio) have been calculated. The devitrification behaviour has also been studied. Internal crystallization is the dominant mechanism and a new (Y, Al)BO₃ ternary phase has been characterized by X-ray powder diffraction. The temperature and time nucleation dependence have been determined from DTA experiments as well as the crystallization kinetics (i.e. the Avrami exponent and the activation energy for crystal growth).     

Bench-Scale Testing of Nanofiltration for Seawater Desalination

A dual-staged nanofiltration process is being evaluated as an alternative to reverse osmosis for seawater desalination. The primary goal of this system is to reduce energy consumption while producing potable water at an acceptable recovery rate. Investigation of this system at the bench-scale level focused on membrane surface characterization, ion rejection (including boron, bromide, and iodide rejection), and flux decline. Results from this study showed that two commercially available nanofiltration membranes can effectively desalinate seawater. Although fouling was apparent—and resulted in approximately 20% flux decline over 3 days—a critical flux was not identifiable. Operation of the system at different cross-flow velocities revealed the significance of hydrodynamic conditions on the polarization modulus, and hence on membrane performance.     

Locations and amplitudes of the extrema of the sinx/x function

This paper addresses the calculation of the extrema of the sin x/x function. First the Newton-Raphson method is used, which allows us to obtain the extrema locations very fast through the use of a recursion formula. Then a second approach is proposed, which gives the extrema locations and the extrema amplitudes in the form of series expansions. Simple, accurate algebraic expressions are derived.     

Ventilatory response to severe acute hypoxia in guinea-pigs and rats with high hemoglobin-oxygen affinity induced by cyanate

Laparoscopic pelvic lymph node dissection has been applied as a minimally invasive staging technique for men with prostate cancer. This procedure has been shown to shorten markedly postoperative hospitalization, decrease analgesic requirements and shorten convalescence period compared to open pelvic node dissection. However, the laparoscopic procedure takes longer to perform and many disposable instruments are used, thus increasing the cost. We determine the overall cost of laparoscopic versus open pelvic lymph node dissection. Between January 1989 and April 1992, 61 men underwent only staging pelvic lymph node dissection for cancer of the prostate at a single university teaching hospital. Of these patients 11 and 50 underwent open and laparoscopic pelvic lymph node dissection, respectively. Information from the hospital business office was reorganized into preoperative, intraoperative and postoperative expenses. All individual charges were transformed up or down to the dollar amounts of the 1990 to 1991 fiscal year so as to correct for inflationary changes. Preoperative costs were not significantly different between the 2 operative approaches. Intraoperative expenses were 52% greater if laparoscopic pelvic lymph node dissection was performed and can be explained by the longer operative times and use of disposable instrumentation. However, the postoperative period lasted an average of 1.61 days following laparoscopic pelvic lymph node dissection. Postoperative nursing and analgesic requirements were significantly more for patients undergoing open pelvic lymph node dissection. The overall postoperative costs following open pelvic lymph node dissection were 280% more expensive than for the laparoscopic procedure. The overall total costs were approximately $1,250 more for laparoscopic pelvic lymph node dissection. Wages lost or earned during this period and rapid return to normal activity following laparoscopic pelvic lymph node dissection would, in our opinion, justify this additional cost.