Influence of melt stability on the crystallization of bis(4-aminophenoxy)benzene-oxydiphthalic anhydride based polyimides

Novel high performance semicrystalline polyimides, based on controlled molecular weight phthalic anhydride (PA) endcapped 1,4-bis(4-aminophenoxy)benzene (TPEQ diamine) and oxydiphthalic dianhydride (ODPA), were synthesized. They exhibited excellent thermal stability in nitrogen and air atmospheres as determined by thermogravimetric analysis (TGA). The glass transition temperatures (T_g) for these polymers ranged from 225°C for the 10,000 M_n (10K) polymer, to 238°C for the 30,000 (30K) M_n material. The observed melting temperatures for all the polymers were ∼420°C. The crystallization behavior of these polymers showed a strong molecular weight dependence, as illustrated by the observation that the 10K and 12.5K polymers crystallized with relative ease, whereas the 15K, 20K, and 30K polymers showed little or no ability to undergo thermal recrystallization. The thermal stability of these polymers above T_m was investigated by studying the effect of time and temperature in the melt on the cold crystallization and melting of these polymers. Increased time and temperature in the melt resulted in lower crystallinity because of melt state degradation, such as crosslinking and branching, as evidenced by an increase in melt viscosity, which was more prominent for the higher molecular weight polymers.     

Planning of randomized early detection trials

Consider a randomized clinical trial to evaluate the benefit of screening an asymptomatic population. Suppose that the subjects are randomized into a usual care and a study group. The study group receives one or more periodic early detection examinations aimed at diagnosing disease early, when there are no signs or symptoms. Early detection clinical trials differ from therapeutic trials in that power is affected by: i) the number of exams, ii) the time between exams and iii) the ages at which exams will be given. These design options do not exist in therapeutic trials. Furthermore; long-term follow-up may result in a reduction of power. In general, power increases with number of examinations, and the optimal follow-up time is dependent on the spacing between examinations. Clinical trials in which the usual care group receives benefit are also discussed. Two designs are discussed, for example the 'up-front design' in which all subjects receive an initial exam and then are randomized to the usual care and study groups and the 'close-out design' in which the usual care group receives an exam which is timed to be given at the same time as the last exam in the study group. Both families of designs significantly reduce the power. Power calculations are made for two clinical trials, which actually used these two designs.     

Similarities and differences in four views of David.

In this article, each author gives a brief comment on similarities he or she sees throughout the case formulations captured in the articles by Watson (2010a), Silberschatz (2010), Goldfried (2010), and Caspar (2010). A systematic comparison is added. Overall, the impression is confirmed and maintained that if authors are ready to renounce the use of the jargon of their specific approach, many similarities can be found. There are nevertheless differences that would lead us to expect a different course of therapy and different effects beyond the main effect of recovery in the case of David, pursuing the conceptualization and interventions proposed by Watson (2010b). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Considerations for linking seatpan and backrest angles

Modern ergonomic chairs typically have several dimensions that can be adjusted independently of one another. Finding a desirable setting for any one dimension can depend on how other dimensions are set, thereby confronting users with a significant control problem. One design strategy for dealing with this problem has been to link changes in seatpan and backrest angles in some ratio, such that a one‐degree change in seatpan angle is associated with a two‐ or three‐degree change in backrest angle. However, there is no evidence to justify the choice of a particular ratio. This article presents data that addresses this issue. Subjects, performing either an entry or verification task, could adjust the chair to any position. Backrest and seatpan angles were plotted over time and analyzed using both graphical and statistical methods. The resulting scatter plots do not support the industry standard, 1:2 or 1:3 ratio, of changes in seatpan to backrest angles. The possibility of a variable linkage is discussed; however, problems associated with such a solution raise the possibility that control issues might be best addressed through training and exploration.     

Prevention and Mitigation Strategies to Address Recent Brittle Fractures in Steel Bridges

Brittle fracture results in unplanned loss of service, very costly repairs, concern regarding the future safety of the structure, and potential loss of life. These types of failures are most critical when there is no evidence of fatigue cracking leading up to the fracture and the fracture origin is concealed from view. Hence, the failure occurs without warning and the details are, essentially, noninspectable. In these cases, it appears desirable to take a proactive approach and introduce preventative retrofits to reduce the potential for future crack development. These efforts will help ensure that the likelihood of unexpected fractures is minimized. This paper examines the behavior of two bridge structures in which brittle fractures have developed in recent times, discusses the causes of the failures, and offers suggested design strategies for prevention and retrofit mitigation techniques. In situations where considerable uncertainty exists in the prediction of accumulated damage or in the ability to reliably inspect critical details, preemptive retrofit strategies appear to be highly desirable.     

Rechtsprechung zum Datenschutz 2006 — Teil 1

Neben den Kontroversen um die Vorratsdatenspeicherung, den personenbezogenen Daten aus der Mautüberwachung und den Reaktionsm?glichkeiten gegenüber dem Terrorismus herrschte auch in der Judikatur zum Datenschutz rege Bewegung. Die davon betroffenen Rechtsgebiete waren mannigfaltig, was abermals unterstreicht, dass das Datenschutzrecht eine Querschnittmaterie darstellt. Dies ist der Anlass, die wichtigsten Entscheidungen des vergangenen Jahres kurz darzustellen.     

Rechtsprechung zum Datenschutz 2006 — Teil 2

Nachdem sich der erste Teil der Rechtsprechungsübersicht insbesondere der Judikatur des BVerfG und des BGH gewidmet hat, befasst sich der zweite Teil vornehmlich mit Entscheidungen aus dem Zeitraum Januar bis Anfang November 2006, die im Arbeitsrecht und dem Internetrecht sowie auf den Gebieten der Werbung und des Marketing ergangen sind.     

Evaluating the usability of natural language query languages and interfaces to Semantic Web knowledge bases

The need to make the contents of the Semantic Web accessible to end-users becomes increasingly pressing as the amount of information stored in ontology-based knowledge bases steadily increases. Natural language interfaces (NLIs) provide a familiar and convenient means of query access to Semantic Web data for casual end-users. While several studies have shown that NLIs can achieve high retrieval performance as well as domain independence, this paper focuses on usability and investigates if NLIs and natural language query languages are useful from an end-user's point of view. To that end, we introduce four interfaces each allowing a different query language and present a usability study benchmarking these interfaces. The results of the study reveal a clear preference for full natural language query sentences with a limited set of sentence beginnings over keywords or formal query languages. NLIs to ontology-based knowledge bases can, therefore, be considered to be useful for casual or occasional end-users. As such, the overarching contribution is one step towards the theoretical vision of the Semantic Web becoming reality.     

Routing on Meshes with Buses

We consider the problem of routing packets on an MIMD mesh-connected array of processors augmented with row and column buses. We give lower bounds and randomized algorithms for the problem of routing k-permutations (where each processor is the source and destination of exactly k packets) on a d-dimensional mesh with buses, which we call the (k,d)-routing problem. We give a general class of ``hard' permutations which we use to prove lower bounds for the (k,d)-routing problem, for all k,d≥ 1. For the (1,1)- and (1,2)-routing problems the worst-case permutations from this class are identical to ones published by other authors, as are the resulting lower bounds. However, we further show that the (1,d)-routing problem requires 0.72 ... n steps for d=3, 0.76 ... n steps for d=4, and slightly more than steps for all d≥ 5. We also obtain new lower bounds for the (k,d)-routing problem for k,d > 1, which improve on the bisection lower bound in some cases. These lower bounds hold for off-line routing as well. We develop efficient algorithms for the (k,1)-routing problem and for the problem of routing k-randomizations (where each processor has k packets initially and each packet is routed to a random destination) on the one-dimensional mesh and use them in a general (k,d)-routing algorithm which improves considerably on previous results. In particular, the routing time for the (1,d)-routing problem is bounded by steps with high probability (whp), whenever for some constant ε > 0, and the routing time for the (k,d)-routing problem is steps whp whenever for some constant ε > 0 and k≥ 3.6 ... d, matching the bisection lower bound. We then present a simple algorithm for the (2,2)-routing problem running in 1.39 ... n+o(n) steps whp. Finally, for the important special case of routing permutations on two-dimensional meshes with buses, the (1,2)-routing problem, we give a more sophisticated algorithm that runs in 0.78 ... n+o(n) steps whp. Received May 18, 1994; revised June 23, 1995.