Mixing speed-controlled gold nanoparticle synthesis with pulsed mixing microfluidic system

Gold nanoparticles with diameters of a few tens of nanometer and a narrow size distribution were synthesized using a pulsed mixing method with a microfluidic system which consists of a Y-shaped mixing microchannel and two piezoelectric valveless micropumps. This mixing method enables control of the mixing speed of gold salts and reducing agent by changing the switching frequency of the micropumps, which was our focus to improve the particle size distribution, which is an essential parameter in gold nanoparticle synthesis. In the proposed method, the mixing time was inversely proportional to the switching frequency and the minimum mixing time was 95 ms at a switching frequency of 200 Hz. During synthesis experiments, the mean diameter of the synthesized gold nanoparticles was found to increase, and the coefficient of variation of particle size was found to decrease with decreasing mixing time. We successfully improved the coefficient of variation to less than 10% for a mean diameter of around 40 nm.     

Cellular automaton simulation of micropowder blasting with mask erosion

Development of a two‐dimensional (2D) micropowder blasting simulator for microfabrication of a glass substrate with a patterned polymer mask is reported. In order to investigate the effect of mask erosion on a processed glass profile, a cellular automaton simulation in which erosion of the glass and the polymer mask were taken into account was applied to the micropowder blasting process for the first time. From a comparison of the simulation result with the processed glass profile in the experiment, it was demonstrated that the processed glass profile with the mask erosion could be simulated using our simulator. Furthermore, it was confirmed that the processed profile in the glass depended on the mask profile and the ratio of the deformation wear and the cutting wear of a mask. Copyright © 2007 Institute of Electrical Engineers of Japan© 2007 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

用于通用变频器的DIP-CIB

针对小功率通用变频器对低成本和小型化的需求,三菱电机开发了集整流、逆变和制动功能于一体的双列直插式封装-整流逆变制动(Dual In Line Package-Converter Inverter Brake,简称DIP-CIB)模块.在此详细介绍了DIP-CIB模块的内部电路、半导体硅片技术、封装技术,以及如何配合专用的HVIC来实现通用变频器的小型化设计.     

PZT capacitor with Ir/IrO2/Ir electrode fabricated by RTA

Abstract

PZT capacitor with direct contact between Si substrate and bottom electrode of the capacitor was obtained with Ir/IrO₂/Ir/Ti electrode, by crystallizing sol-gel PZT thin film using RTA (650°CC 30 sec.). Contact resistance for hole diameter of 0.72 μm was 19 Ω. It was observed by cross-sectional TEM that Ti silicide was formed at the interface, but there was not oxygen diffusion from PZT thin film. Fatigue property of the PZT thin film was improved by RTA compared with furnace annealed film (600°CC 60 min.). The absolute value of the remnant polarization was 13 μC/cm² for both films, but it did not degrade until 10⁸ cycles of switching for the film by RTA, while it degraded before 10⁵ cycles for furnace annealed film.     

Programmed High‐Hole‐Mobility Supramolecular Polymers from Disk‐Shaped Molecules

In this paper a simple, casting solution technique for the preparation of two‐dimensional (2D) arrays of very‐high molecular weight (MW) 1D‐Pc supramolecular inorganic polymers is described. The soluble fluoroaluminium tetra‐tert‐butylphthalocyanine (ttbPcAlF) is synthesized and characterized, which can be self‐assembled to form 2D arrays of very‐high‐MW 1D‐Pc supramolecular inorganic polymers. High‐resolution transmission electron microscopy (HRTEM) demonstrates that the 1D‐ttbPcAlF, having a cofacial ring spacing of ～0.36 nm and an interchain distance of ～1.7 nm, self‐assembles into 2D‐nanosheets (～140 nm in length, ～20 nm in width, and equivalent to MW of 3.2 × 10⁵ g mol^?1). The film cast from a 1,2‐dichloroethane (DCE) solution shows a minimum hole‐mobility of ～0.3 cm² V^?1 s^?1 at room temperature by flash‐photolysis time‐resolved microwave conductivity (TRMC) measurements and a fairly high dark dc‐conductivity of ～1 × 10^?3 S cm^?1.     

Electrostatic properties of antistatic cloth woven partly withelectrically conductive fibers

An electrically conductive fiber and an antistatic cloth woven partly with electrically conductive fibers have a high electrostatic elimination effect in wet as well as dry atmospheres. The electrostatic elimination effect of the antistatic cloth does not decay with repeated washing. Antistatic cloth has been widely used in industry to prevent the electrostatic risk caused by electrification of fiberware. Charge densities and discharge characteristics of various antistatic cloths, controlled primarily by weaving electrically conductive fibers into the cloth, have been investigated experimentally. The electrostatic elimination effect of these is evaluated     

New electrical shunt with two rectangular holes in a copper plate

A new concept of an electrical shunt with two rectangular holes in a copper plate (ESRP) has been developed to be used for measuring a large current with a short‐duration steep wave in a high‐voltage field. The ratio of the input current to the output current is 10⁶, as obtained from a DC voltage test circuit. The electrical shunt has a special configuration. To verify the shunt current ratio of ESRP in a real application, the shunt current was connected to a sphere‐to‐sphere electrode breakdown test circuit with a 10 mm gap to measure the large damping current (8.4 kA) of a DC breakdown voltage. The voltage signal from the shunt was transmitted to excite two light‐emitting diodes (max. 50 mA, 4 V), which were reverse‐connected in series. The light‐emitting diodes operated properly and were illuminated, which validated the capability of the newly designed electrical shunt. © 2015 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Restraint Method for Overcoming Heating Irregularity and Improving Heating Equipment Efficiency for Beverage Cans Using High‐Frequency Induction Heating

We were able to reduce heating irregularities in equipment for heating beverage cans by using the high‐frequency induction heating method and determining the resulting improvement in the heating efficiency. The heating irregularity between the top and bottom of the can was reduced to less than 3°C by improving the arrangement of the heating coils for the beverage can by thinning the winding and changing the circuit configuration. The efficiency of power conversion was improved from 93.0% to 97.4%. In this paper, the configuration of the equipment and the experimental results are reported.     

Silica-supported cobalt catalysts for the selective reduction of nitrogen monoxide with propene

Catalytic behavior of silica-supported transition metals for NO reduction with propene in the presence of oxygen was investigated. While both silica and cobalt oxides did not show any activity for the selective NO reduction, impregnated CoO/SiO₂ prepared from cobalt acetate showed good activity although the preparation conditions had significant effect on the activity. It was suggested that highly dispersed surface Co²⁺ ions on silica are responsible for the catalytic activity.     

Thermotropic polyarylates derived from substituted hydroquinones and p-terphenyl-4,4″-dicarboxylic acid

Polyarylates from substituted hydroquinones (HQs) and p-terphenyl-4,4″-dicarboxylic acid (TPDA) that were modified with 1,2-bis(phenoxy)ethane-4,4′-dicarboxylic acid (PEC), 1,2-bis(2-chlorophenoxy)ethane-4,4′-dicarboxylic acid (ClPEC), terephthalic acid (TA) and p-hydroxybenzoic acid (HBA) were prepared and their thermal and mechanical properties were investigated. These polyarylates exhibited liquid crystallinity at about the same temperatures as polyarylates derived from substituted HQs and 4,4′-diphenyldicarboxylic acid (BB). However, as-spun fibers and injection-molded specimens of these polyarylates exhibited lower moduli than those of substituted HQs and BB that were modified with PEC, Cl-PEC and TA.