Remarkable enhancement in durability of Pd/H-ZSM-5 zeolite catalysts for CH4-SCR

Effect of second components on the catalytic performance of Pd/H-ZSM-5 zeolite (Pd: 0.4 wt.%) was evaluated by a durability test of NO reduction with CH₄ at a relatively high temperature of 500°C in the presence of water vapor for a prolonged period. The Pd/H-ZSM-5 showed high stable activity for this reaction without H₂O in the reactant feed, while immediate and irreversible deactivation was observed in the presence of H₂O, resulting in no activity after 7 h. The second components such as Co, Rh, Ag, Ce, and Fe introduced individually to the Pd/H-ZSM-5 enhanced the durability, and in particular the addition of 3.3 wt.% Co led to a stable NO conversion for more than 40 h in the presence of H₂O.     

Phase transition of thermosensitive amphiphilic cellulose esters bearing olig(oxyethylene)s

Summary A series of cellulose esters bearing olig(oxyethylene)s with different degree of substitution (DS) and different length of the oxyethylene chain were synthesized by a homogeneous reaction of cellulose with corresponding monofunctional acid chloride in a 10% LiCl-dimethyl acetoamide (DMAc) solution. The effect of total DS value on the solubility of the derivatives in aqueous solution was investigated. It was found that the lower limit DS value for both water-soluble and amphiphilic derivatives decreases with increasing length of oxyethylene chains. The amphiphilic derivatives, which are soluble in both water and chloroform, precipitate out of aqueous solution on heating without gel forming, such a phase transition behavior was studied in terms of DS value, length of oxyethylene and concentration. The precipitation temperature (T_p) of the amphiphilic derivatives is range from 54°C to 96°C. It decreases with increasing the total DS value, and increases with an increase in the length of oxyethylene chains. The T_p value of the derivatives was found to be almost independent in the concentration range of 1–15 wt %, however the T_p value increases sharply with decreasing polymer concentration when the concentration is lower than 1 wt%. Received: 29 August 2000/Revised version: 16 October 2000/Accepted: 31 October 2000     

Geology and fluid chemistry of the Fushime geothermal field, Kyushu, Japan

The Fushime geothermal field is located in a depression close to the coast line. The system is characterized by very high reservoir temperature (>350°C), and a high salinity production fluid. Geological analysis shows that the main reservoir in this field occurs in a fractured zone developed around a dacite intrusion located in the center of the field. High permeability zones recognized by drilling data are found to be associated with fault zones. One of these zones is clearly associated with a NW–SE trending andesite dike swarm which was encountered in some wells.Alteration in the system can be divided into four zones, in order of increasing temperature, based on calcium–magnesium aluminosilicate mineral assemblages: i.e., the smectite, transition, chlorite and epidote zones. The feed zone is located in the chlorite and epidote zones, which can be further divided into three sub-zones according to their potassium or sodium aluminosilicate mineralogy, from the center of the discharge zone: K-feldspar–quartz, sericite–quartz, and albite–chlorite zones.Chloride concentration of the sea-water is 19,800 mg/l, and Br/Cl mole ratio is 1.55. Based on geochemical information, the reservoir chloride concentration of this field ranges from 11,600 to 22,000 mg/kg. The Clres (Cl in reservoir), Br/Cl ratios and stable isotope data indicate that the Fushime geothermal fluid originated from sea-water and is diluted by ground water during its ascent. Some fluids produced from geothermal wells show low pH (about 4). It is thought that sulfide mineral (PbS, ZnS) precipitation during production produces this acidic fluid.     

Low-dose exposure energy-resolved X-ray computed tomography using a contrast agent with a high-energy K-edge

X-ray computed tomography (CT) with iodine contrast agent is widely employed to locate cancers. However, this method has shortcomings such as high-radiation dose exposure, iodine side effects, and a beam hardening effect. We have been working on the energy-resolved CT measurement method using a novel X-ray detection system, the “transXend” detector, which measures X-rays as electric currents and gives the energy distribution of incident X-rays after analysis. In the present study, we propose a method for low-dose exposure CT that involves the combination of the energy-resolved CT method, which is free from the beam hardening effect, and a harmless contrast agent with high-energy K-edge absorption, such as gold nanoparticles expected as a future contrast agent. Comparisons of radiation dose exposures as functions of aluminum filter thickness at the exit aperture of an X-ray tube and the K-edge energies of contrast agents are described.     

Kinetic study on the first stage during thermal degradation of polystyrene

The kinetic parameters of the first stage of polystyrene degradation have been investigated to elucidate the reaction mechanisms using the flow reactor system. The decrease in molecular weight of polystyrene was recorded at minute intervals over the temperature range 310°–390°C. Generally, the first and second stages were observed by thermogravimetric analysis (t.g.a.), however in the early stage of the degradation volatile yields of at least 5% occurred. Therefore, using t.g.a. analysis it is difficult to detect this earlier stage. It became evident that the first stage in the earlier part of the reaction could be detected by g.p.c. analysis. We have observed the hidden kinetic parameters of the nature of the first stage of the polystyrene degradation. The results indicate that the main chains were degraded randomly with the small quantitative volatile groups in the first stage and the rates of decrease in molecular weight in the first stage against reaction temperatures were evaluated as log k_s = 12.0 ? 41300/RT.     

Thermoelectric properties of Bi and Cu co-doped Ca3Co2O6single crystals

Single crystals of Bi and Cu-doped Ca₃Co₂O₆were synthesized in a molten K₂CO₃flux. Using an obtained single crystal of (Ca_0.985(5)Bi_0.015(5))₃(Co_0.990(3)Cu_0.010(3))₂O₆elongated to the c-axis direction of the crystal structure, the electric resistivity (ρ) and Seebeck coefficient (S) were measured from room temperature to over 1000 K in air. The single crystal showed p-type semiconducting behavior with ρ values of 1.8 Ω cm at 303 K and 0.017 Ω cm at 1000 K. The S values were +254 μ VK^{− 1} at 325 K, +360 μ VK^{− 1} at 420 K, and +214 μ VK^{− 1} at 1000 K. The power factor (S ² ρ ^{− 1}) increased with an increase of temperature and attained 2.70 × 10^{− 4} Wm^{− 1}K^{− 2} at 1000 K.     

Thermal degradation characteristics of oil‐filled cable joint with extremely degraded tan δ oil

Much of oil‐filled (OF) cable has been used for a long time as 66‐ to 500‐kV extrahigh‐voltage cable. Sometimes we can see extremely degraded tan δ oil (several tens of percent of tan δ, for example) in joint boxes, etc. The values of tan δ calculated by a simple combination model of paper/oil show that the oil‐impregnated paper with such a high tan δ oil likewise has an extremely high tan δ, which must result in thermal breakdown. However, such an event has not taken place up to the present in actually operated transmission lines. This fact suggests that some mechanism for the suppression of tan δ has acted in the paper insulation impregnated with degraded tan δ oil. Therefore, we investigated in detail the tan δ characteristics of paper impregnated with extremely high tan δ oil. In addition, based on the investigation results, we developed a method for simulation of heat generation by dielectric loss in an OF cable joint (which has degraded tan δ oil). © 2011 Wiley Periodicals, Inc. Electr Eng Jpn, 178(1): 1–10, 2012; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21184     

Preparation of PZT Thin Films by Liquid-Source MOCVD Using of Cyclohexane Solvent

Pb(Zr, Ti)O₃ thin films were grown on 8-inch Ir(111)/SiO₂/Si substrate by a MOCVD system aiming at application utilizing high-density ferroelectric memory (FRAM). Two types of solvents, THF and cyclohexane were used for liquid source delivery. It was found that the ferroelectric properties of the MOCVD-PZT films using cyclohexane solvent were better than them using THF solvent. By choosing cyclohexane as solvent, the MOCVD-PZT thin films showed strong ?111? preferred orientation and the Pt/PZT/Ir capacitors exhibited promising ferroelectric performances, for instance, large switching charge (Qsw) of 56.4 uC/cm².     

The Critical Energy Release Rate of Welded Joints Between Fiber-Reinforced Thermoplastics and Metals When Thermal Residual Stress is Considered

Thermal effects on welded joints between fiber-reinforced thermoplastics (FRTPs) and metals have been investigated theoretically and experimentally. Because FRTPs use thermoplastics as the matrix resin, they have advantages over fiber-reinforced thermoset plastics (FRPs or FRSPs), including the ability to be welded. When dissimilar materials are welded together, however, thermal stress occurs due to the different thermal expansions of the materials and affects the energy release rate of the joint. Therefore, a method for evaluating the true energy release rate, including the effect of thermal stress, is necessary for strength evaluation tests. Although several theories that compensate for the thermal stress and evaluate the true energy release rate have already been proposed, they require parameters that are difficult to measure. Therefore, it is difficult to apply them in experimental investigations. In this article, a theoretical method with easily measurable parameters is proposed to calculate the energy release rate of welded double cantilever beam (DCB) joints. The effect of the thermal stress on the critical energy release rate is discussed in terms of the experimental results of a welded DCB specimen composed of a FRTP and an aluminum alloy.