One-pot hydrothermal synthesis of uniformly cubic Co3O4 nanocrystals

Cubic Co₃O₄ nanocrystals (NCs) were synthesized by a one-pot hydrothermal reaction in the presence of the oxidant KClO₃ and the capping reagent polyvinylpyrrolidone (PVP). The as-prepared Co₃O₄ NCs were uniformly cubic with sharp edges and good crystallinity and showed flat surfaces with {100} facets. The capped PVP could be removed without losing cubic shape by heating the NCs at 300 °C.     

Structure Analysis of Molten Ba–Ge Alloys Using Electrostatic Levitation Technique Combined With High-Energy X-Ray Diffraction

High-energy synchrotron X-ray diffraction experiments were performed for clathrate-forming barium–germanium (Ba–Ge) alloys in the liquid state near the eutectic composition. The accurate structure information of highly reactive melts has been obtained by applying electrostatic levitation technique as a containerless method. The structure information obtained from the reverse Monte Carlo simulation suggests that the short-range ordering between the Ge atoms occurs with the addition of Ba atoms in the liquid Ba–Ge alloys. This can be associated with the formation of the cage-like structure composed of the Ge atoms in the liquid alloys near the eutectic composition.     

Molecular simulation for adsorption of chlorinated hydrocarbon in zeolites

Equilibrium and isosteric heat of adsorption for the system of chloroform and USY-type zeolite were studied. The USY-type zeolite (PQ Co., SiO₂/Al₂O₃=70) was used both as a pure crystalline powder and as granulated particles with binder. Chloroform was reagent grade. The adsorption equilibria were measured using a gravimetric method and were expressed as isotherms. A chromatographic method (i.e. pulse response of chloroform through the USY column with helium carrier) was used to get the initial slope of the isotherms. In the simulation, the GCMC method was used to calculate amounts adsorbed for various conditions. FF parameters were confidently applied. And modified structure model was effective for simulation. This paper was presented at The 5th International Symposium on Separation Technology-Korea and Japan held at Seoul between August 19 and 21, 1999.     

Unexpected discoveries and S-invention of design requirements: important vehicles for a design process

Designers, during a conceptual design process, do not just synthesize solutions that satisfy initially given requirements, but also invent design issues or requirements that capture important aspects of the given problem. How do they do this? What becomes the impetus for the invention of important issues or requirements? So-called ‘unexpected discoveries', the acts of attending to visuo-spatial features in sketches which were not intended when they were drawn, are believed to contribute to it. The purpose of the present research is to verify this hypothesis. Analysing the cognitive processes of a practising architect in a design session, we found that in about a half of his entire design process there were bi-directional relations between unexpected discoveries and the invention of issues or requirements. Not only did unexpected discoveries become the driving force for the invention of issues or requirements, but also the occurrence of invention, in turn, tended to cause new unexpected discoveries. This has provided empirical evidence for two anecdotal views of designing. First, designing is a situated act; designers invent design issues or requirements in a way situated in the environment in which they design. We call inventions of this sort situated-invention (S-invention). Secondly, a design process progresses in such a way that the problem-space and the solution-space co-evolve. Further, this has brought a pedagogical implication as well as an insight about an important aspect of learning by experience in design.     

Parallel processing of network calculations in order to speed up transient stability analysis

Power systems have become very large, and in addition the forthcoming open electricity market will make power system operation more complex. Therefore, power system operation must become more efficient and flexible. Very fast power system simulation is a means of achieving more sophisticated power system on‐line monitoring and control, and parallel computing is a key technology for very fast power system simulation. This paper proposes an efficient and fast parallel network calculation algorithm that will contribute to the development of fast power system simulation programs. Numerical examples show that the proposed method using six processors is about 4.0 times as fast as the usual serial algorithm when applied to a large‐scale radial power system and about 3.2 times as fast when applied to a large‐scale loop power system. © 2001 Scripta Technica, Electr Eng Jpn, 135(3): 26–36, 2001     

Poly(thienylenevinylene) prepared by ring-opening metathesis polymerization: Performance as a donor in bulk heterojunction organic photovoltaic devices

Poly(3,4-dioctylthienylenevinylene) (PDOTV) was synthesised by ring-opening metathesis polymerization (ROMP) with controlled molecular weight. PDOTV has been used to fabricate organic photovoltaic devices in combination with phenyl C₆₁-butyric acid methyl ester (PCBM) for the first time. The devices show power conversion efficiency up to 0.18%. Optimal device performance was found at a film thickness of 100 nm and a ratio of PCBM to PTV of 2:1. External quantum efficiency (EQE) measurements, transient absorption spectroscopy and morphology studies were carried out to establish factors governing photovoltaic performance. These results suggest that the efficiency values for the devices were limited by the hole mobility and unexpected phase separation within the blend. Nevertheless, the results show that ROMP is a viable, alternative, synthetic strategy for preparing PTV donors for use in bulk heterojunction OPVs.     

Conditional transformation of immunoglobulin mutation pattern from gene conversion into point mutation by controlling XRCC3 expression in the DT40 B cell line

A hypermutating B cell line DT40 is useful for screening antibodies and improving affinity of the selected antibodies in vitro. To perform affinity maturation efficiently, we generated an engineered DT40 line whose immunoglobulin mutation pattern can be transformed from gene conversion into point mutation by conditional suppression of XRCC3 expression.     

Structure of effective catalyst layers around bubbles in a fluidized catalyst bed

In a fluidized catalyst bed, the reactant gas transfers from the bubble phase to the emulsion phase and reactions proceed in the emulsion phase. The catalyst particles around the bubbles should contact the gases containing a high concentration of the reactants. Therefore, the effect of the catalysts around the bubbles is very important for estimating the conversion and selectivity in the reactor. In order to study the role of these catalysts, the hydrogenation of carbon dioxide was carried out in a fluidized catalyst bed. Based on the results, the amount of the catalyst that was effective for the reaction was calculated. In addition, the shape of the bubbles ascending in the fluidized catalyst bed was observed using a fast X-ray computer tomography (CT) scanner. The structure of the bubbles in the fluidized catalyst bed was very complicated and the surface area of the bubbles was much greater than the obtained when assuming spherical shaped bubble. By assuming that effective catalysts existed around the bubbles, the thickness of catalyst layer was obtained. Finally, the 3-dimensional images of the catalyst layers around the bubbles were reconstructed.