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81.
A simple and fast method to disperse long single-walled carbon nanotubes introducing few defects 总被引:1,自引:0,他引:1
A simple and fast dispersion method that incorporates heating is used to disperse long (more than 10 μm) single-walled carbon nanotubes (SWCNTs) with minimal defects. The method enables a dispersed solution of SWCNTs to be produced in less than 10 min in only three steps: (1) addition of the dispersant, (2) heating, and (3) grinding. The dispersion method does not require sonication, which shortens the SWCNTs and can generate surface defects. SWCNT films were prepared from the dispersed solution, and the films exhibited a resistance of 380 Ω/sq at a transparency of 64.8%. This dispersion method can be easily scaled up, making it useful for the preparation of dispersed SWCNTs for commercial and industrial applications. 相似文献
82.
Masaru Ogura Susumu Kage Masayoshi Hayashi Masahiko Matsukata Eiichi Kikuchi 《Applied catalysis. B, Environmental》2000,27(4):L213-L216
Effect of second components on the catalytic performance of Pd/H-ZSM-5 zeolite (Pd: 0.4 wt.%) was evaluated by a durability test of NO reduction with CH4 at a relatively high temperature of 500°C in the presence of water vapor for a prolonged period. The Pd/H-ZSM-5 showed high stable activity for this reaction without H2O in the reactant feed, while immediate and irreversible deactivation was observed in the presence of H2O, resulting in no activity after 7 h. The second components such as Co, Rh, Ag, Ce, and Fe introduced individually to the Pd/H-ZSM-5 enhanced the durability, and in particular the addition of 3.3 wt.% Co led to a stable NO conversion for more than 40 h in the presence of H2O. 相似文献
83.
Makoto Yoshinaga Shingo Katsuki Masaru Miyazaki Lijie Liu Shin‐Ichi Kihara Kazumori Funatsu 《Polymer Engineering and Science》2000,40(1):168-178
In recent years, twin screw extruders have been applied to various kinds of polymer processing. It has been important to find their optimum geometrical configurations and operational processing conditions for the best performance of extrusions and products. Many engineers have been evolving numerical and the experimental methods to characterize the mixing performance for twin screw extruders. We have carried out three‐dimensional flow simulations of kneading blocks in intermeshing co‐rotating twin screw extruders by using the finite element method to quantify their ability in distributive and dispersive mixing. We discuss their performance in distributive mixing for three different type of kneading blocks in terms of the residence time distribution and the nearest distance between markers at various periods of time, by using the marker tracking method. Those numerical techniques and applications of mixing indices have enabled us to quantify and evaluate their abilities in distributive mixing of kneading blocks in twin screw extruders. 相似文献
84.
Yoshinori Kawamura Kentaro Ochiai Tsuyoshi Hoshino Keitaro Kondo Yasunori Iwai Kazuhiro Kobayashi Masaru Nakamichi Chikara Konno Toshihiko Yamanishi Takumi Hayashi Masato Akiba 《Fusion Engineering and Design》2012,87(7-8):1253-1257
In a fusion reactor, the prediction of tritium release behavior from breeder blanket is important to design the tritium recovery system, but the amount of tritium generated is necessary information to do that. Hence, tritium generation and recovery studies on lithium ceramics packed bed have been started by using fusion neutron source (FNS) in Japan Atomic Energy Agency (JAEA). Lithium titanate (Li2TiO3) was selected as tritium breeding material, and its packed bed was enclosed by the beryllium blocks, and was kept at certain temperature during fusion neutron irradiation. During irradiation, the packed bed was purged with the sweep gas continuously, and tritium released was trapped in each gas absorber selectively by chemical form. In this work, the effect of sweep gas species on tritium release behavior was investigated. In the case of sweep by helium with 1% of hydrogen, tritium in water form was released sensitively corresponding to the irradiation. This is due to existence of the water vapor in the sweep gas. On the other hand, in the case of sweep by helium without water vapor, tritium in gaseous form was released first, and release of tritium in water form was delayed from gaseous tritium and was gradually increased. 相似文献
85.
Masaru Hoshiya Takaaki Nakamura Tomoya Mochizuki 《Canadian Metallurgical Quarterly》2004,130(7):780-785
Since cash flow of asset in the long run is generally subject to economic fluctuation, and also to potential damage due to seismic hazard risk, asset pricing is more relevantly evaluated, provided that uncertainties of both cash flow and seismic risk are properly taken into account. This study will propose a discounted cash flow method to evaluate asset pricing, in which incomes gained from asset are modeled as a Markov process and seismic loss is modeled due to only one earthquake event during the service time. A numerical example is demonstrated for an 11 story steel reinforced commercial building considering the service time of 50 years. Various risk–asset price curves are numerically obtained in the form of probability of excess versus asset price with discount rate as a parameter for cases with and without earthquake loss taken into account, and for a case in which earthquake strengthening measure is implemented. These curves contribute information to decision makers in charge of risk and investment management. 相似文献
86.
Masaru KuboKeisuke Ishiyama Atsushi ShimojimaTatsuya Okubo 《Microporous and mesoporous materials》2012,147(1):194-199
We investigate the hydrogen adsorption properties of periodic mesoporous organosilicas (PMOs) and focus, in particular, on how these properties are affected by diverse organic groups embedded in the walls. PMOs with π electrons on the pore surface adsorb more hydrogen molecules per unit area and have a higher isosteric heat of hydrogen adsorption (Qst). The number of adsorbed hydrogen molecules per unit area correlates well with the density of organic groups on the pore surface. We attribute the high Qst to the high polarizability of organic groups with π electrons, which enhances the dispersion force. The molecular order of organic groups affects the adsorption-site affinity to hydrogen molecules as well as the location of adsorption sites. For phenylene-bridged PMOs with crystal-like pore walls, Qst decreases rapidly with increasing hydrogen loading, which indicates two types of adsorption sites with different affinities to hydrogen molecules: one is an exposed CH bond and the other is a siloxane bond. However, Qst for phenylene-bridged PMOs with amorphous pore walls exhibits a moderate slope, which might be caused by the random order of organic groups; this results in several types of adsorption sites with various affinities. 相似文献
87.
88.
The motion of conservative 2D thermals on beds with slope angles θ ranging from 5 to 90° is investigated theoretically and experimentally. Using a large number of experimental data, important flow characteristics, including the shape factors, spatial growth rate, propagation speed, and entrainment coefficient, are quantified as functions of bottom slope angles. A thermal model, which includes a resistance term, is developed. It is found semiempirically that resistance coefficients Cd are almost independent of θ and the values of Cd are in the range of 0.4–0.6. Capability of the model is demonstrated by comparing numerical results with theoretical as well as experimental results. 相似文献
89.
90.