Determination of optical purity and absolute configuration of natural 12‐hydroxystearic acid by the 1H NMR anisotropy method

The enantiopure of (R)‐(?) MαNPA was allowed to react with racemic 18‐(tert‐butyldimethylsilyloxy)‐5‐octadecayne‐7‐ol which was derived from dodecane‐1,12‐diol, yielding diastereomeric esters mixture. These racemic esters were easily separated by HPLC on silica‐gel. The absolute configurations of the first‐eluted diastereomeric esters from the separated esters were determined using ¹H NMR anisotropy method. Analysis on ¹H NMR spectra and HPLC elution time of the synthesized esters and those of MαNP ester derived from natural methyl‐12‐hydroxystealate showed that the absolute configuration of natural 12‐hydroxystearic acid was R form, and the enantiomeric excess was over 99%.     

The influence of dopant species on thermal stability of NiSi film

We investigated the relationship between thermal stability of NiSi films and the implanted dopant species on Si substrates. The most stable NiSi layer appeared on Boron-implanted Si substrate, where the formation of pseudo-epitaxial transrotational structure was observed, just in case that the dose of boron is more than 5e15 atoms/cm². This unique crystallographic orientation of NiSi film on Boron-implanted substrate is a key role of thermal stability because thermal stress at grain boundary can be diminished by peculiar arrangement of transrotational domains, owing to the anisotropy in coefficient of thermal expansion (CTE) of NiSi.     

Kinetics of solid acid catalyzed 1-octene reactions with TiO2 in sub- and supercritical water

Acid catalyzed reactions of 1-octene on TiO₂ in sub- and supercritical water were investigated (T = 250-450 °C, P = 11-33 MPa). The main products were 2-octene and 2-octanol. Additionally, other liner C₈ alkenes and liner secondary C₈ alcohols were produced as by-products. Through kinetic analysis, acid catalyzed reactions can divide into the reaction catalyzed by Lewis acidic sites on TiO₂ and the reaction catalyzed by protons produced by the dissociation of water molecules. Each type of the reaction is affected by water density or ionic product of water, respectively, therefore, reaction mechanism changes with temperature and pressure. From the contribution of each reaction type, the temperature dependence of cis/trans ratio of produced 2-octene could also be explained.     

Extending image processing strain measurement system to evaluate fracture behavior of wall-thinned pipes

In this paper, an image processing strain measurement system was extended so that fracture behavior of wall-thinned pipes, such as out of plane and large plastic deformation observed in bulging, can be evaluated by the system. Regular grids with nominal size of 10 mm × 10 mm were marked on 100A carbon steel pipes and the images taken with 6 CCD cameras of 15 million pixels were correlated to achieve resolution of 0.3% strain. Strain of the cylinder's outer surface was evaluated by (1) modeling the grids as a cylindrical shell, (2) measuring deformation of the grid on a projected plane, and (3) applying an updated Lagrangian method. The validity of the system was confirmed by applying the proposed system to the burst tests of a wall-thinned cylinder. In addition, the system measured the non-uniform strain distribution that explained the unexpected cracking location.     

Improvement of mechanical properties of ferritic stainless steel weld metal by ultrasonic vibration

Authors investigated the effect of ultrasonic vibration on the solidification microstructure and mechanical properties of the weld metal of ferritic stainless steel by introducing directly ultrasonic vibration into the weld molten pool using ultrasonically vibrating filler metal. The main results obtained in this study are as follow.     

Fabrication and electrical properties of SrTiO3/diamond junctions

Strontium titanate (STO) films were directly deposited on Ib (100) single crystal diamond by r.f. magnetron sputtering. The as-deposited STO film was in amorphous state. On the other hand, the crystalline STO film was obtained under the optimized condition of a deposition temperature of 250 °C and a post-annealing temperature of 650 °C. STO/diamond junctions were fabricated on boron-doped homoepitaxial layers grown on p⁺-type single crystal diamond substrates. Electrical properties of the STO/diamond junction were investigated by changing the surface terminations of diamond with hydrogen or oxygen and the crystallinity of the STO film. It was found that the amorphous STO acted like a semi-insulator on H-diamond surface and that the amorphous STO/O-diamond junction behaved like a Schottky diode. The crystalline STO/O-diamond showed a complex rectifying behavior. The crystalline STO film possessed a higher dielectric constant as compared to that of the amorphous one.     

First results on U levels in global fallout

The global fallout ²³⁶U level in soil was deduced from measurements of ²³⁶U, ^239+240Pu and ¹³⁷Cs in surface soils which are solely influenced by global fallout. A total of 12 soil cores from the depths of 0-10, 0-20 and 0-30 cm were collected at a flat forest area in Japan. Concentrations of ^239+240Pu and ²³⁸U were determined by α-particle spectrometry, while the ²³⁶U/²³⁸U ratio was measured with accelerator mass spectrometry (AMS). Consistent ²³⁶U/²³⁹Pu ratios between 0.212 and 0.253 were found. Using this ratio, the total global fallout of ²³⁶U on the earth is estimated to be as much as ca. 900 kg. This knowledge will contribute to the promotion of research on U isotopes, including ²³⁶U, for the fields of geo-resources, waste management and geochemistry.