Soil hydraulic parameters estimated from satellite information through data assimilation

Leaf area index (LAI) and actual evapotranspiration (ET_a) from satellite observations were used to estimate simultaneously the soil hydraulic parameters of four soil layers down to 60 cm depth using the combined soil water atmosphere plant and genetic algorithm (SWAP–GA) model. This inverse model assimilates the remotely sensed LAI and/or ET_a by searching for the most appropriate sets of soil hydraulic parameters that could minimize the difference between the observed and simulated LAI (LAI_sim) or simulated ET_a (ET_asim). The simulated soil moisture estimates derived from soil hydraulic parameters were validated using values obtained from soil moisture sensors installed in the field. Results showed that the soil hydraulic parameters derived from LAI alone yielded good estimations of soil moisture at 3 cm depth; LAI and ET_a in combination at 12 cm depth, and ET_a alone at 28 cm depth. There appeared to be no match with measurement at 60 cm depth. Additional information would therefore be needed to better estimate soil hydraulic parameters at greater depths. Despite this inability of satellite data alone to provide reliable estimates of soil moisture at the lowest depth, derivation of soil hydraulic parameters using remote sensing methods remains a promising area for research with significant application potential. This is especially the case in areas of water management for agriculture and in forecasting of floods or drought on the regional scale.     

Updating geomorphic features of watersheds and their boundaries in hazardous areas using satellite synthetic aperture radar

Volcanic disasters can cause severe loss of human life and damage to property. The main damage is caused during an eruption and from subsequent erosion of deposited materials. Heavy rainfall in volcanic areas erodes volcanic deposits, mainly pyroclastic flows and ash fall deposits, which flow as lahar to the foothill of the mountain and cause drastic damage to economically important areas. This post-eruption disaster becomes complex due to the occurrence of stream captures and watershed breakouts that lead to devastating lahars. Continuous monitoring of such geomorphic and hydrologic changes is necessary to cope with changing hazard conditions. Therefore it is important to update the watershed boundaries in order to study current hazard conditions and develop mitigation plans for future disasters. Changes of geomorphic and watershed boundary have occurred in the Mayon Volcano in the Philippines mainly as a result of a major volcanic eruption of 1993, due to which mitigation structures were constructed and modified in the low lying areas. In this study interferometry was used to develop DEM from SAR data to delineate watershed boundaries. New lava flows, pyroclastic flows and lahar deposits in the watersheds were mapped using elevation changes, coherence and intensity derived from the SAR images. Updating geomorphic features of the watersheds and their boundaries using SAR provides a new weather independent alternative technique for monitoring the effect of volcanic activity.     

Esquentian of the mean by three stage procedure

Let X₁, X₂... be i.i.d. observations with mean μ and variance σ², and suppose that given a sample of size n one wishes to estimate μ by X_n, subject to the loss function L_n= A²(X_n-μ)²+n. When σ² is unknown, the optimal sample size n₀ for minimizing the risk R_n = E{L_n} cannotbe found. To resolve this problem, Robbins (1959) proposed a sequential procedure whenX_i is normally distributed, and then the asymptotic properties have been extensively studied. In this paper, we apply Hall's three stage procedure to the problem without specifying the distribution of X_i and derive the second order asymptotic expansions of the expected sample size and the risk.     

sequential estimation of the hgarginal density function for a strongly mixing process

Suppose that {X_n} is a strongly mixing process with unknow marginal density f(x) and that we estimate f(x) by a kernel estimator [fcirc]_n(x|h_n)and want to achive the MISE no larger than some preassigned postive number w. However,the appropriate sample size n^*depends on a functional of the unknow density function. Therefore some sequential procedure is required and we adopt a fully sequential procedure. In this paper we investigate the asymptotic properties of the procedure and show that the producure is asymptotically efficient in a certain sense as w→0. The results are almost the same in the i.i.d. setting. our result extend a class of models to which the methodology can be applied. For example economic variable,experiments on a single subject in which obervation are not indepent, and so on.     

High-temperature pyrolysis of ceramic fibers derived from polycarbosilane–polymethylhydrosiloxane polymer blends with porous structures

The polymer blends of PCS (polycarbosilane) and PMHS-h (polymethylohydrosiloxane with high molecular weight) were prepared by freeze-drying process of mixed benzene solution. Melt viscosity, mass loss, and gas evolution from prepared polymer blends were analyzed. A polymer blend of HSah15 (15 mass% PMHS-h to PCS) was melt-spun to fiber form, curing by thermal oxidation and pyrolyzed at various temperatures up to 1773 K. The obtained fibers were investigated by tensile tests, FE-SEM (field emission scanning electron microscope) observation, and XRD (X-ray diffraction) analysis. After pyrolysis at 1273 K, there were no pores in the cross section of the fiber derived from pure PCS; however, there were amounts of pores in the cross sections of the fiber derived from HSah15. After pyrolysis at 1773 K, the coarse β-SiC (silicon carbide) crystals were formed on the outside surface of the fiber derived from pure PCS; however, no remarkable β-SiC crystal were formed on the outside surface of the fiber derived from HSah15.     

Destruction of volatile organic compounds used in a semiconductorindustry by a capillary tube discharge reactor

Nonthermal plasma technologies offer an innovative approach to the problem of decomposing various volatile organic compounds (VOCs). The authors focused on DC capillary tube discharge plasma reactors to study the decomposition/destruction efficiency for toluene, EGM, trichloroethane and trichloroethylene at 50-2300 ppm levels in dry air. The effects of gas flow rate, VOC concentration and reactor operating conditions on decomposition and analysis of reactant conversion for each VOC were investigated. The results show that VOC destruction efficiency as high as 90% can be achieved, even under a short residence time (3.8 ms) with a destruction energy efficiency of up to 95 g (VOC)/kWh. Laboratory-scale plasma technology was successfully demonstrated for its potential application for VOC control in the semiconductor clean-room environment     

Remarkable enhancement in durability of Pd/H-ZSM-5 zeolite catalysts for CH4-SCR

Effect of second components on the catalytic performance of Pd/H-ZSM-5 zeolite (Pd: 0.4 wt.%) was evaluated by a durability test of NO reduction with CH₄ at a relatively high temperature of 500°C in the presence of water vapor for a prolonged period. The Pd/H-ZSM-5 showed high stable activity for this reaction without H₂O in the reactant feed, while immediate and irreversible deactivation was observed in the presence of H₂O, resulting in no activity after 7 h. The second components such as Co, Rh, Ag, Ce, and Fe introduced individually to the Pd/H-ZSM-5 enhanced the durability, and in particular the addition of 3.3 wt.% Co led to a stable NO conversion for more than 40 h in the presence of H₂O.     

Pyrrolizidine Alkaloids Mediate Host-Plant Recognition by Ovipositing Females of an Old World Danaid Butterfly, Idea leuconoe

A giant danaid butterfly, Idea leuconoe, specializes on apocynaceous plants such as Parsonsia laevigata, which has been reported to contain pyrrolizidine alkaloids. Females of I. leuconoe deposited eggs in response to methanolic extract of P. laevigata, and subsequent bioassay-guided fractionation of the extract revealed that phytochemicals crucial for host recognition by ovipositing females are Parsonsia-specific macrocyclic pyrrolizidine alkaloids including parsonsianine, parsonsianidine, and 17-methylparsonsianidine. Parsonine, another P. laevigata pyrrolizidine component with a keto-dihydropyrrolizine moiety that is closely related in structure to male pheromones of the butterfly, and several nonhost pyrrolizidine alkaloids were entirely inactive. We interpret these data as strong evidence for an ancestral association through herbivory between danaid butterflies and pyrrolizidine alkaloids.     

A simple approach to observe non-conductive hydrated materials with FE-SEM: Case study on porous hydroxyapatite green bodies

The purpose of this study is to develop a simple method to observe the surface morphology of non-conductive material in its hydrated condition. Here porous hydroxyapatite (HAp) green body prepared by gelcasting process was considered as a case study, and, the resultant body was subsequently treated with hydrophilic ionic liquid (IL). The surface morphology and the pore structure of the IL-treated porous HAp green body were successfully observed even in hydrated condition without any charging using field emission scanning electron microscope (FE-SEM). Results showed that the pore diameter from 300 to 600 μm in as-prepared green body was reduced to 100–300 μm in the sample sintered at 1000 °C. Raman results showed that the IL forms weak hydrogen bond with water molecules within the sample and, that prevents from drying in vacuum condition. In addition, the IL acts as a conducting media for HAp ceramics to be observed under FE-SEM.