Copper-Tungsten Composites Sprayed by HVOF

Copper and copper-tungsten composite coatings were produced by high-velocity oxy-fuel spraying (HVOF). After initial optimization of the spraying parameters, coatings of various compositions were made and their structure, composition, mechanical, thermal, and electrical properties were characterized. The HVOF technique was able to produce rather dense coatings with minimal oxide content and relatively good mechanical and thermal properties compared to, for example, plasma-sprayed coatings; however, the achieved tungsten content was quite low.     

Thermoeconomic optimization for a finned‐tube evaporator configuration of a roof‐top bus air‐conditioning system

This paper presents a methodology of a design optimization technique that can be useful in assessing the best configuration of a finned‐tube evaporator, using a thermoeconomic approach. The assessment has been carried out on a direct expansion finned‐tube evaporator of a vapor compression cycle for a roof‐top bus air‐conditioning (AC) system at a specified cooling capacity. The methodology has been conducted by studying the effect of some operational and geometrical design parameters for the evaporator on the entire cycle exergy destruction or irreversibility, AC system coefficient of performance (COP), and total annual cost. The heat exchangers for the bus AC system are featured by a very compact frontal area due to the stringent space limitations and structure standard for the system installation. Therefore, the current study also takes in its account the effect of the variation of the design parameters on the evaporator frontal area. The irreversibility due to heat transfer across the stream‐to‐stream temperature difference and due to frictional pressure drops is calculated as a function of the design parameters. A cost function is introduced, defined as the sum of two contributions, the investment expense of the evaporator material and the system compressor, and the operational expense of AC system that is usually driven by an auxiliary engine or coupled with the main bus engine. The optimal trade‐off between investment and operating cost is, therefore, investigated. A numerical example is discussed, in which a comparison between the commercial evaporator design and optimal design configuration has been presented in terms of the system COP and evaporator material cost. The results show that a significant improvement can be obtained for the optimal evaporator design compared with that of the commercial finned‐tube evaporator that is designed based on the conventional values of the design parameters. Copyright © 2007 John Wiley & Sons, Ltd.     

Study on transient heat transfer through multilayer thermal insulation: Numerical analysis and experimental investigation

This paper reports on a numerical and experimental study of heat transfer phenomena through two different multilayer fibrous insulations for building applications. The investigated samples were composed of different layers of fibrous materials and aluminium foils, placed between one or two air gaps in the vertical dimension. An experimental apparatus (a guarded hot box) has been used to measure heat transfer through the samples, while a finite volume numerical model combined radiation/conduction heat transfer was developed to predict the temperature distribution and heat transfer in such insulation systems comprised of the materials separated by multiple reflective foils. The model takes into account the coupling between the solid conduction of the fibrous system and the gaseous conduction and radiation. The radiation heat transfer through the insulation system has been modelled via the two flux approximation. The numerical results were compared with the experimental data from the guarded hot box for model validation, as well as to assess the effectiveness of the reflective foils in changing the resistance of the insulations. The comparative verification of the model showed that the numerical results were consistent with the experimental data through the environmental conditions under examination.     

Flammability and mechanical properties of wood flour‐filled polypropylene composites

Polypropylene (PP) composites filled with wood flour (WF) were prepared with a twin‐screw extruder and an injection‐molding machine. Three types of ecologically friendly flame retardants (FRs) based on ammonium polyphosphate were used to improve the FR properties of the composites. The flame retardancy of the PP/WF composites was characterized with thermogravimetric analysis (TGA), vertical burn testing (UL94‐V), and limiting oxygen index (LOI) measurements. The TGA data showed that all three types of FRs could enhance the thermal stability of the PP/WF/FR systems at high temperatures and effectively increase the char residue formation. The FRs could effectively reduce the flammability of the PP/WF/FR composites by achieving V‐0 UL94‐V classification. The increased LOI also showed that the flammability of the PP/WF/FR composites was reduced with the addition of FRs. The mechanical property study revealed that, with the incorporation of FRs, the tensile strength and flexural strength were decreased, but the tensile and flexural moduli were increased in all cases. The presence of maleic anhydride grafted polypropylene (MAPP) resulted in an improvement of the filler–matrix bonding between the WF/intumescent FR and PP, and this consequently enhanced the overall mechanical properties of the composites. Morphological studies carried out with scanning electron microscopy revealed clear evidence that the adhesion at the interfacial region was enhanced with the addition of MAPP to the PP/WF/FR composites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Super/subcritical fluid extractions for preparation of the crystalline titania

Various extraction techniques which use fluids in super/subcritical state (CO₂, H₂O, CH₃OH) were used for the preparation of crystalline TiO₂ from surfactant-mediated titania organogels (the amorphous reaction intermediate products of surfactant-mediated sol-gel synthesis). Crystallinity, purity and texture of TiO₂ powders (titania aerogels) were studied in detail for different treatment modes of titania organogels. Suitable combinations of extraction solvents and extraction temperature and pressure were considered for synthesis of TiO₂ powder crystalline phase (anatase) with high specific surface area and purity (carbon content < 0.1 wt.%). Optimum results were achieved by combined extraction procedures—subcritical water extraction and supercritical fluid extraction or pressurised liquid extraction. Moreover, the possible tuning of the TiO₂ powder pore-size distribution by regulation of temperature at constant pressure for the combined subcritical water extraction and pressurised liquid extraction was found.     

Thermophysical properties of medium grain rough rice (<Emphasis Type="Italic">LIDO cultivar</Emphasis>) at medium and low temperatures

Bulk density, specific heat capacity, bulk thermal conductivity and bulk thermal diffusivity of medium-grain rough rice (LIDO cultivar) have been studied. Specific heat was determined by DSC, thermal conductivity by the probe method and bulk thermal conductivity indirectly from bulk density, specific heat capacity and bulk thermal conductivity. All the thermal properties have been determined at different moisture contents and temperatures used during cooling and storage operations and the effect of these variables has been investigated. It has been shown that moisture content has the greatest effect on specific heat and bulk thermal conductivity. Temperature also affected these thermal properties, but to a smaller extent. Mathematical expressions have been developed to determine each of these thermophysical properties as a function of moisture content and temperature.List of Abbreviations and Symbols C_p Specific heat capacity (kJ/kg °C) - k Bulk thermal conductivity (W/m °C) - T Temperature (ºC) - W Moisture content (%, d.b.) - Bulk thermal diffusivity (m²/s) - Bulk density (kg/m³)     

Physico-chemical properties of various palm-based diacylglycerol oils in comparison with their corresponding palm-based oils

Palm-based diacylglycerol (P-DAG) oils were produced through enzymatic glycerolysis of palm kernel oil (PKO), palm oil (PO), palm olein (POL), palm mid fraction (PMF) and palm stearin (PS). High purity DAG (83–90%, w/w) was obtained and compared to palm-based oils (P-oil) had significantly (P < 0.05) different fatty acid composition (FAC), iodine value (IV) and slip melting point (SMP). Solid fat content (SFC) profiles of P-DAG oils as compared to P-oils had less steep curves with lower SFC at low temperature range (5–10 °C) and the higher complete melting temperatures. Also, P-DAG oils in contrast with P-oils showed endothermic as well as exothermic peaks with higher transition temperatures and significantly (P < 0.05) higher crystallisation onsets, heats of fusion, and heats of crystallisation. Crystal forms for P-DAG oils were mostly in the β form.     

Analysis of Lard’s Aroma by an Electronic Nose for Rapid <Emphasis Type=Italic>Halal</Emphasis> Authentication

An electronic nose was successfully used to detect and discriminate lard from other types of animal body fats and samples containing lard. The results are presented in the form of VaporPrint™, the image of the polar plot of the odor amplitudes from the surface acoustic wave (SAW) detector frequency. In the VaporPrint™, the radial angles representing the sensor provides individual fingerprints of the aroma of different animal body fats. Principal component analysis (PCA) was used to interpret the data and it provided a good grouping of samples, with 61% of the variation accounted for by PC 1 and 29% accounted for by PC 2. All of the lard-containing samples formed a separate group from the samples that were free from lard. This method can be developed into a rapid method for detecting the presence of lard in food samples for Halal authentication.     

Multisensor Fusion: An Autonomous Mobile Robot

A conventional autonomous mobile robot is introduced. The main idea is the integration of many conventional and sophisticated sensor fusion techniques, introduced by several authors in recent years. We show the actual possibility of integrating all these techniques together, rather than analyzing implementation details. The topics of multisensor fusion, observation integration and sensor coordination are widely used throuhout the article. The final goal is to demonstrate the validity of both mathematical and artificial intelligence techniques in guaranteeing vehicle survival in a dynamic environment, while the robot carries out a specific task. We review conventional techniques for the management of uncertainty while we describe an implementation of a mobile robot which combines on-line heterogeneous sensors in its navigation and localisation tasks.     

Application of native and phosphorylated tapioca starches in potato starch noodle

Summary Characteristics of potato starch noodles substituted with native, phosphorylated and commercial phosphorylated (MTS283) tapioca starches were evaluated. Substitution of up to 17% with phosphorylated tapioca starch or up to 35% with MTS283 improved the quality of potato starch noodles. The resulting noodles were transparent and less brittle when uncooked, and were moderately elastic, less sticky and experienced lower cooking loss and less swelling when cooked. Substitution with native tapioca starch of up to 17% was also possible, but the uncooked noodles were less transparent and the cooked noodles swelled more and were less elastic.