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61.
Density functional calculations and minimization techniques have been employed to characterize the structural and electronic properties of [5,6]-heterofullerene-C58Si-C2v. Since it has odd number of atoms and a near planar tetracoordinate Si atom on the skeleton of the cage, it has odd number of atoms assembling a cage and is a novel molecule. Vibrational frequencies of the molecule have been calculated at the B3LYP/6-31G* level of theory. The absence of imaginary vibrational frequency confirms that the molecule corresponds to a true minimum on the potential energy hypersurface. Sixteen 13C nuclear magnetic resonance (NMR) spectral signals of C58Si are characterized, and its heat of formation was estimated in this work. 相似文献
62.
Das S. Abraham A. Konar A. 《IEEE transactions on systems, man, and cybernetics. Part A, Systems and humans : a publication of the IEEE Systems, Man, and Cybernetics Society》2008,38(1):218-237
Differential evolution (DE) has emerged as one of the fast, robust, and efficient global search heuristics of current interest. This paper describes an application of DE to the automatic clustering of large unlabeled data sets. In contrast to most of the existing clustering techniques, the proposed algorithm requires no prior knowledge of the data to be classified. Rather, it determines the optimal number of partitions of the data "on the run." Superiority of the new method is demonstrated by comparing it with two recently developed partitional clustering techniques and one popular hierarchical clustering algorithm. The partitional clustering algorithms are based on two powerful well-known optimization algorithms, namely the genetic algorithm and the particle swarm optimization. An interesting real-world application of the proposed method to automatic segmentation of images is also reported. 相似文献
63.
This article is about testing the equality of several normal means when the variances are unknown and arbitrary, i.e., the set up of the one-way ANOVA. Even though several tests are available in the literature, none of them perform well in terms of Type I error probability under various sample size and parameter combinations. In fact, Type I errors can be highly inflated for some of the commonly used tests; a serious issue that appears to have been overlooked. We propose a parametric bootstrap (PB) approach and compare it with three existing location-scale invariant tests—the Welch test, the James test and the generalized F (GF) test. The Type I error rates and powers of the tests are evaluated using Monte Carlo simulation. Our studies show that the PB test is the best among the four tests with respect to Type I error rates. The PB test performs very satisfactorily even for small samples while the Welch test and the GF test exhibit poor Type I error properties when the sample sizes are small and/or the number of means to be compared is moderate to large. The James test performs better than the Welch test and the GF test. It is also noted that the same tests can be used to test the significance of the random effect variance component in a one-way random model under unequal error variances. Such models are widely used to analyze data from inter-laboratory studies. The methods are illustrated using some examples. 相似文献
64.
65.
Considerations of metropolitan commuting have often related to urban space as a continuum, and to commuting itself as a process. This approach has led to escalating complexity in the measurement, modeling and analysis of commuting, often with no commensurate results. The present study extends an alternative approach that considers commuter space of a metropolis as a discrete set of small areas. Each small area throughout the metropolis is a nighttime location of some households and, as a possible discrete destination choice of individuals within households, each subarea is also a daytime location of some persons. Each subarea, therefore, may be thought of as attaining two values, corresponding to its daytime (e.g., noontime) and nighttime (e.g., midnight) populations. The diurnal demographic shift of subareas, as a set of binary events, or toggles, between daytime and nighttime populations, is associated with commuter access throughout the metropolis. Diurnal shift offers structural simplicity aimed at estimating small-area daytime populations across a metropolitan region that might suitably precede and complement conventional continuum considerations of commuting. Using data for the Tokyo Metropolitan Region, we identify average household size as the nighttime indicator of small-areas, and daytime population density as their daytime indicator. The potential for the estimation of daytime populations across metropolitan regions where daytime population data are unavailable, is underscored by the clear tendency towards inverse relation of these two indicators of diurnal shift. 相似文献
66.
We consider conditionals of the form A ? B where A depends on the future and B on the present and past. We examine models for such conditional arising in Talmudic legal cases. We call such conditionals contrary to time conditionals. Three main aspects will be investigated:
- Inverse causality from future to past, where a future condition can influence a legal event in the past (this is a man made causality).
- Comparison with similar features in modern law.
- New types of temporal logics arising from modelling the Talmudic examples.
67.
Javier Irizarry Katy L. Simonsen Dulcy M. Abraham 《Canadian Metallurgical Quarterly》2005,131(12):1310-1319
In spite of the efforts by government agencies, labor organizations, and researchers in the field of health and safety, injuries and fatalities continue to affect the construction industry. In 2002 the construction industry had the undesirable distinction of having two of the most dangerous occupations in the United States, with fatalities among structural steel workers at 58.2 per 100,000 workers (fourth highest rate) and among construction laborers at 27.7 per 100,000 workers (ninth highest rate). Costs associated with construction accidents, such as increased insurance premiums and medical expenses, and loss of productivity are also concerns in the industry. It has not been demonstrated how unsafe working conditions affect worker performance, and the impact of unsafe work practices on worker performance has not been quantified. This paper describes a methodology that included direct observation of steel erection activities and statistical analysis of task duration data. The data collected at steel erection sites included safety conditions such as the use of personal protective equipment (PPE), elevation of the work area, environmental conditions such as temperature and humidity, and worker performance in the form of task durations. Analysis of variance (ANOVA) analysis of 186 of steel erection task durations collected over a six-month period showed that the use of personal protective equipment (PPE), the time of day during which the operation was being performed, the elevation at which the work was being performed, and the presence of decking below the work area had statistically significant effects on the durations of steel erection tasks. 相似文献
68.
Rat strain differences in the acoustic startle response (ASR) and prepulse inhibition (PPI) of that response are of increasing interest, especially as the genetics of PPI may provide an approach to studying the genetics of certain mental illnesses. However, strain differences in PPI are confounded by differences in ASR. To clarify this issue, the authors investigated the ASR and PPI across a range of startling stimulus intensities (70 dB-120 dB) in Wistar and Sprague-Dawley rats (N=96). Sprague-Dawleys showed more PPI of ASR capacity (response limit) than Wistars. In contrast, Wistars exhibited greater PPI than Sprague-Dawleys, as measured by an increase in response threshold. This dissociation suggests that PPI is more complex than that assessed by single startling stimulus intensity. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
69.
Kahana Michael J.; Rizzuto Daniel S.; Schneider Abraham R. 《Canadian Metallurgical Quarterly》2005,31(5):933
This article addresses the relation between item recognition and associative (cued) recall. Going beyond measures of performance on each task, the analysis focuses on the degree to which the contingency between successful recognition and successful recall of a studied item reflects the commonality of memory processes underlying the recognition and recall tasks. Specifically, 4 classes of distributed memory models are assessed for their ability to account for the relatively invariant correlation (≈ .5) between successive recognition and recall. Basic versions of each model either under- or overpredict the intertask correlation. Introducing variability in goodness-of-encoding and response criteria, as well as output encoding, enabled all 4 models to reproduce the moderate intertask correlation and the increase in correlation observed in 2 mixed-list experiments. This model-based analysis provides a general theoretical framework for interpreting contingencies between successive memory tests. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
70.
The basic operations of fuzzy sets, such as negation, intersection, and union, usually are computed by applying the one‐complement, minimum, and maximum operators to the membership functions of fuzzy sets. However, different decision agents may have different perceptions for these fuzzy operations. In this article, the concept of parameterized fuzzy operators will be introduced. A parameter α will be used to represent the degree of softness. The variance of α captures the differences of decision agents' subjective attitudes and characteristics, which result in their differing perceptions. The defined parameterized fuzzy operators also should satisfy the axiomatic requirements for the traditional fuzzy operators. A learning algorithm will be proposed to obtain the parameter α given a set of training data for each agent. In this article, the proposed parameterized fuzzy operators will be used in individual decision‐making problems. An example is given to show the concept and application of the parameterized fuzzy operators. © 2003 Wiley Periodicals, Inc. 相似文献