Oxidation of formic acid at a high surface area supported platinum modified by foreign metal adatoms

The anodic oxidation of formic acid was studied on platinum distributed in the form of small particles in a porous substrate modified by metal adatoms deposited at underpotentials. The rate of the reaction was greatly enhanced on the commercial catalyst Powercat 3000 (PC 3000). The hydrogen adsorption and the underpotential deposition of several metals at PC 3000 were shown to be dissimilar to that at smooth polycrystalline Pt. Steady-state and long-term experiments were performed to determine the stability of this electrode.     

Mechanical and fracture behavior of powder metalurgy processed Ti3Al-based alloys

This work considers structural and compression mechanical properties of three Ti₃Al-based alloys processed by powder metallurgy. Mechanically alloyed powders were compacted by hot-pressing to non-porous homogenous compacts. Prior to compression tests, all compacts were homogenized by a solution treatment at 1050°C (α + β region) for 1h, followed by water quenching. The compression tests were performed from room temperature to 500°C in vacuum at a strain rate of 2.4 × 10⁻³ s⁻¹. Detailed microstructural characterization has been evaluated by scanning electron microscopy (SEM), followed by electron dispersive spectroscopy (EDS) and X-ray diffraction analysis. Fracture topography was examined by SEM. The Ti₃Al-Nb alloy exhibits the highest ductility in the whole temperature range, whereas addition of Mo to Ti₃Al-Nb alloy yields the highest ultimate compression strength. A correlation between ductility and the fracture mode exists for all materials.     

Statistical Properties of Transition Amplitudes in Generic Systems

I review some recent results on the statistical properties of matrix elements of typical observables (transition amplitudes) in an eigenbasis of generic quantum Hamiltonian systems. The classical limit of an underlying system can be either integrable, or fully chaotic, or mixed with regular and irregular regions coexisting in phase space. In any case, the variance of transition amplitudes (the local average transition probability) as a function of energy and transition frequency can be calculated in terms of classical power spectra. The probability distribution of transition amplitudes in high energy (semiclassical) regime is derived by means of random matrix theory, whereas in low and intermediate energy (nonsemiclassical) regime the probability distribution of transition amplitudes exhibits universal exponential tails which still call for theoretical explanation.     

Stereometric analysis of nanostructured boehmite coatings synthesized by aluminum nitride powder hydrolysis

We studied the morphological properties of precipitated, nanostructured, boehmite coatings on a polished alumina surface by exploiting the aluminum nitride (AlN) powder hydrolysis at elevated temperatures. The hydrolysis tests of the 3 wt% AlN powder suspensions in the temperature range 50–90 °C were performed in order to estimate the time needed for the synthesis of the coatings. They consisted of interlocked boehmite lamellas, positioned perpendicularly to the ceramic surface, and they exhibited a strong temperature-dependent size and surface density. The aim of this research was a quantitative assessment of the as-formed boehmite coatings. Based on electron microscopy micrographs, a stereometric analysis of the as-prepared coatings was performed in order to estimate the relevant geometric parameters of the lamellas. In spite of the temperature-dependent lamellas’ size and surface density, the specific volume of the coatings was similar for all the synthesis temperatures.     

Foveation-based content adaptive root mean squared error for video quality assessment

Multimedia Tools and Applications - When the video is compressed and transmitted over heterogeneous networks, it is necessary to ensure the satisfying quality for the end user. Since human...     

Influence of high power ultrasound on physical–chemical properties of polypropylene films aimed for food packaging: barrier and contact angle features

Investigation was focused on the impact of high power ultrasound (HPUS), also called thermosonication, on the oxygen permeation properties (permeability, solubility and diffusion coefficients) of barrier films aimed for food packaging. For this purpose, biaxially oriented polypropylene (BOPP) coated with acrylic/polyvinylidene chloride (BOPPAcPVDC) and biaxially oriented coextruded polypropylene (BOPPcoex) were used. The physical–chemical profile of the samples was determined using goniometry. There is a significant impact only of extreme HPUS conditions (the longest time and the highest amplitude) on the permeability, solubility and diffusion coefficients of oxygen through the BOPP films. The highest influence on the oxygen permeability in both investigated BOPP samples involved an HPUS with an amplitude of 100% during a 6 min treatment. However, BOPP samples showed different sensitivities at lower HPUS treatments. © 2017 Society of Chemical Industry     

Harvesting of river flow energy for wireless sensor network technology

River courses play a vital role in preserving unpolluted ecosystems. On the other hand, networks of sensor nodes can be used to measure characteristic parameters in the environment such as temperature, pressure, humidity or the concentration of pollutants. In the framework of the EU FP7 project “GOLDFISH”, technical competences of a consortium of 11 institutions are hence employed in designing, manufacturing, validating and operating wireless sensors nodes for tracking pollution in remote rivers. The sensor network is composed of sensor clusters located underwater and gateways on the riverbank with long-distance communication links to the central management and monitoring station. Each sensor node is composed of active electronic devices that have to be constantly powered. Batteries can generally be used for this purpose, but problems may occur when they are to be recharged or replaced, especially in the case of large networks placed in scarcely accessible locations. State-of-the-art energy harvesting technologies can hence constitute a viable powering solution. The possibility to use different small-scale river flow energy harvesting principles is thoroughly studied in this work by the University of Rijeka GOLDFISH team: a miniaturized hydro-generator, a ‘piezoelectric eel’ and a hybrid solution of a rotating shaft plucking a piezoelectric beam. The first two concepts are validated experimentally in a flow channel and in real river conditions. The miniaturized hydro-generator with suitable power management electronics is finally embedded into the wireless sensor node deployed into the river, allowing the GSM transmission of collected data to be successfully performed.     

Surface Defects on Semicoherent and Incoherent NaCl-Type Carbides Dispersed in Hot-Rolled Ferritic Steel

Metallurgical and Materials Transactions A - The interface structure of semicoherent titanium carbide (TiC) nanoparticles and incoherent micron-sized TiC precipitates in Fe–C–Ti alloy...