Spectroscopic studies and first-principles modelling of 2,2,4-trifluoro-5-trifluoromethoxy-1,3-dioxole (TTD) and TTD-TFE copolymers (Hyflon AD)

Amorphous fluorinated optical polymers, characterized by high transparency in the visible and near infrared spectra, high glass transition temperature and very good resistance to chemical environment, have been developed by co-polymerisation of tetrafluoroethylene (TFE) and 2,2,4-trifluoro-5-trifluoromethoxy-1,3-dioxole (TTD). In this work we study at molecular level the effect of the introduction of the bulky TTD unit in a perfluoroalkyl chain.In particular the effect on the molecular structure and chain flexibility is investigated and spectroscopic markers correlated to chemical and structural defects are identified. The study includes a thorough experimental spectroscopic analysis (infrared and Raman spectra) of several different copolymer samples and a modelling based on Density Functional Theory calculations and semiempirical calculations on suitable model molecules.     

Characterization of microstructured optical fibers for wideband dispersion compensation

Microstructured optical fibers (MOFs) with small hole-to-hole spacing and large airholes are designed to compensate the anomalous dispersion and the dispersion slope of single-mode fibers. The geometrical parameters that characterize triangular MOFs are chosen to optimize the fiber length and the compensation over a wide wavelength range. A proper design of the photonic crystal fiber geometry allows us to achieve dispersion values of approximately -1700 ps nm(-1) km(-1) at 1550 nm and to compensate the dispersion of standard fibers within +/- 0.5 ps nm(-1) km(-1) over a 100-nm range. The MOF dispersion properties have been studied by means of a numerical simulator for modal analysis based on the finite-element method.     

Assessing the health research’s social impact: a systematic review

Scientometrics - In recent year, a growing attention is dedicated to the assessment of research’s social impact. While prior research has often dealt with results of research, the last decade...     

Plasmon hybridization engineering in self-organized anisotropic metasurfaces

Nano Research - The engineering of self-organized plasmonic metasurfaces is demonstrated using a maskless technique with defocused ion-beam sputtering and kinetically controlled deposition. The...     

Co-loading of a photostabilizer with the sunscreen agent, butyl methoxydibenzoylmethane in solid lipid microparticles

The sunscreen agent, butyl methoxydibenzoylmethane (BMDBM), one of the most widely used UV-A filter, undergoes decomposition under sunlight exposure, which is a limiting factor on its overall performance. To reduce the sunscreen photodegradation, this study investigates the incorporation into solid lipid microparticles (SLMs) of BMDBM together with the photostabilizer, 4-methylbenzylidene camphor (MBC). The microparticles were produced by the melt dispersion technique using various lipid materials (tristearin, glyceryl behenate, and stearic acid) and hydrogenated phosphatidylcholine as the surfactant. The highest retention capacity for BMDBM and MBC was achieved with tristearin microparticles. These SLMs were characterized by scanning electron microscopy and powder X-ray diffraction analyses. The BMDBM and MBC loading was 10.4 and 10.1%, respectively. The efficacy of the SLMs was evaluated after their introduction in a conventional cream (oil-in-water emulsion). The light-induced decomposition of BMDBM was decreased by encapsulation into the SLMs (the extent of degradation was 33.8 +/- 5.5% for unencapsulated BMDBM/MBC and 25.3 +/- 4.2% for BMDBM-loaded microparticles in conjunction with free MBC). Moreover, the co-loading of the MBC stabilizer in the SLMs produced a further reduction of the photodegradation of the UV-A filter (the BMDBM loss was 16.9 +/- 5.9%) compared with the microparticles containing BMDBM without MBC. Therefore, incorporation in lipid microparticles of BMDBM together with the MBC photostabilizer is more effective in enhancing the UV-A filter photostability than the SLMs loaded with BMDBM alone.     

Smart consumer load balancing: state of the art and an empirical evaluation in the Spanish electricity market

The basis of an efficient functioning of a power grid is an accurate balancing of the electricity demand of all the consumers at any instant with supply. Nowadays, this task involves only the grid operator and retail electricity providers. One of the facets of the Smart Grid vision is that consumers may have a more active role in the problem of balancing demand with supply. With the deployment of intelligent information and communication technologies in domestic environments, homes are becoming smarter and able to play a more active role in the management of energy. We use the term Smart Consumer Load Balancing to refer to algorithms that are run by energy management systems of homes in order to optimise the electricity consumption, to minimise costs and/or meet supply constraints. In this work, we analyse different approaches to Smart Consumer Load Balancing based on (distributed) artificial intelligence. We also put forward a new model of Smart Consumer Load Balancing, where consumers actively participate in the balancing of demand with supply by forming groups that agree on a joint demand profile to be contracted in the market with the mediation of an aggregator. We specify the business model as well as the optimisation model for load balancing, showing the economic benefits for the consumers in a realistic scenario based on the Spanish electricity market.     

Tags for Multi-Protocol Authentication

Formal methods have been proved successful in analyzing different kinds of security protocols. They typically formalize and study the security guarantees provided by cryptographic protocols, when executed by a (possibly unbounded) number of different participants. A key problem in applying formal methods to cryptographic protocols, is the study of multi-protocol systems, where different protocols are concurrently executed. This scenario is particularly interesting in a global computing setting, where several different security services coexist and are possibly combined together. In this paper, we discuss how the tagging mechanism presented in [M. Bugliesi, R. Focardi, and M. Maffei. Compositional analysis of authentication protocols. In Proceedings of European Symposium on Programming (ESOP 2004), volume 2986 of Lecture Notes in Computer Science, pages 140–154. Springer-Verlag, 2004, M. Bugliesi, R.Focardi, and M.Maffei. A theory of types and effects for authentication. In ACM Proceedings of Formal Methods for Security Engineering: from Theory to Practice (FMSE 2004), pages 1–12. ACM Press, October 2004] addresses this issue.     

Sensitivity Analysis and Model Validation of a 2-DoF Mini Spherical Robot

This paper is focused on the development and validation of an error kinematic model of a mini spherical robot, aimed at its kinematic calibration. The robot is actually a spatial five-bar linkage, provided with two rotational degrees of freedom. A non-overconstrained kinematics is assumed for the robot in order to provide a simple mathematical model and allow a sensitivity analysis of all the involved geometric parameters. A simplified version of the model is proposed. It differs only for the degree of approximation. A comparison between full and reduced models is presented by means of numerical simulations, analyzing their behavior in a significant region of the robot workspace. In order to validate both of them a robot calibration is carried out on a physical prototype of the robot using a vision system, namely a fixed camera in a eye-to-hand configuration. An iterative algorithm aimed at the experimental identification of the geometric data of the robot is used. Some experimental results show the effectiveness of the study.