Faceting, composition and crystal phase evolution in III-V antimonide nanowire heterostructures revealed by combining microscopy techniques

III-V antimonide nanowires are among the most interesting semiconductors for transport physics, nanoelectronics and long-wavelength optoelectronic devices due to their optimal material properties. In order to investigate their complex crystal structure evolution, faceting and composition, we report a combined scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning tunneling microscopy (STM) study of gold-nucleated ternary InAs/InAs(1-x)Sb(x) nanowire heterostructures grown by molecular beam epitaxy. SEM showed the general morphology and faceting, TEM revealed the internal crystal structure and ternary compositions, while STM was successfully applied to characterize the oxide-free nanowire sidewalls, in terms of nanofaceting morphology, atomic structure and surface composition. The complementary use of these techniques allows for correlation of the morphological and structural properties of the nanowires with the amount of Sb incorporated during growth. The addition of even a minute amount of Sb to InAs changes the crystal structure from perfect wurtzite to perfect zinc blende, via intermediate stacking fault and pseudo-periodic twinning regimes. Moreover, the addition of Sb during the axial growth of InAs/InAs(1-x)Sb(x) heterostructure nanowires causes a significant conformal lateral overgrowth on both segments, leading to the spontaneous formation of a core-shell structure, with an Sb-rich shell.     

Exploiting anionic and cationic interactions with a new emissive imine-based β-naphthol molecular probe

A new emissive molecular probe derived from 1,7-bis(2′-formylphenyl)-1,4,7-trioxaheptane and 2-hydroxy-1-naphthaldehyde has been synthesized by a Schiff-base condensation method. Its sensor capability towards cations such as Cu²⁺, Zn²⁺, Cd²⁺ and Hg²⁺, and anions such as halides (F⁻, Cl⁻, Br⁻ and I⁻) and CN⁻ was explored in DMSO solution. The geometry was optimized using density functional theory (DFT). The probe showed remarkable selectivity for Cu²⁺ and interaction with the more basic anions CN⁻ and F⁻.     

Structure and catalytic performance of Pt-promoted alumina-supported cobalt catalysts under realistic conditions of Fischer–Tropsch synthesis

The structure of alumina-supported cobalt catalysts promoted with platinum and their catalytic performance in Fischer–Tropsch synthesis were investigated under realistic reaction conditions (P = 20 bar, T = 493 K) using in situ time-resolved X-ray diffraction with simultaneous analysis of reaction products. The catalysts were prepared via incipient wetness impregnation and characterized by a wide range of ex situ techniques. Direct in situ measurements were indicative of considerable versatility of alumina-supported cobalt catalysts during Fischer–Tropsch synthesis. Cobalt sintering occurred at the first hours of the reaction and resulted in a significant drop of the catalytic activity. In addition to sintering, partially oxidized catalysts containing smaller cobalt particles (mean particle size <5 nm) were slowly reducing during Fischer–Tropsch reaction. Treatment of cobalt catalysts in pure carbon monoxide led to selective transformation of cobalt metallic phases to Co₂C cobalt carbide. Cobalt carbidization followed by hydrogenation selectively led to cobalt hcp metallic phase, which seems to be more active in Fischer–Tropsch synthesis than cobalt fcc phase. Cobalt oxidation by water was not significant in the catalysts with metal particles larger than 5 nm even at high water concentrations.     

Pressure drop measurements and modeling on SiC foams

Foam-structured beds are likely to be the next generation of catalyst supports due to their interesting specific properties (large exchange area, low pressure drop, easy control of external porosity, etc.). Nevertheless, chemical engineering parameters of this new catalyst support types are still not completely clear for the scientific community and many approaches are attempted to solve this problem. SiC foams offer the dual advantages of the interesting properties of structured beds and the intrinsic thermal and mechanical properties of silicon carbide as a catalytic support. In the present work, the problem of pressure drops along foam beds is studied with a new simplistic geometrical model as a first step in the understanding of the peculiar hydrodynamic behavior of SiC foams in chemical processes. The proposed model was successfully validated by experimental results on a relatively large range of parameters which fully confirm the validity of the model.     

The genuine short GRB 090227B and the disguised by excess GRB 090510

GRB 090227B and GRB 090510, traditionally classified as short gamma-ray Bursts (GRBs), indeed originate from different systems. For GRB 090227B we inferred a total energy of the e ⁺ e ^? plasma \(E_{e^ + e^ - }^{tot} \) = (2.83 ± 0.15) × 10⁵³ erg, a baryon load of B = (4.1 ± 0.05) × 10^?5, and a CircumBurstMedium (CBM) average density 〈n _CBM〉 = (1.90 ± 0.20) × 10^?5 cm^?3. From these results we have assumed the progenitor of this burst to be a symmetric neutron stars (NSs) merger with masses m = 1.34 M_⊙, radii R = 12.24 km. GRB 090510, instead, has \(E_{e^ + e^ - }^{tot} \) = (1.10 ± 0.06) × 10⁵³ erg, B = (1.45 ± 0.28) × 10^?3, implying a Lorentz factor at transparency of Γ = (6.7 ± 1.7) × 10², which are characteristic of the long GRB class, and a very high CBM density, 〈n _CBM〉 = (1.85 ± 0.14) × 10³ cm^?3. The joint effect of the high values of Γ and of 〈n _CBM〉 compresses in time and “inflates” in intensity in an extended afterglow, making appear GRB 090510 as a short burst, which we here define as “disguised short GRB by excess” occurring an overdense region with 10³ cm^?3.     

VACUUM DRYING OF OAKWOOD :MOISTURE STRAINS AND DRYING PROCESS

After presenting the characteristics and the data acquired in an industrial evacuated kiln, a simplified analysis of heat and mass transfers is proposed. This analysis is based on the existence of a evaporization front determining two zones in the longitudinal direction :

-a dried zone in which moisture is less than 30 %

-a wet zone in which moisture is still at its initial value.

Such a hypothesis allows to study transfers transversally first, then longitudinally. Both equation systems ore linked by conditions of continuity for mass and energy.

This study allows to determine the shapes of the temperature and pressure curves in the longitudinal direction. The linearity of the variation of the average drying velocity versus the average moisture content of the board is also proved. Finally, the modeling of mechanical phenomena thanks to a finite element program shows the rupture zones appearing during the drying process.