Low Dielectric Loss Ceramics of AlN Fine and Nanopowders

The dielectric properties of ceramics pressurelessly sintered from nano (10-100 nm) and fine (0.8-1.0 μm) aluminum nitride powders have been studied. High-purity aluminum nitride sintered from nanopowder of nearly-theoretical density has been found to exhibit a low dielectric constant ε = 6.3 and low loss, tgδ = 0.011 at 3.32 GHz. Ceramics sintered from a fine aluminum nitride powder doped with yttrium oxide have revealed ε = 7.7 and tgδ = 0.021 at 3.23 GHz. The dielectric properties have allowed us to use ceramics sintered from fine aluminum nitride powder as a material for microwave windows for the diagnosis and treatment of tumors of the larynx and breast.     

Don't worry, be happy? Neuroticism, trait-consistent affect regulation, and performance.

People regulate their affect either to feel good or to achieve instrumental success. The present experiments show that when driven by performance goals, people can be motivated to experience unpleasant affect when it is trait-consistent, because of its instrumental benefits (e.g., M. Tamir & M. D. Robinson, 2004). In 4 studies, individuals high in neuroticism were more likely than those low in neuroticism to choose to increase their level of worry, as indicated by self-reported preferences (Study 1) and by behavioral choices in experimental settings (Studies 2-4). As predicted, such preferences were evident when expecting to perform demanding tasks but not when expecting an undemanding task (Study 2). Study 4 suggests that such preferences for short-term unpleasant affect may be beneficial to performance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Fault estimation and tolerant control for discrete‐time switched systems with sojourn probabilities

This paper addresses the issue of fault estimation and accommodation for a discrete‐time switched system with actuator faults. Here, we assume that the sojourn probabilities are known a priori. By using the reduced‐order observer method, the sojourn probability approach, and the Lyapunov technique, a fault estimation algorithm is obtained for the considered system. The main objective of this work is to design a dynamic output feedback fault‐tolerant controller based on the obtained fault estimation information such that the closed‐loop discrete‐time switched system with available sojourn probabilities is robustly mean‐square stable and satisfies a prescribed mixed and passivity disturbance attenuation level in the presence of actuator faults. More precisely, a dynamic output feedback fault‐tolerant controller is established in terms of linear matrix inequalities. Finally, numerical examples are provided to illustrate the usefulness and effectiveness of the proposed design technique.     

Improved CO2 Capture from Flue Gas by Basic Sites,Charge Gradients,and Missing Linker Defects on Nickel Face Cubic Centered MOFs

The adsorptive properties of the isoreticular series [Ni₈(OH)₄(H₂O)₂(BDP_X)₆] (H₂BDP_X = 1,4‐bis(pyrazol‐4‐yl)benzene‐4‐X with X = H (1), OH (2), NH₂ (3)) can be enhanced by postsynthetic treatment with an excess of KOH in ethanol. In the case of X = H, NH₂, this treatment leads to partial removal of the organic linkers, deprotonation of coordinated water molecules and introduction of extraframework cations, giving rise to materials of K[Ni₈(OH)₅(EtO)‐(H₂O)₂(BDP_X)_5.5] (1@KOH, 3@KOH) formulation, in which the original framework topology is maintained. By contrast, the same treatment with KOH in the [Ni₈(OH)₄(H₂O)₂(BDP_OH)₆] (2) system, enclosing the more acidic phenol residues, leads to a new material containing a larger fraction of missing linker defects and extra‐framework cations as well as phenolate residues, giving rise to the material K₃[Ni₈(OH)₃(EtO)(H₂O)₆(BDP_O)₅] (2@KOH), which also conserves the original face cubic centered (fcu) topology. It is noteworthy that the introduction of missing linker defects leads to a higher accessible pore volume with a concomitant increased adsorption capacity. Moreover, the creation of coordinatively unsaturated metal centers, charge gradients, and phenolate nucleophilic sites in 2@KOH gives rise to a boosting of CO₂ capture features with increased adsorption heat and adsorption capacity, as proven by the measurement of pulse gas chromatography and breakthrough curve measurements of simulated flue gas.     

Hydrogenation of Nitrobenzene with Supported Transition Metal Catalysts in Supercritical Carbon Dioxide

Transition metal catalysts such as Pd, Pt, Ru, and Rh supported on carbon, silica and alumina have been examined for the hydrogenation of nitrobenzene (NB) in supercritical carbon dioxide (scCO₂) and in ethanol. The order of hydrogenation activity is Pt>Pd>Ru, Rh in scCO₂ and in ethanol. The effectiveness of the support is C>Al₂O₃, SiO₂ for either Pt or Pd in scCO₂. For all the catalysts, higher selectivity to aniline has been obtained in scCO₂ compared with ethanol. Hydrogenation of nitrobenzene catalyzed with Pd/C and Pt/C catalysts was successfully conducted in scCO₂ with a 100% yield to aniline at a lower reaction temperature of 35 °C. The product aniline (organic phase) can be easily separated from the side‐product water (aqueous phase), solvent (scCO₂), and catalyst (solid) by a simple phase separation process. The hydrogenation of NB is a structure‐sensitive reaction in ethanol as well as in scCO₂ except for a few Pt/C catalysts in which the degree of metal dispersion is small (<0.08).     

Analysis of e-business models in real estate

We use Canvas Application Framework to analyze e-business models of Realestate.yahoo.com, Yahoo.com, Redfin.com, Realtor.com, Trulia.com, Zillow.com, and Craigslist.com. We investigate the similarities and differences among e-business models and how e-business model differentiation affects company success. We looked at which business model components, such as distribution channels, business partnerships, attracting customers, revenue streams, etc., are important. We further investigate whether the web-advertising, brokerage, virtual value-chain, or the diversified internet business model is used by each company, and which ones are more successful. We discover similarities and differences among e-business models. Differences include the use of revenue streams for generating revenue, the extent of partnerships, and the role they play in a company’s success.     

A metaheuristic for a teaching assistant assignment-routing problem

The Flemish Ministry of Education promotes the integrated education of disabled children by providing educational opportunities in common schools. In the current system, disabled children receive ambulant help from a teaching assistant (TA) employed at an institute for extra-ordinary education. The compensation that the TAs receive for driving to visit the pupils is a major cost factor for the institute that provides the assistance. Therefore, the institute's management desires a schedule that minimizes the accumulated distance traveled by all TAs combined. We call this optimization problem the teaching assistants assignment-routing problem (TAARP). It involves three decisions that have to be taken simultaneously: (1) pupils have to be assigned to TAs; (2) pupils assigned to a given TA have to be spread over the TA's different working days; and (3) the order in which to visit the pupils on each day has to be determined. We propose a solution strategy based on an auction algorithm and a variable neighborhood search heuristic which has an excellent performance when applied to both simulated and real instances. The total distance traveled in the solution obtained for the institute's data set improves the current solution by about 22% which represents a saving of approximately 9% on the annual budget of the institute for integrated education.     

Neuroticism as Mental Noise: A Relation Between Neuroticism and Reaction Time Standard Deviations.

Those higher in neuroticism are often more variable in their behavior and experience. On the basis of this observation, the authors hypothesized that the trait of neuroticism might be correlated with the variability of performance pertaining to relatively basic cognitive operations. Three studies involving 242 college undergraduates supported this prediction in that neuroticism correlated positively with the variability of performance across trials of reaction time tasks. These results link neuroticism to cognitive noise that intervenes between stimulus and response. Such noise has been associated with executive dysfunctions (e.g., frontal lobe injury) in previous research. The present findings are potentially useful for understanding why neuroticism often correlates with variations in the functionality of cognition and behavior. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Efficacy of citric acid against Listeria monocytogenes attached to poultry skin during refrigerated storage

The aim of this study was to evaluate the effect of citric acid washing on the growth of Listeria monocytogenes on poultry legs stored at 4 °C for 8 days. Fresh inoculated chicken legs were dipped into either a 0.052, 0.104 or 0.156  m citric acid solution for 5 min or distilled water (control). Surface pH values, sensorial characteristics and L . monocytogenes , mesophiles and psychrotrophs counts were evaluated. Legs washed with 0.156  m citric acid for 5 min showed a significant ( P  < 0.05) inhibitory effect on L . monocytogenes compared with control legs, being about 1.55 log units lower in the first ones than in control legs after 1 day of storage. Treatments with 0.156  m citric acid reduced bacterial growth and preserved reasonable sensorial quality after storage at 4 °C for 8 days.