Effect of phosphoric acid on the performance of low antimony grid of Pb‐acid cell under constant current charging and discharging

Effect of phosphoric acid on the performance of Pb‐1.7%Sb grid of lead‐acid cell is studied in 5 M H₂SO₄ by cyclic galvanostatic polarization and impedance spectroscopy. An increase in capacitance to a maximum is recorded during the initial stages of the electro‐reduction of PbO₂ into Pb(II) compounds and attributed to concurrent compositional and dimensional changes. These changes include removal of O₂ bubbles, insertion of large amounts of H₂SO₄ and H₂O. Efficiency of PbO₂ formation decreases, while its rate of self‐discharge increases with increasing the charging current and in the presence of H₃PO₄. The charge capacity increases with increasing the discharging current due to the decrease in the self‐discharge. The charge capacity is lower in the presence of H₃PO₄. On increasing the cycle number, the corrodibility of the grid increases, because more layers of the surface Pb are involved in the self‐discharge. H₃PO₄ significantly retards the effect of cycle number.     

Performance comparison of battery power consumption in wireless multiple access protocols

Energy efficiency is an important issue in mobile wireless networks since the battery life of mobile terminals is limited. Conservation of battery power has been addressed using many techniques such as variable speed CPUs, flash memory, disk spindowns, and so on. We believe that energy conservation should be an important factor in the design of networking protocols for mobile wireless networks. In particular, this paper addresses energy efficiency in medium access control (MAC) protocols for wireless networks. The paper develops a framework to study the energy consumption of a MAC protocol from the transceiver usage perspective. This framework is then applied to compare the performance of a set of protocols that includes IEEE 802.11, ECMAC, PRMA, MDRTDMA, and DQRUMA*. The performance metrics considered are transmitter and receiver usage times for packet transmission and reception. The time estimates are then combined with power ratings for a Proxim RangeLAN2 radio card to obtain an estimate of the energy consumed for MAC related activities. The analysis here shows that protocols that aim to reduce the number of contentions perform better from an energy consumption perspective. The receiver usage time, however, tends to be higher for protocols that require the mobile to sense the medium before attempting transmission. The paper also provides a set of principles that could be applied when designing access protocols for wireless networks.*ECMAC: energyconserving MAC. PRMA: packet reservation multiple access. MDRTDMA: multiservices dynamic reservation TDMA. DQRUMA: distributedqueuing request update multiple access.