Wear of graphite anodes during electrolysis of add sulphate solutions

Graphite electrodes were prepared by mixing calcined coke and coal tar pitch. They were pressed under 250 kg cm^–2 and heat treated up to 2800° C. Rectangles measuring 70 mm x 40 mm x 8 mm were anodically polarized under galvanostatic and potentiostatic conditions. Electrolyses were conducted at 10–50 mA cm^–2 for periods ranging from 10–120 hours in Na₂SO₄ solutions acidified with sulphuric acid to various pH values. The wear of graphite anodes increased with decreasing bath temperature, increasing acid concentration, decreasing pH of the electrolyte and increasing current density. A model is suggested which assumes that corrosion takes place via the formation of a lamellar crystal compound with the formula (C ₈ ⁰ O)(OH)₃HSO ₄ ^– ·2H₂SO₄.The compound is unstable at higher temperatures when corrosion is effected by oxidation of graphite by atomic oxygen. The formation of the carbon ions was found to be a necessary precondition for the formation of the complex.     

Graft Copolymerization of Acrylamide onto Oil Palm Empty Fruit Bunch (OPEFB) Fiber

Grafting of acrylamide (AAm) onto oil palm empty fruits bunch fiber using hydrogen peroxide as initiator and methyl acrylate as comonomer was investigated. The amount of comonomer needed to make grafting of acrylamide possible was determined. The percentage of poly(acrylamide) and the comonomer in the final graft copolymer was estimated by elemental analysis. Results obtained indicated that methyl acrylate facilitated the incorporation of acrylamide monomer onto OPEFB. The reactivity ratios for both monomers were determined by using Fineman–Ross plot. The effects of reaction temperature and period as well as amount of the initiator, solvent, monomer and comonomer on the percentage of grafting at fixed amount of comonomer (11 mmol) were studied. Maximum percentage of grafting was achieved when the amount of initiator and solvent 3.98×10⁻³ mol and 50 mL respectively. The optimum reaction temperature was 50 ^○C and the reaction period was 90 min. Highest percentage of grafting was 232% when 25.6 mmol of acrylamide was used under these optimum conditions. The presence of functional group in the grafted polymer is characterized by infrared spectroscopy and the surface morphology is observed by scanning electron microscopy. Thermoanalytic investigation on OPEFB and OPEFB-g-PAAM were carried out to evaluate the thermal stability and respective activation energy of the materials.     

Effect of scraped-surface tube cooler temperatures on the physical properties of palm oil margarine

The effects of scraped-surface tube cooler temperatures on the isothermal solid fat content (SFC) of palm oil margarine during processing and on margarine consistency (yield value, g/cm²), SFC, and polymorphic changes in storage were studied. SFC was measured in the mixing tank after leaving the tube cooler and the pin worker. The SFC at the tube cooler exit was proportional to the amount of cooling; a higher SFC was produced by more extreme cooling treatment. The SFC of all margarines were reduced in the pin worker, and the reduction was related to the initial SFC profile of palm oil. Margarine samples were stored at 28°C for 28 d and tested daily. Margarine processed at 25°C in the tube cooler had the highest consistency and the least change in SFC, but by the second week crystals had transformed into the β form. Uniform product consistency and SFC were observed in margarines processed at 20 and 15°C. These margarines retained the β′ crystal form for 3 and 4 wk, respectively. The best palm oil margarine was obtained with a tube cooler temperature of 15°C and a residence time of 1.8 min.     

Characterization and preparation of new multiwall carbon nanotube/conducting polymer composites by in situ polymerization

Composites based on poly(diphenyl amine) (PDPA) and multiwall carbon nanotubes (MWNTs) were prepared by chemical oxidative polymerization through two different approaches: in situ polymerization and intimate mixing. In in situ polymerization, DPA was polymerized in the presence of dispersed MWNTs in sulfuric acid medium for different molar composition ratios of MWNT and DPA. Intimate mixing of synthesized PDPA with MWNT was also used for the preparation of PDPA/MWNT composites. Transmission electron microscopy revealed that the diameter of the tubular structure for the composite was 10–20 nm higher than the diameter of pure MWNT. Scanning electron microscopy provided evidence for the differences in the morphology between the MWNTs and the composites. Raman and Fourier transform IR (FTIR) spectroscopy, thermogravimetric analysis, X‐ray diffraction, and UV–visible spectroscopy were used to characterize the composites and reveal the differences in the molecular level interactions between the components in the composites. The Raman and FTIR spectral results revealed doping‐type molecular interactions and coordinate covalent‐type interactions between MWNT and PDPA in the composite prepared by in situ polymerization and intimate mixing, respectively. The backbone structure of PDPA in the composite decomposed at a higher temperature (>340°C) than the pristine PDPA (～300°C). This behavior also favored the molecular level interactions between MWNT and PDPA in the composite. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3721–3729, 2006     

Fuzzy triangulation signature for detection of change in human emotion from face video image sequence

The present article proposes a geometry-based fuzzy relational technique for capturing gradual change in human emotion over time available from relevant face image sequences. As associated features, we make use of fuzzy membership arising out of five triangle signatures such as - (i) Fuzzy Isosceles Triangle Signature (FIS), (ii) Fuzzy Right Triangle Signature (FRS), (iii) Fuzzy Right Isosceles Triangle Signature (FIRS), (iv) Fuzzy Equilateral Triangle Signature (FES), and (v) Other Fuzzy Triangles Signature (OFS) to achieve the task of appropriate classification of facial transition from neutrality to one among the six expressions viz. anger (AN), disgust (DI), fear (FE), happiness (HA), sadness (SA) and surprise (SU). The effectiveness of the Multilayer Perceptron (MLP) classifier is tested and validated through 10 fold cross-validation method on three benchmark image sequence datasets namely Extended Cohn-Kanade (CK+), M&M Initiative (MMI), and Multimedia Understanding Group (MUG). Experimental outcomes are found to have achieved accuracy to the tune of 98.47%, 93.56%, and 99.25% on CK+, MMI, and MUG respectively vindicating the effectiveness by exhibiting the superiority of our proposed technique in comparison to other state-of-the-art methods in this regard.

     

Thermal deformation analysis of tabbed solar cells using solder alloy and conductive film

Finite element analysis (FEA) has been carried out with the aim of understanding the thermal deformation characteristics of two solar cell configurations. One of the solar cell models is tabbed by lead-free solder, the other model by Conductive film (CF). A high temperature soldering process could weaken the bond and reduce the reliability of the cells because of the residual stress caused by the different thermal expansion coefficients of the materials. Moreover, solar irradiation generates temperature distribution across the surface of the solar cell, and the development of solar cells made of thinner crystalline silicon wafers will lead to the reduction in manufacturing costs. In this study, Finite element analysis (FEA) of the manufacturing process has been carried out using both solder and CF bonding. Three temperature cycles were applied to analyze different environmental operating conditions and understand how thermal cycles affect the residual stress during actual service conditions. This investigation provides a comparison of thermal deformations between solder and CF bonded solar cells in order to understand which offers substantial reliability in the long term. Also this study explores the effects of various thicknesses of the silicon wafer on the residual stress and deformation of the solar cells.     

Synthesis and characterization of photopolymerizable hydrogels based on poly (ethylene glycol) for biomedical applications

Hydrogels are polymeric materials widely used in medicine due to their similarity with the biological components of the body. Hydrogels are biocompatible materials that have the potential to promote cell proliferation and tissue support because of their hydrophilic nature, porous structure, and elastic mechanical properties. In this work, we demonstrate the microwave-assisted synthesis of three molecular weight varieties of poly(ethylene glycol) dimethacrylate (PEGDMA) with different mechanical and thermal properties and the rapid photo of them using 1-hydroxy-cyclohexyl-phenyl-ketone (Irgacure 184) as UV photoinitiator. The effects of the poly(ethylene glycol) molecular weight and degree of acrylation on swelling, mechanical, and rheological properties of hydrogels were investigated. The biodegradability of the PEGDMA hydrogels, as well as the ability to grow and proliferate cells, was examined for its viability as a scaffold in tissue engineering. Altogether, the biomaterial hydrogel properties open the way for applications in the field of regenerative medicine for functional scaffolds and tissues.     

Progress and challenges in sustainability,compatibility, and production of eco-composites: A state-of-art review

Owing to economic and environmental benefits, new generations of materials/commodities follow “from waste to wealth” strategy. Recently, there has been a huge upsurge in research on the development of eco-composites using recycled plastic polymers and agro-residues because the eco-composites satisfy the stringent environment regulations and are cost-effective. Herein, we present a detailed review on the potential use of several types of natural fillers as an efficient reinforcement for recycled plastic polymers. In particular, the characterization of different categories of eco-composites according to their morphological, physical, thermal, and mechanical properties is extensively reviewed and their results are analyzed, compared, and highlighted. Furthermore, a framework to produce functional eco-composites, which includes functionalization of ingredients, critical issues on microstructural parameters, processing, and fabrication methods, is outlined and supported with sufficient data from the literature. Finally, the review outlines the emerging challenges and future prospects of eco-composites to be addressed by interested researchers to bridge the gap between research and commercialization of such a class of material. Overall, the acquired knowledge will guide researchers, scientists, and manufacturers to plan, select, and develop various forms of eco-composites with enhanced properties and optimized production processes.     

Perfect secret sharing scheme based on vertex domination set

Due to the fast development in data communication systems and computer networks in recent years, the necessity to protect the secret data has become extremely imperative. Several methods have been proposed to protect the secret data; one of them is the secret sharing scheme. It is a method of distributing a secret K among a finite set of participants, in such a way that only predefined subset of participant is enabled to reconstruct a secret from their shares. A secret sharing scheme realizing uniform access structure described by a graph has received a considerable attention. In this scheme, each vertex represents a participant and each edge represents a minimum authorized subset. In this paper, an independent dominating set of vertices in a graph G is introduced and applied as a novel idea to construct a secret sharing scheme such that the vertices of the graph represent the participants and the dominating set of vertices in G represents the minimal authorized set. While most of the previous schemes were based on the principle of adjacent vertices, the proposed scheme is based upon the principle of non-adjacent vertices. We prove that the scheme is perfect, and the lower bound of the information rate of this new construction is improved when compared to some well-known previous constructions. We include an experiment involving security threats to demonstrate the effectiveness of the proposed scheme.