Development and Simulation of Sulfur‐doped Graphene Supported Platinum with Exemplary Stability and Activity Towards Oxygen Reduction

Sulfur‐doped graphene (SG) is prepared by a thermal shock/quench anneal process and investigated as a unique Pt nanoparticle support (Pt/SG) for the oxygen reduction reaction (ORR). Particularly, SG is found to induce highly favorable catalyst‐support interactions, resulting in excellent half‐cell based ORR activity of 139 mA mg_Pt ^?1 at 0.9 V vs RHE, significant improvements over commercial Pt/C (121 mA mg_Pt ^?1) and Pt‐graphene (Pt/G, 101 mA mg_Pt ^?1). Pt/SG also demonstrates unprecedented stability, maintaining 87% of its electrochemically active surface area following accelerated degradation testing. Furthermore, a majority of ORR activity is maintained, providing 108 mA mg_Pt ^?1, a remarkable 171% improvement over Pt/C (39.8 mA mg_Pt ^?1) and an 89% improvement over Pt/G (57.0 mA mg_Pt ^?1). Computational simulations highlight that the interactions between Pt and graphene are enhanced significantly by sulfur doping, leading to a tethering effect that can explain the outstanding electrochemical stability. Furthermore, sulfur dopants result in a downshift of the platinum d‐band center, explaining the excellent ORR activity and rendering SG as a new and highly promising class of catalyst supports for electrochemical energy technologies such as fuel cells.     

Symbol error rate calculation and data pre‐distortion for 16‐QAM transmission over nonlinear memoryless satellite channels

This paper presents a simplified mathematical approach to evaluate the performance of any given circular constellation of 16‐level quadrature amplitude modulation (16‐QAM) in terms of symbol error rate (SER). Following this approach, with the aim to work with memoryless nonlinear satellite channels, a model is derived as a generalized form for both linear and nonlinear channels in the presence of down link additive white Gaussian noise (AWGN). The analysis provides means to calculate the optimal ring ratio (RR) and phase difference (PD) for several possible candidates of 16‐QAM circular constellations. The effects of RR and PD on the SER performance are investigated in the analysis. To overcome the nonlinear distortion, data pre‐distortion is taken into account in the study. The paper gives a general procedure for data pre‐distortion implementation for all circular 16‐QAM constellations. The analytical formulation has been extended for total degradation (TD) performance measure as a function of input back‐off (IBO) of the nonlinear amplifier. A SER performance‐comparison between different constellations for 16‐QAM systems has also been presented in this paper. The analytical results are validated by simulation. Copyright © 2006 John Wiley & Sons, Ltd.     

Optical Properties of K<Subscript>2</Subscript>O-Li<Subscript>2</Subscript>O-WO<Subscript>3</Subscript>-B<Subscript>2</Subscript>O<Subscript>3</Subscript> Glasses: Evidence of Mixed Alkali Effect

Glass with compositions xK₂O-(30 ? x)Li₂O-10WO₃-60B₂O₃ for 0 ≤ x ≤ 30 mol.% have been prepared using the normal melt quenching technique. The optical reflection and absorption spectra were recorded at room temperature in the wavelength range 300–800 nm. From the absorption edge studies, the values of the optical band gap (E _opt) and Urbach energy (ΔE) have been evaluated. The values of E _opt and ΔE vary non-linearly with composition parameter, showing the mixed alkali effect. The dispersion of the refractive index is discussed in terms of the single oscillator Wemple Di-Domenico model.     

The impact of online brand community characteristics on customer engagement: An application of Stimulus-Organism-Response paradigm

The advent of interactive digital platforms has led people to progressively interact on such platforms, urging organizations to create online communities to engage customers with them and with each other to enhance brand loyalty. This study attempts to investigate what motivates customers to engage in these brand communities. Through a questionnaire survey of 430 Facebook users, this study investigates whether and how the unique characteristics (information quality, system quality, virtual interactivity, and rewards) of online brand communities affect customer engagement. The consequent effect of customer engagement on brand loyalty is also examined. This study frames and empirically validates a model for engaging customers with online brand communities on Facebook, considering the moderating role of gender. The Stimulus-Organism-Response paradigm is solicited to justify the theoretical background of this study. The data were analyzed using structure equation modelling. Results reveal that each of the characteristics positively influences customer engagement, with information quality and virtual interactivity bearing the strongest influence. Customer engagement also exhibits a strong positive impact on brand loyalty. This results further reveal that gender gap in the online environment is declining as the impact of all the four characteristics of online brand communities on customer engagement was invariable across male and female members.     

Multibit Σ–∆ PWM Digital Controller IC for DC–DC Converters Operating at Switching Frequencies Beyond 10 MHz

An integrated digital controller for dc-dc switch-mode power supplies (SMPS) used in portable applications is introduced. The controller has very low power consumption, fast dynamic response, and can operate at programmable constant switching frequencies exceeding 10 MHz. To achieve these characteristics, three novel functional blocks, a digital pulse-width modulator based on second-order sigma-delta concept (Sigma-Delta DPWM), dual-clocking mode compensator, and nonlinear analog-to-digital converter are combined. In steady state, to minimize power consumption, the controller is clocked at a frequency lower than SMPS switching frequency. During transients the clock rate is increased to the switching frequency improving transient response. The controller integrated circuit (IC) is fabricated in a standard 0.18-mum process and tested with a 750-mW buck converter prototype. Experimental results show the controller current consumption of 55 muA/MHz and verify closed-loop operation at programmable switching frequencies up to 12.3 MHz. Simulation results indicating that this architecture can potentially support operation at switching frequencies beyond 100 MHz are also presented.     

Multicast Network Security with Asymmetric Cooperative Relaying

International Journal of Wireless Information Networks - This paper exhibits the confidentiality performance study of a cooperative multicast network consisting of $${\mathcal {K}}$$ asymmetric...     

PbS and CdS Quantum Dot‐Sensitized Solid‐State Solar Cells: “Old Concepts,New Results”

Lead sulfide (PbS) and cadmium sulfide (CdS) quantum dots (QDs) are prepared over mesoporous TiO₂ films by a successive ionic layer adsorption and reaction (SILAR) process. These QDs are exploited as a sensitizer in solid‐state solar cells with 2,2′,7,7′‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD) as a hole conductor. High‐resolution transmission electron microscopy (TEM) images reveal that PbS QDs of around 3 nm in size are distributed homogeneously over the TiO₂ surface and are well separated from each other if prepared under common SILAR deposition conditions. The pore size of the TiO₂ films and the deposition medium are found to be very critical in determining the overall performance of the solid‐state QD cells. By incorporating promising inorganic QDs (PbS) and an organic hole conductor spiro‐OMeTAD into the solid‐state cells, it is possible to attain an efficiency of over 1% for PbS‐sensitized solid‐state cells after some optimizations. The optimized deposition cycle of the SILAR process for PbS QDs has also been confirmed by transient spectroscopic studies on the hole generation of spiro‐OMeTAD. In addition, it is established that the PbS QD layer plays a role in mediating the interfacial recombination between the spiro‐OMeTAD⁺ cation and the TiO₂ conduction band electron, and that the lifetime of these species can change by around 2 orders of magnitude by varying the number of SILAR cycles used. When a near infrared (NIR)‐absorbing zinc carboxyphthalocyanine dye (TT1) is added on top of the PbS‐sensitized electrode to obtain a panchromatic response, two signals from each component are observed, which results in an improved efficiency. In particular, when a CdS‐sensitized electrode is first prepared, and then co‐sensitized with a squarine dye (SQ1), the resulting color change is clearly an addition of each component and the overall efficiencies are also added in a more synergistic way than those in PbS/TT1‐modified cells because of favorable charge‐transfer energetics.     

A Distance Based Communication Mode Selection Mechanism for M2M Communications Over Cellular Networks

The implementation of machine-to-machine (M2M) communications in fifth-generation (5G) cellular networks can facilitate with several benefits like enhancement of bandwidth utilization, accommodating large number of users and decreasing traffic load on evolved node B (eNB). Integration of location information of unknown machine in communication mode selection mechanism is the key feature of this research. In this paper, a distance based communication mode selection mechanism using non-orthogonal resource sharing scheme is adopted in the proposed system model. Under the proposed mechanism, the expressions of throughput and RBs utilization policy are derived, which are the key parameters to evaluate the performance in the proposed network. Depending on the mode selection condition, such as threshold distance and threshold SINR between M2M users and regular cellular users, a UE can automatically choose its communication mode in the network. It is supposed that selection of mode before data transfer can improve the system performance. On the other hand, designing of efficient distance assisted proposed resource blocks (RBs) utilization policy reduces the traffic load on the eNB. Extensive simulations are carried out for evaluating the performance of the proposed mechanisms. The system performance is compared with various changeable parameters, such as throughput, mode selection threshold SINR, threshold distance and RBs. Besides, the proposed mechanism provides better network performance as well as reduces the traffic load in the proposed network.

     

Node to Node Performance Evaluation through RYU SDN Controller

In this paper a novel jamming technique is presented. The idea of the proposed jamming technique is based on adding inphase and quadrature impairments to the jamming signal. The jammer is simply a quadrature phase shift keying signal. The bit error rate probability (BER) of the proposed jamming signal is derived analytically and validated with the aid of the software defined radio SystemVue design software. The standard multi input multi output (MIMO) wireless local area network (WLAN) IEEE802.11n communication system is chosen as the victim system. Its BER performance is simulated in the presence of the proposed jamming signal in multipath fading channel. Finally, the efficiency of the proposed jamming signal on the MIMO WLAN IEEE802.11n communication system is practically measured in the laboratory where a practical experiment is held and the efficiency of the proposed jamming signal is compared with the traditional single tone jamming signal. It will be shown practically that the proposed jamming technique outperforms the traditional single tone jamming signal by nearly 15 dBm on the impact of efficiently jam the MIMO WLAN IEEE802.11n communication system.