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91.
Fatemeh Sadat Sangsefidi Masoud Salavati-Niasari Hossein Khojasteh Mehdi Shabani-Nooshabadi 《International Journal of Hydrogen Energy》2017,42(21):14608-14620
Pure CuO–CeO2 nanocomposites were synthesized by simple thermal decomposition method in presence of various Cu salts as a copper source and fructose as a green capping agent. In this study, the effect of various parameters such as the type of copper sources, temperature and time of reaction on the morphology and the particles size were studied. The products were characterized via X-ray diffraction (XRD) pattern, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), N2 adsorption (BET), vibrating sample magnetometer (VSM), and infrared spectrum (FT-IR). The optical property of the nanocomposite was examined via UV–vis (DRS) spectroscopy and the band gap was calculated to 3 eV. Also, the hydrogen storage capacity of CuO–CeO2 nanocomposites and CeO2 nanoparticles were investigated via chronopotentiometry method for the first time. The discharge capacity of CeO2 nanoparticles and CuO–CeO2 nanocomposites in 1 mA current and 20 cycles obtained 2150 and 2450 mAh/g, respectively. 相似文献
92.
Seyyed Ahmadreza Amirsadat Babak Moradi Ali Zeinolabedini Hezave Siamak Najimi Mehdi Hojjat Farsangi 《Korean Journal of Chemical Engineering》2017,34(12):3119-3124
Due to the vast production of crude oil and consequent pressure drops through the reservoirs, secondary and tertiary oil recovery processes are highly necessary to recover the trapped oil. Among the different tertiary oil recovery processes, foam injection is one of the most newly proposed methods. In this regard, in the current investigation, foam solution is prepared using formation brine, C19TAB surfactant and air concomitant with nano-silica (SiO2) as foam stabilizer and mobility controller. The measurements revealed that using the surfactant-nano SiO2 foam solution not only leads to formation of stable foam, but also can reduce the interfacial tension mostly considered as an effective parameter for higher oil recovery. Finally, the results demonstrate that there is a good chance of reducing the mobility ratio from 1.12 for formation brine and reservoir oil to 0.845 for foam solution prepared by nanoparticles. 相似文献
93.
The geometries, interaction energies, and bonding properties of cationic chalcogen bonds are studied in binary complexes XF2Y+?NCZ (X═H, CN, F; Y═S, Se; Z═H, Cl, Br). The nature of these interactions is studied by a vast number of methods, including molecular electrostatic potential (MEP), Noncovalent Interaction Index (NCI), quantum theory of atoms in molecules (QTAIM), and natural bond orbital (NBO) analyses. The interaction energies of these complexes vary between ?20.94?kcal/mol in HF2S+?NCH and ?33.72?kcal/mol in F3Se+?NCBr. According to the QTAIM analysis, all these cationic chalcogen bonds are classified as a closed-shell interaction with a partial covalent character. Moreover, cooperative effects between cationic chalcogen bond and hydrogen or halogen bond interactions are studied in ternary XF2Y+?NCZ?NH3 complexes. These cooperative effects are analyzed in terms of the parameters derived from the QTAIM and NBO analyses, and electron density difference plots. 相似文献
94.
95.
Current Distribution and Nonlinearity of Open-Ends and Gaps in Superconducting Microstrip Structures
S. Mohammad Hassan Javadzadeh Forouhar Farzaneh Mehdi Fardmanesh 《Journal of Superconductivity and Novel Magnetism》2013,26(5):1821-1825
Superconducting devices are known to produce nonlinear effects. In planar structures, these nonlinearities depend on the current distribution on the strip, which definitely depends on the structure of device. This paper used a numerical method based on 3D-FEM to obtain the current distribution in the open-ends and gaps in the superconducting microstrip structures. This is used to present the nonlinear distributed circuit modeling of these discontinuities and its impact on the nonlinear phenomenon. This nonlinear circuit model is used in the Harmonic Balance (HB) method to analyze nonlinearity in the superconducting microwave devices. Therefore, this simple accurate enough nonlinear circuit model is warmly welcomed to retire the seemingly inevitable use of time- and memory-consuming numerical techniques for nonlinear analysis of discontinuities in superconducting microwave structures. As an example, we analyze a microstrip superconducting end-coupled band pass filter (BPF). These results are very useful for optimizing the resonators of the superconducting microwave filters in order to minimize its nonlinear distortions. 相似文献
96.
A parametric analytical study is carried out to scrutinize the mechanism of fluid flow, heat transfer and entropy generation in a low-speed rarefied gaseous flow confined between a shaft and its concentric housing, i.e., the cylindrical Couette flow. In the first law analysis, closed form solutions for the radial temperature profiles are obtained by incorporating the calculated velocity distribution into the energy equation. The derivations for three thermal cases, which are founded on imposing different thermal conditions, namely, the Uniform Heat Flux (UHF) and the Constant Wall Temperature (CWT) boundary conditions, are presented. In the second law analysis, the contributions of thermal diffusion and fluid friction irreversibility to the total entropy generation in the micro domain are illustrated, and the relevant expressions for the Bejan number and the entropy generation number as well as the average entropy generation rate are derived. Finally, the variations of major variables with influential parameters such as the Knudsen number, the Brinkman number and rotation mode are investigated to elucidate the associated effects of rarefaction phenomenon, viscous dissipation and geometric condition on the characteristics of the flow. 相似文献
97.
Ali Shirazi Mehdi Aminyavari Behzad Najafi Fabio Rinaldi Majid Razaghi 《International Journal of Hydrogen Energy》2012
In this article, an internal-reforming solid oxide fuel cell–gas turbine (IRSOFC–GT) hybrid system is modeled and analyzed from thermal (energy and exergy), economic, and environmental points of view. The model is validated using available data in the literature. Utilizing the genetic algorithm optimization technique, multi-objective optimization of modeled system is carried out and the optimal values of system design parameters are obtained. In the multi-objective optimization procedure, the exergy efficiency and the total cost rate of the system (including the capital and maintenance costs, operational cost (fuel cost), and social cost of air pollution for CO, NOx, and CO2) are considered as objective functions. A sensitivity analysis is also performed in order to study the effect of variations of the fuel unit cost on the Pareto optimal solutions and their corresponding design parameters. The optimization results indicate that the final optimum design chosen from the Pareto front results in exergy efficiency of 65.60% while it leads to total cost of 3.28 million US$ year−1. It is also demonstrated that the payback time of the chosen design is 6.14 years. 相似文献
98.
Mehdi Panji Hamid Koohsari Mohammad Adampira Hamid Alielahi Jafar Asgari Marnani 《岩石力学与岩土工程学报(英文版)》2016,(4):480-488
In this paper, stress behavior of shallow tunnels under simultaneous non-uniform surface traction and symmetric gravity loading was studied using a direct boundary element method(BEM). The existing fullplane elastostatic fundamental solutions to displacement and stress fields were used and implemented in a developed algorithm. The cross-section of the tunnel was considered in circular, square, and horseshoe shapes and the lateral coefficient of the domain was assumed as unit quantity. Double-node procedure of the BEM was applied at the corners to improve the model including sudden traction changes. The results showed that the method used was a powerful tool for modeling underground openings under various external as well as internal loads. Eccentric loads significantly influenced the stress pattern of the surrounding tunnel. The achievements can be practically used in completing and modifying regulations for stability investigation of shallow tunnels. 相似文献
99.
Hossein Pourmohamadian Ghanbar Ali Sheikhzadeh Mehdi Rahimi-Nasrabadi Hassan Basirat Tabrizi 《Journal of Materials Science: Materials in Electronics》2017,28(14):9990-9997
In the present study, the microencapsulated phase change material with palmitic acid as core and inorganic SiO2 shell was successfully fabricated by a sol–gel method in alkaline medium via sodium silicate precursor. The chemical compositions, crystalloid phase, microstructure and morphology of PA@SiO2 microcapsule were studied by Fourier transform infrared spectroscopy, X-ray diffractometer, scanning electron microscopy and transmission electron microscopy. Differential scanning calorimetry and thermogravimetric analysis were used to determine the thermal properties and thermal stability of microcapsules, respectively. According to the XRD and FT-IR results, all the characteristic peaks of PA and SiO2 were observed and there is no chemical reaction between them. Scanning electron microscopy images indicated that the microcapsule synthesized in pH 11 had a perfect spherical shape with smooth surfaces compared with other samples, and transmission electron microscopy images confirm that the PA have been well encapsulated by SiO2. Differential scanning calorimetry analysis showed that the microcapsules indicated similar phase change behaviors as those of pristine PA, which melt at 67.2?°C with a latent heat of 111.2 J/g and freezing at 56.5?°C with a latent heat of 103.2 J/g. TGA analysis indicated that the thermal stability of the PA was also improved due to the protection of SiO2 shell toward the encapsulated PA. 相似文献
100.
Mehdi Golpayegani Jafar Fathali Eiman Khosravian 《Neural computing & applications》2014,24(3-4):613-619
Let n existing facilities be given in the plane. The classical version of the median line location problem asks to find a line L in the plane, so that the sum of the weighted distances from L to all existing facilities is minimized. We consider the semi-obnoxious case, where every point has either a positive or a negative weight. In this paper, we discuss some properties of semi-obnoxious median line location problem with Euclidean norm and propose a particle swarm optimization algorithm for this problem. 相似文献