Effects of aluminium nitride silane-treatment on the mechanical and thermal properties of polybenzoxazine matrix

A new kind of polymer composite, produced from the typical polybenzoxazine and 0–30 wt-% native and silane-treated aluminium nitride (T-AlN), was investigated. The mechanical tests revealed a significant increase in the microhardness and flexural properties upon adding the T-AlN particles compared to that obtained from the untreated ones. By adding 0–30 wt-% T-AlN, the tensile moduli were accurately reproduced by the Halpin-Tsai and Nielsen models. At 30 wt-% T-AlN, dynamic mechanical analysis showed a significant increase in the storage moduli and the glass transition temperature (T_g), reaching 3.2?GPa and 217°C, respectively. The thermal stability of these materials was significantly improved upon the addition of the T-AlN fillers. These improvements are attributed to the high thermal and mechanical properties of the fillers and their good dispersion and adhesion in and to the matrix as revealed by a morphological analysis.     

Isogeometric level set topology optimization for elastoplastic plane stress problems

International Journal of Mechanics and Materials in Design - This article aims to utilize IsoGeometric analysis (IGA) and Level set method for topology optimization of elastoplastic plane stress...     

Synthesis of highly isotactic poly 1-hexene using Fe-doped Mg(OEt)2/TiCl4/ED Ziegler–Natta catalytic system

In this article, polymerization of 1-hexene with FeCl_3-doped Mg(OET)₂/TiCl₄/electron donor (ED) catalytic system is presented. For this purpose, first a number of TiCl₄ catalysts supported on Mg(OEt)₂ and Fe-doped Mg(OEt)₂ supports were prepared with ethylbenzoate or dibutylphthalate as the internal EDs. After successive catalysts synthesis, they were employed in 1-hexene polymerization using cyclohexyl methyl dimethoxysilane as external ED as well as without it. The catalysts activity and molecular weight distribution (MWD) of poly 1-hexenes (PHs) were influenced strongly by both FeCl₃ doping and donor presence so that a remarkable increase in the catalyst activity was seen in doped catalysts. Deconvolution of MWD curves revealed that increase in the type of active centers by introducing FeCl₃ into the support should be responsible for the broadening of MWD of PHs. ¹³CNMR analysis indicated that while isotacticity does not change considerably by Fe doping, EDs increase its amount as high as 8–21%. Second, the stereoselective behavior of active Ti species in doped and undoped catalysts was fully explored by molecular modeling using density functional theory (DFT) method. Finally, with the aid of rheological measurements, the processability of polymers were evaluated and then the gel permeation chromatography (GPC) results were approved through the values obtained from model fitting as well as changes in moduli crossover modulus.     

The influence of heterogeneous meninges on the brain mechanics under primary blast loading

In the modeling of brain mechanics subjected to primary blast waves, there is currently no consensus on how many biological components to be used in the brain–meninges–skull complex, and what type of constitutive models to be adopted. The objective of this study is to determine the role of layered meninges in damping the dynamic response of the brain under primary blast loadings. A composite structures composed of eight solid relevant layers (including the pia, cerebrospinal fluid (CSF), dura maters) with different mechanical properties are constructed to mimic the heterogeneous human head. A hyper-viscoelastic material model is developed to better represent the mechanical response of the brain tissue over a large strain/high frequency range applicable for blast scenarios. The effect of meninges on the brain response is examined. Results show that heterogeneous composite structures of the head have a major influence on the intracranial pressure, maximum shear stress, and maximum principal strain in the brain, which is associated with traumatic brain injuries. The meninges serving as protective layers are revealed by mitigating the dynamic response of the brain. In addition, appreciable changes of the pressure and maximum shear stress are observed on the material interfaces between layers of tissues. This may be attributed to the alternation of shock wave speed caused by the impedance mismatch.     

Energy use efficiency and economical analysis of almond production: a case study in Chaharmahal-Va-Bakhtiari province,Iran

The aim of this study was to analyse input–output energy and economical assessment of almond production in three age groups of orchards (group I 6–10, group II 11–15 and group III 16–20 years old) in Chahrmahal-Va-Bakhtiari province, Iran. Data for almond production were collected by administering questionnaire in face-to-face interviews from the orchards selected based on random sampling method during a 3-year period. The results showed that 57,027.13, 60,341.14 and 61,640.43 MJ ha^?1 energy was consumed by group I, group II and group III, respectively. The most energy input was consumed by electricity, followed by chemical fertilizer. Energy indices were calculated, and the results revealed that energy efficiency was 0.62, 1.12 and 0.81 in the triple groups of orchards, respectively. Economical assessment showed that total production cost of almond in group I, II and III was $4547.54, $5799.26 and $5687.05 ha^?1, respectively. In all orchard groups, the shares of variable and fixed production costs found to be same nearly. Net return for almond production was $14,516.22, $30,735.19 and $21,395.57ha^?1, respectively. According to the research results, it was concluded that although almond production in the study region was not an efficient process in terms of energy consumption, it was a profitable agricultural operation.     

Synthesis,characterization and investigation of the electrochemical hydrogen storage properties of CuO–CeO2 nanocomposites synthesized by green method

Pure CuO–CeO₂ nanocomposites were synthesized by simple thermal decomposition method in presence of various Cu salts as a copper source and fructose as a green capping agent. In this study, the effect of various parameters such as the type of copper sources, temperature and time of reaction on the morphology and the particles size were studied. The products were characterized via X-ray diffraction (XRD) pattern, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), N2 adsorption (BET), vibrating sample magnetometer (VSM), and infrared spectrum (FT-IR). The optical property of the nanocomposite was examined via UV–vis (DRS) spectroscopy and the band gap was calculated to 3 eV. Also, the hydrogen storage capacity of CuO–CeO₂ nanocomposites and CeO₂ nanoparticles were investigated via chronopotentiometry method for the first time. The discharge capacity of CeO₂ nanoparticles and CuO–CeO₂ nanocomposites in 1 mA current and 20 cycles obtained 2150 and 2450 mAh/g, respectively.     

Investigating the effect of nano-silica on efficiency of the foam in enhanced oil recovery

Due to the vast production of crude oil and consequent pressure drops through the reservoirs, secondary and tertiary oil recovery processes are highly necessary to recover the trapped oil. Among the different tertiary oil recovery processes, foam injection is one of the most newly proposed methods. In this regard, in the current investigation, foam solution is prepared using formation brine, C₁₉TAB surfactant and air concomitant with nano-silica (SiO₂) as foam stabilizer and mobility controller. The measurements revealed that using the surfactant-nano SiO₂ foam solution not only leads to formation of stable foam, but also can reduce the interfacial tension mostly considered as an effective parameter for higher oil recovery. Finally, the results demonstrate that there is a good chance of reducing the mobility ratio from 1.12 for formation brine and reservoir oil to 0.845 for foam solution prepared by nanoparticles.     

An ab initio study on properties of cationic chalcogen bonds in XF2Y+⋯NCZ (X═H,CN, F; Y═S,Se; Z═H,Cl, Br) complexes

The geometries, interaction energies, and bonding properties of cationic chalcogen bonds are studied in binary complexes XF₂Y⁺?NCZ (X═H, CN, F; Y═S, Se; Z═H, Cl, Br). The nature of these interactions is studied by a vast number of methods, including molecular electrostatic potential (MEP), Noncovalent Interaction Index (NCI), quantum theory of atoms in molecules (QTAIM), and natural bond orbital (NBO) analyses. The interaction energies of these complexes vary between ?20.94?kcal/mol in HF₂S⁺?NCH and ?33.72?kcal/mol in F₃Se⁺?NCBr. According to the QTAIM analysis, all these cationic chalcogen bonds are classified as a closed-shell interaction with a partial covalent character. Moreover, cooperative effects between cationic chalcogen bond and hydrogen or halogen bond interactions are studied in ternary XF₂Y⁺?NCZ?NH₃ complexes. These cooperative effects are analyzed in terms of the parameters derived from the QTAIM and NBO analyses, and electron density difference plots.     

Work sequencing in a manufacturing cell with limited labour constraints

This study focuses on the analysis of group scheduling heuristics in a dual-constrained, automated manufacturing cell, where labour utilization is limited to setups, tear-downs and loads/unloads. This scenario is realistic in today's automated manufacturing cells. The results indicate that policies for allocating labour to tasks have very little impact in such an environment. Furthermore, the performance of efficiency oriented, exhaustive, group scheduling heuristics deteriorated while the performance of the more complex, non-exhaustive heuristics improved. Thus, it is recommended that production managers use the simplest labour scheduling policy, and instead focus their efforts to activities such as job scheduling and production planning in such environments.