全文获取类型
收费全文 | 2690篇 |
免费 | 144篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 38篇 |
综合类 | 2篇 |
化学工业 | 562篇 |
金属工艺 | 63篇 |
机械仪表 | 95篇 |
建筑科学 | 130篇 |
矿业工程 | 2篇 |
能源动力 | 211篇 |
轻工业 | 414篇 |
水利工程 | 16篇 |
石油天然气 | 14篇 |
无线电 | 175篇 |
一般工业技术 | 526篇 |
冶金工业 | 127篇 |
原子能技术 | 39篇 |
自动化技术 | 426篇 |
出版年
2024年 | 10篇 |
2023年 | 28篇 |
2022年 | 56篇 |
2021年 | 113篇 |
2020年 | 108篇 |
2019年 | 115篇 |
2018年 | 130篇 |
2017年 | 110篇 |
2016年 | 149篇 |
2015年 | 86篇 |
2014年 | 121篇 |
2013年 | 250篇 |
2012年 | 163篇 |
2011年 | 207篇 |
2010年 | 158篇 |
2009年 | 182篇 |
2008年 | 151篇 |
2007年 | 126篇 |
2006年 | 97篇 |
2005年 | 71篇 |
2004年 | 68篇 |
2003年 | 44篇 |
2002年 | 49篇 |
2001年 | 19篇 |
2000年 | 15篇 |
1999年 | 30篇 |
1998年 | 41篇 |
1997年 | 22篇 |
1996年 | 23篇 |
1995年 | 13篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 3篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1972年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有2840条查询结果,搜索用时 0 毫秒
101.
Baki Hazer Songun I. Demirel Mehlika Borcakli Mehmet S. Eroglu Miko Cakmak Burak Erman 《Polymer Bulletin》2001,46(5):389-394
Summary
Poly(-3-hydroxy alkanoate) containing unsaturated side chains, PHA-soybean, were produced by feeding Pseudomonas oleovorans with soybean oily acids obtained from soybean oil. Unsaturation of PHA-soybean were found to be 10 mol-% of unsaturated side
chains.
Main saturated part of the biopolymer was Poly(3-hydroxy octanoate) with minor hexanoate and decanoate units. PHA films were
crosslinked via free radical mechanism by means of thermally or under UV irradiation in the presence of benzoyl peroxide,
benzophenon, and /or ethylene glycol dimethacrylate (EGDM). Crosslinking yield of the PHA films were found to be from 81 to
93 wt.-% from the sol-gel analysis. Swelling properties of the crosslinked PHA films in chloroform and toluene were also studied.
Mc values of crosslinked PHAs were also calculated using Flory-Rehner equation. The crosslinked biopolyester obtained by thermally
at 60 °C with benzoyl peroxide indicated the highest crosslinking density. Glass transition temperatures (Tg) of crosslinked
biopolyester samples were changed from −33 to −45 °C while that of PHA-soybean was −60 °C.
Received: 16 June 2000/Revised version: 22 January 2001/Accepted: 20 May 2001 相似文献
102.
ABSTRACT Treatments of phenol formaldehyde producing wastewater (PFPW) by electrooxidation (EO) and electro-Fenton (EF) successive processes were carried out in a batch electrolytic reactor using graphite (Gr) and stainless steel (Ss) electrodes. After the completion of the EO process, the wastewater was further treated with EF process. The influence of operating variables such as current density, operating time, initial pHi and H2O2 concentration was evaluated for removals of phenol, TOC and COD in PFPW. Gr/Gr, Gr/Ss or Ss/Ss and Ss/Gr electrode pair were used as anode and cathode. The best removal efficiency in the EO process was obtained with Gr/Gr (93%) as compared to Gr/Ss (82%), Ss/Ss (63%) and Ss/Gr (55%). The removal efficiencies for the EO process using Gr-Gr electrode pair were obtained as 93% for phenol, 61% for COD and 44% for TOC at initial pHi 7,5 g/L of NaCl, 50 mA/cm2 and 5 h. In the EF process, the removal efficiencies at pHi 3,5 mA/cm2 and 30 mM H2O2 and 45 min were 100% for phenol, 76% for COD and 59% for TOC. This study provided that the successive processes are an effective method for the removal of phenolic compounds from the wastewater. 相似文献
103.
There has been a great interest in research towards elastomers and their composites with an attempt to obtain the desired biological and mechanical response to scaffold materials in bone tissue engineering. Composites made of ceramic-thermoplastic mixtures have been shown success to deliver the inorganic component while fail to provide replacement of an elastic protein, that is, collagen, of the target bone tissue. Thus, in order to match up with the inherent elasticity of the native tissue, it is proposed an alternative to well-known thermoplastic-containing matrices by using a poly(glycerol-sebacate) (PGS)–beta-tricalcium phosphate elastomeric composite to offer flexibility and mechanical integrity. This study reports for the first time a successful extrusion of PGS containing biodegradable composites with shape-memory feature. The resulting structures are physically and chemically characterized. In vitro cell culture performance of the obtained materials is investigated by using an MC3T3-E1 mouse preosteoblast cell line. The materials obtained in this study can be shaped into the desired size and various forms via temperature stimuli. Resulting materials have been proposed for craniofacial tissue engineering as a bone filler in which surgeons need to shape biomaterials during the surgical procedure due to the complex geometry of the bones. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 137, 48689. 相似文献
104.
Dr. Taha Bilal Uyar Dr. Kui Wu Muhan He Dr. Irfan Khan Prof. Maksim Royzen Prof. Mehmet V. Yigit 《ChemMedChem》2020,15(11):988-994
Monitoring the release and activation of prodrug formulations provides essential information about the outcome of a therapy. While the prodrug delivery can be confirmed by using different imaging techniques, confirming the release of active payload by using imaging is a challenge. Here, we have discovered that the switchable fluorescence of doxorubicin can validate drug release upon its uncaging reaction with a highly specific chemical partner. We have observed that the conjugation of doxorubicin with a trans-cyclooctene (TCO) diminishes its fluorescence at 595 nm. This quenched fluorescence of the doxorubicin prodrug is recovered upon its bond-cleaving reaction with tetrazine. Clinically assessed iron oxide nanoparticles were used to formulate a doxorubicin nanodrug. The release of doxorubicin from the nanodrug was studied under various experimental conditions. A fivefold increase in doxorubicin fluorescence is observed after complete release. The studies were carried out in vitro in MDA-MB-231 breast cancer cells. An increase in Dox signal was observed upon tetrazine administration. This switchable fluorescence mechanism of Dox could be employed for fundamental studies, that is, the reactivity of various tetrazine and TCO linker types under different experimental conditions. In addition, the system could be instrumental for translational research where the release and activation of doxorubicin prodrug payloads can be monitored by using optical imaging systems. 相似文献
105.
Hynek Biederman Ismail H. Boyaci Petra Bilkova Danka Slavinska Selma Mutlu Josef Zemek Miroslava Trchova Josef Klimovic Mehmet Mutlu 《应用聚合物科学杂志》2001,81(6):1341-1352
Cellulose acetate membranes (CA) were modified by means of plasma polymerization of ethylene diamine (EDA) and n‐butylamine (n‐BA). The motivation for this work was the application of a modified membrane for the single‐layer enzyme electrode. A tubular reactor with the external radiofrequency (13.56 MHz) excitation was used. Surface modification was performed at 5, 10, and 15 W power (at 27 Pa working pressure) for 5, 10, 15 min. Modified surfaces were characterized in detail by FTIR–ATR, XPS (ESCA), contact angle, and enzyme immobilization activity. The best treatment results were obtained for EDA with 5 W and 30 min and 15 W and 10 min. These results are discussed using surface analysis data. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1341–1352, 2001 相似文献
106.
Commercially available chlorinated polypropylene has been used as a macroinitiator for the Cu(0)‐mediated atom transfer radical polymerization of methyl methacrylate and tert‐butyl acrylate to obtain well‐defined graft copolymers. The relatively narrow molecular weight distribution in the graft copolymers and linear kinetic plots indicated the controlled nature of the copolymerization reactions. Both Fourier transform infrared and 1H NMR studies confirmed that the graft reactions had taken place successfully. After graft copolymer formation, tert‐butyl groups of poly(tert‐butyl acrylate) side chains were completely converted into poly(acrylic acid) chains to afford corresponding amphiphilic graft copolymers. © 2016 Society of Chemical Industry 相似文献
107.
Melek Akman Makbule Bilge Akbulut Mehmet Burak Güneşer Ayçe Ünverdi Eldeniz 《Journal of Adhesion Science and Technology》2016,30(5):459-467
To evaluate the effect of intracanal medicaments on the push-out bond strength of Biodentine in comparison with DiaRoot BioAggregate (BA) when used as apical plugs. Forty single-rooted teeth were prepared using Peeso reamers. The samples were divided into four groups. The intracanal medicaments were applied to the root canals as follows: Group1: a combination of metronidazole–ciprofloxacin–cefaclor, Group2: a combination of metronidazole–ciprofloxacin, Group3: calcium hydroxide, and Group4: no medication. After 21 days, the medicaments were removed. The apical part of each root was horizontally sectioned into 1-mm thick slices. The samples were divided into two subgroups, and the following materials were placed: Biodentine, DiaRoot-BioAggregate. After 48-h incubation, the push-out bond strength was measured. The data were analyzed by a two-way ANOVA. Biodentine showed a significantly higher mean push-out bond strength value than DiaRoot-BioAggregate (P = 0.00). The medications have an effect on the push-out bond strength of both materials (P = 0.002). Biodentine showed better adhesive performance as an apical plug than DiaRoot-BioAggregate. 相似文献
108.
109.
110.
Native, iminodiacetic acid and triethylenetetraamine modified biomasses of Funalia trogii were used for removal of Congo Red dye (CRD) from aqueous medium. The native and modified fungal biomasses were characterized using ATR-FTIR, Zeta potential, contact angle studies and analytical methods. FTIR studies of the native and chemically modified adsorbent preparations show that amine, carboxyl and hydroxyl groups are involved in the adsorption of the model dye (i.e., Congo Red). The maximum adsorption of the CRD on the native, carboxyl and amine groups modified fungal biomasses was obtained at pH 5.0. The amount of adsorbed dye on the adsorbent samples increased as the initial concentration of CRD in the solution increased to 200mg/L. The adsorption capacities of native, carboxyl groups and amine modified fungal preparations were 90.4, 153.6 and 193.7mg/g dry adsorbents, respectively. The data was fitted well with the Langmuir isotherm model, and followed the pseudo-second-order equations. Thermodynamic parameters (ΔG o , ΔH o and ΔS o ) were also calculated. The results showed that triethylenetetraamine (TETA) modified biomass of F. trogii presented an excellent dye removal performance and can be used in various environmental applications such as various micro-pollutants removal from aqueous medium. 相似文献