用于气相色谱进行气体分析的一种定量分析方法

用气相色谱来分析气体混合物已有过许多报导。通常使用的进样方法是用六通进样阀系统导入或由气密性的注射器进行。但前者气样用量较大,后者则易于造成较大的操作误差,所以对于样量较少的气体混合物的定量分析常常给分析人员带来较大困难。例如在安瓿瓶中进行气发生率试验的测定等。为此,本文提出了一种简便而行之有效的分析方法,以满足生产和科研的需要。     

A NEW Ba-W DISPENSER CATHODE IMPREGNATED WITH BARIUM YTTERBATE

A new kind of Ba-W dispenser cathode impregnated with barium ytterbate has been deve-loped.It has good properties;high coefficient of secondary emission,strong ability of resisting oxygenpoisoning,high thermionic emission current density and more uniform emission on the cathode surface.The cathode is suitable for using as an electron emitter for microwave tubes,especially magnetrons.     

YDQC-500Ⅱ型强磁选机的分选数学模型研究

阐述了YDQC -5 0 0Ⅱ型强磁选机的永磁旋转磁系和精矿传送带的多功能性 ,分析分选的最佳形式及条件 ,并对磁性颗粒进行受力分析 ,得出数学模型     

基于Tent映射的混沌粒子群优化算法及其应用

针对基本粒子群优化算法在迭代后期易陷入局部最优而出现早熟收敛的现象,基于混沌搜索的全局遍历性、随机性和规律性的特点,以粒子群群体适应度方差作为粒子群优化算法早熟收敛的判据,将Tent映射作为混沌搜索引入到基本粒子群算法中,对以一定概率随机选择的粒子群中的部分粒子实施混沌搜索,利用混沌特性提高种群的多样性和粒子搜索的遍历性,从而使粒子获得持续搜索的能力,提高了粒子群优化算法的全局搜索能力和抗早熟收敛性能.几个典型测试函数的仿真实验和应用实例均证明了该算法的可行性.     

国内外雨水花园研究综述

系统归纳国内外雨水花园的研究现状,明确了国内的研究内容主要涉及雨水花园的起源与发展、国外优秀案例介绍、雨水花园的营造技术、雨水花园场地试验及模型构建等;国外的研究内容主要涉及雨水花园的水文模拟研究、土壤渗透力研究、污染物滞留能力研究、不同植物应用对水文的影响、建造及应用等,为今后的雨水花园研究工作奠定基础和提供借鉴。     

Electrochemical behaviors of double-walled carbon nanotubes encapsulating ferrocene

Electrochemical properties of a novel nanohybrid material, ferrocene-filled double-walled carbon nanotubes (Fc@DWNTs), have been successfully investigated for the first time by preparing different kinds of Fc@DWNTs modified glassy carbon electrodes. One pair of surface-confined redox waves corresponding to the couple of Fc/Fc+ is obtained, indicating Fc encapsulated in DWNTs retains electrochemical activity. Significantly differing from those of ferrocene-filled single-walled carbon nanotubes (Fc@SWNTs), Fc@DWNTs shows a specific electrochemical behavior, typically exhibiting thin-layer electrochemical characteristics at low scan rates, whereas diffusion-confined characteristics at high scan rates. The results indicate that the novel nanohybrid material possessing excellent electrochemical properties may have possible applications in constructing specific chemical and biological sensors.     

浅议柱下独基加防水板基础设计

通过对独基加防水板实际工程设计经验的总结,对防水板的受力特点、计算原则、构造措施及设计建议进行探讨。     

稀土Gd-铁粉煤灰预处理甲基橙模拟染料废水的研究

以甲基橙模拟染料废水为处理对象,微电解法为主体工艺,采用铁屑和粉煤灰作为微电解填料,以获得粉煤灰资源化利用的新途径,并探讨稀土Gd催化提高微电解处理效果的新方法。结果表明,粉煤灰可以替代活性炭参与微电解反应,并有良好的处理效果,稀土Gd能明显加快反应速率并提高甲基橙的脱色率和降解率。试验最佳运行参数:进水pH为3.5,反应时间60 min,稀土Gd以Gd3+溶液(3.08 g/L)形式投加,投加量为10 mL,铁粉煤灰投加量为150 g/L,m(粉煤灰)∶m(铁屑)为2∶1。     

Recent Advances in Mechanical Vibration Energy Harvesters Based on Triboelectric Nanogenerators

With the development of autonomous/smart technologies and the Internet of Things (IoT), tremendous wireless sensor nodes (WSNs) are of great importance to realize intelligent mechanical engineering, which is significant in the industrial and social fields. However, current power supply methods, cable and battery for instance, face challenges such as layout difficulties, high cost, short life, and environmental pollution. Meanwhile, vibration is ubiquitous in machinery, vehicles, structures, etc., but has been regarded as an unwanted by-product and wasted in most cases. Therefore, it is crucial to harvest mechanical vibration energy to achieve in situ power supply for these WSNs. As a recent energy conversion technology, triboelectric nanogenerator (TENG) is particularly good at harvesting such broadband, weak, and irregular mechanical energy, which provides a feasible scheme for the power supply of WSNs. In this review, recent achievements of mechanical vibration energy harvesting (VEH) related to mechanical engineering based on TENG are systematically reviewed from the perspective of contact–separation (C-S) and freestanding modes. Finally, existing challenges and forthcoming development orientation of the VEH based on TENG are discussed in depth, which will be conducive to the future development of intelligent mechanical engineering in the era of IoT.     

Ferrocene peapod modified electrodes: preparation, characterization, and mediation of H2O2

Electrochemical properties of a new nanomaterial ferrocene (Fc) peapod, Fc-filled single-walled carbon nanotubes (Fc@SWNTs), have been investigated in an aqueous solution in detail by preparing different kinds of Fc@SWNTs-modified glassy carbon electrodes (Fc@SWNTs/GCE and Fc@SWNTs-gel/GCE). One pair of surface-confined redox waves corresponding to the couple of Fc/Fc+ is obtained, which indicates that Fc encapsulated inside SWNTs retains electrochemical activity. The Fc@SWNTs-gel/GCE shows better electrochemical reversibility due to the existence of room temperature ionic liquid (RTIL). Furthermore, it shows excellent mediation of H2O2 based on Fc/Fc+ used as electron-transfer mediators for oxidation of H2O2 to O2 and reduction to H2O, suggesting specific properties of Fc@SWNTs due to a combination of Fc and SWNTs. The interaction between Fc and SWNTs is also characterized by UV-vis-NIR spectrometry and Raman spectrometry. A Fc@SWNTs-based sensor for H2O2 with a determination limit of 5 microM is fabricated, and it shows good stability and reproducibility. This work not only demonstrates that the Fc peapod is a new kind of functional nanomaterial but also appears promising in constructing novel chemical and biosensors and fuel cells.