Opportunities in nanometer sized Si wires for PV applications

Quantum-confined silicon material has been a very active field of research in the years 1990–2000 with the rapid development of opto-electronics. The main application targeted by this research was a light-emitting device (either LED, or laser). In the years 2000–2010, with the emerging need for efficient and cheap photovoltaic devices, new materials, and in particular new silicon-based materials trigger again a special interest. In particular, all-crystalline-Si tandem solar cells where the high-bandgap material is provided by the 2D confinement of excitons in nm-sized nanowires could provide the high-efficiency potential of a tandem device, while taking benefit of the decade-long buildup of knowhow of crystalline silicon material technology (both science and processing). In a first part of this review, we summarize the features described in the relevant literature for the functioning of a photovoltaic device based on Si NWs. This literature shows that from the conceptual point of view such an all-crystalline-Si-tandem solar cell using quantum confined nanowires should be feasible to produce in order to achieve the goal of inexpensive high efficiency (>30%) Si-based solar cells. Keeping the fabrication of efficient photovoltaic devices as driving theme, we review the dense literature of Si nanowires. The literature on the fabrication of nanometer-sized Si nanowires is reviewed in the second part.     

Capture of Co(II) from its aqueous EDTA-chelate by DTPA-modified silica gel and chitosan

The adsorption of Co(II) by diethylenetriaminepentaacetic acid (DTPA)-modified silica gel and chitosan in the presence of EDTA and other interfering species was studied. Co(II) removal ranged from 93% to 96% from the solutions where Co(II) was totally chelated by EDTA. The amount of oxalate or Fe(II) did not affect the adsorption of Co(II) in the case of DTPA-chitosan. However, increasing the amount of oxalate enhanced the adsorption performance of DTPA-silica gel, probably due to the formation of new active sites on the silica gel surface. DTPA-chitosan was also effective in simulated decontamination solutions. For DTPA-silica gel, the rate of adsorption of free Co(II) was controlled by pore diffusion, but the rate of adsorption of Co(II)EDTA was controlled by the surface chelation reaction, which was attributed to the inhibited diffusion of Co(II)EDTA inside the silica gel mesopores. However, the macroporous structure of DTPA-chitosan enabled pore diffusion of both Co(II) and Co(II)EDTA. The equilibrium isotherms of DTPA-silica gel were best described by a BiLangmuir model, in which there are two different adsorption sites on the silica gel surface assigned to different speciations of DTPA. For DTPA-chitosan, the data fit best with a Sips model, which indicates system heterogeneity. Finally, measurements with capillary electrophoresis showed an increase in dissolved EDTA during adsorption, demonstrating the ability of DTPA-modified adsorbents to release Co(II) from its EDTA chelate. This promising result can provide a basis for applying the studied materials to the treatment of water effluents containing Co(II) chelated by EDTA by a simple one-step adsorption process.     

Does contextual cuing guide the deployment of attention?

Contextual cuing experiments show that when displays are repeated, reaction times to find a target decrease over time even when observers are not aware of the repetition. It has been thought that the context of the display guides attention to the target. The authors tested this hypothesis by comparing the effects of guidance in a standard search task with the effects of contextual cuing. First, in standard search, an improvement in guidance causes search slopes (derived from Reaction Time × Set Size functions) to decrease. In contrast, the authors found that search slopes in contextual cuing did not become more efficient over time (Experiment 1). Second, when guidance was optimal (e.g., in easy feature search), they still found a small but reliable contextual cuing effect (Experiments 2a and 2b), suggesting that other factors, such as response selection, contribute to the effect. Experiment 3 supported this hypothesis by showing that the contextual cuing effect disappeared when the authors added interference to the response selection process. Overall, the data suggest that the relationship between guidance and contextual cuing is weak and that response selection can account for part of the effect. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Strategies to enhance employee well‐being and organisational performance in a postcrisis environment: A case study

Business Continuity Management processes aim at getting businesses backup and running after a crisis or disaster, but do not necessarily have a focus on the longer‐term, people‐related challenges that can follow. This study, based on a longitudinal, action‐research case study, demonstrates how employee well‐being and organisational performance of an organisation were affected over 2 years after the Canterbury earthquakes (2010–2011), in New Zealand. It details the organisational actions taken to improve staff resilience and well‐being, and their performance, including: acknowledgement, increased autonomy, process flexibility, and focus on well‐being. These lessons are presented to guide organisational strategies for crisis recovery. The strategies can strengthen organisations’ adaptive capacity and increase performance in the long‐term aftermath of a disaster.     

A Broadband Double-Conversion RF Tuner

A prototype design of upconverter and downconverter units for a double-conversion cable-modem RF tuner are presented. The upconverter upconverts a channel from 47–862 MHz input band to around 1575 MHz intermediate frequency. The image-reject downconverter shifts the channel to 36.125 MHz (EU) or to 43.75 MHz (US). The upconverter includes a variable-gain low-noise amplifier, a double-balanced mixer, a three-stage VCO bank for LO generation and a divide-by-two circuit for driving an external PLL. The downconverter includes a LNA, image-reject mixers in Hartley configuration, a 3-stage polyphase filter, an IF-amplifier and a SAW driver. For the second LO generation the circuit includes a 6-GHz on-chip VCO, a divide-by-four circuit for quadrature LO and a divide-by-16 for feeding an external PLL. Signal reversal switching in the LO buffer can be used for the selection of LSB/USB injection. All building blocks are presented in this paper and experimental results are given from the upconverter, downconverter, and RF tuner demonstrator including SAW filters with center frequencies at 1575 and 44 MHz. The circuits are fabricated in a 0.9- m SiGe bipolar process.Kari Stadius received the M.Sc. degree in electrical engineering in 1994 and the Licentiate of Technology degree in 1997, both from Helsinki University of Technology, where he is currently working as a research scientist. His research interests include the design and analysis of RF transceiver blocks with special emphasis on RF oscillators and modelling of passive components.Arto Malinen was born in Savonlinna, Finland, in 1978. He received the M.Sc. degree in electrical engineering from the Helsinki University of Technology (HUT), Finland, in 2003, where he is currently working towards the Ph.D. degree. He is a research engineer with the Electronic Circuit Design Laboratory, HUT. His main research interests are in RF IC design, including low-noise amplifiers and mixers.Petri S. Järviö was born in Kitee on December 10, 1975. He received the M.Sc (EE) degree in 2001 from the Helsinki University of Technology. From 1999 to 2001 he worked as a research assistant at the Electronic Circuit Design Laboratory in Helsinki University of Technology. Nowadays he works at Finnish Defence Forces Technical Research Centre, Electronics and Information Technology Division where his research area is Radio frequency sensors.Kari A.I. Halonen was born in Helsinki, Finland, in 1958. He received the M.Sc. degree in electrical engineering from Helsinki University of Technology, Finland, in 1982, and the Ph.D. degree in electrical engineering from the Katholieke Universiteit Leuven, in Heverlee, Belgium, in 1987. From 1982 to 1984 he was employed as assistant at Helsinki University of Technology and as research assistant at the Technical Research Centre of Finland. From 1984 to 1987 he was research assistant at the E.S.A.T. Laboratory of the Katholieke Universiteit Leuven, enjoying also a temporary grant of the Academy of Finland. Since 1988 he has been with the Electronic Circuit Design Laboratory, Helsinki University of Technology, as senior assistant (1988–1990), and the director of the Integrated Circuit Design Unit of the Microelectronics Centre (1990–1993). He was on leave of absence the academic year 1992/93, acting as R{&}D manager in Fincitec Inc., Finland. From 1993 to 1996 he has been an associate professor, and since 1997 a full professor at the Faculty of the Electrical Engineering and Telecommunications, Helsinki University of Technology. He specializes in CMOS and BiCMOS analog integrated circuits, particularly for telecommunication applications. He is author or co-author of a hundred international and national conference and journal publications on analog integrated circuits.     

The effect of enzymatic treatment on blackcurrant (Ribes nigrum) juice flavour and its stability

The effects of different enzymatic treatments on the sensory profile and chemical composition, especially various phenolic compounds, sugars and fruit acids, of blackcurrant juices were investigated. In addition to pectinolytic activities, the enzymes had different cellulolytic, hemicellulolytic and glycolytic activities. The enzymatic treatments improved significantly the yield of juice, but with more fermented and astringent characteristics than juices without enzymatic hydrolysis. Enzymes with higher glycosidase activity increased astringency and the content of phenolic compounds in the juice. When the incubation temperature was elevated the contents of fruit acids increased whereas sugars and the perceived sweetness were the highest in the juices without enzymatic treatments. Despite of the significant changes in chemical composition, the sensory properties did not change significantly during 6 weeks of storage. Optimisation of the enzymatic process is crucial for juice making as maximising the juice yield or the content of phenolic compounds may produce unwanted sensory properties to the juice.     

Decomposition of residual austenite as the result of ultrasonic vibration

Conclusions We have shown that ultrasonic vibration with an amplitude of 20 and 12 at 250°C favors the decomposition of the austenite in KhVG steel, fragments the microstructure of the steel, and increases its hardness. Ultrasonic vibration of the same amplitude does not induce any significant changes in the steel at 200°C.Translated from Metallovedenie i Termicheskaya Obrabotka Metalov, No. 1, pp. 50–51, January, 1964     

Photocatalytic degradation of C.I. Acid Orange 7 by TiO2 nanoparticles immobilized onto/into chitosan‐based hydrogel

Photocatalytic degradation of dye C.I. Acid Orange 7 in aqueous solution using TiO₂/hydrogel nanocomposite under solar light simulating source was studied. Hydrogel based on chitosan, itaconic and methacrylic acid was modified with colloidal TiO₂ nanoparticles synthetized by acidic hydrolysis of TiCl₄ and commercial Degussa P25 TiO₂ nanoparticles. SEM/EDX analysis confirmed the presence of TiO₂ nanoparticles onto/into hydrogel. It was found that both types of photocatalysts efficiently removed the dye from solution, but sorption rates and photodegradation efficiency were higher in the case of colloidal TiO₂ nanoparticles. They ensured complete discoloration of dye solution. The efficiency of the reused TiO₂/hydrogel nanocomposite showed that photodegradation activity was maintained at satisfactory level after three repeated cycles of illumination. POLYM. COMPOS., 35:806–815, 2014. © 2013 Society of Plastics Engineers