High-Efficiency Organic Solar Cells Based on a Low-Cost Fully Non-Fused Electron Acceptor

A series of tetrathiophene-based fully non-fused ring acceptors (4T-1, 4T-2, 4T-3, and 4T-4), which can be paired with the star donor polymer PBDB-T to fabricate highly efficient organic solar cells are developed. Tailoring the size of lateral chains can tune the solubility and packing mode of acceptor molecules in neat and blend films. It is found that the incorporation of 2-ethylhexyl chains can effectively change the compatibility with the donor polymer PBDB-T, and an encouraging power conversion efficiency of 10.15% is accomplished by 4T-3-based organic solar cells. It also presents good compatibility with the other polymer donor and an even higher power conversion efficiency (PCE) of 12.04% is achieved based on D18:4T-3 blend, which is the champion PCE for the fully non-fused acceptors. Importantly, these inexpensive tetrathiophene fully non-fused ring acceptors provide cost-effective photovoltaic performance. The results demonstrate a high photovoltaic performance from synthetically inexpensive materials could be achieved by the rational design of non-fused ring acceptor molecules.     

Acid and Alkali-Resistant Textile Triboelectric Nanogenerator as a Smart Protective Suit for Liquid Energy Harvesting and Self-Powered Monitoring in High-Risk Environments

Industrialization and anthropogenic activities are expected and unavoidable to consummate the current resources of humankind, which also lead to accidents in the laboratory, chemical plants, or other high risk areas that cause severe burns, or even casualties. Increased casualties in such accidents are due to inappropriate safety measures and prevention. Here, a smart anti-chemical protective suit with a bio-motion energy harvesting and self-powered safety monitoring system is demonstrated, which can protect the body from chemical harm, detect sudden chemical spills, monitor human real-time living signals, and trigger alarms in an emergency. Particularly, a fabric triboelectric nanogenerator (F-TENG), which is fabricated by the all-fiber single-electrode triboelectric nanogenerator yarn (SETY), works as the basic elements of the intelligent suit. The SETY with core-shell structured design shows a high sensitivity to the corrosive liquids including acids and alkalis. Furthermore, the working principle of the yarn based nanogenerator that is powered by contacting with acid liquid droplets is demonstrated for the first time. In addition, discretionary thickness, permeability, and any other functionalities are also achieved by taking advantage of the fabric structure. This self-powered smart anti-chemical protective suit equipped with a real time monitoring system will benefit the wearer who works in a very high-risk environment.     

Efficiency Breakthrough of Fluorescence OLEDs by the Strategic Management of “Hot Excitons” at Highly Lying Excitation Triplet Energy Levels

Aggregation-induced emission (AIE) and hybridized local and charge-transfer (HLCT) materials are two kinds of promising electroluminescence systems for the fabrication of high-efficiency organic light-emitting diodes (OLEDs) by harnessing “hot excitons” at the high-lying triplet exciton states (T_n, n ≥ 2). Nonetheless, the efficiency of the resulting OLEDs did not meet expectations due to the possible loss of T_n→T_n−1. Herein, experimental results and theoretical calculations demonstrate the “hot exciton” process between the high-lying triplet state T₃ and the lowest excited singlet state S₁ in an AIE material 4⁗-(diphenylamino)-2″,5″-diphenyl-[1,1″:4′,1″:4″,1′″:4′″,1⁗-quinquephenyl]-4-carbonitrile (TPB-PAPC) and it is found that the Förster resonance energy transfer (FRET) between two molecules can facilitate the “hot exciton” process and inhibit the T₃→T₂ loss by doping a blue fluorescent emitter in TPB-PAPC. Finally, the doped TPB-PAPC blue OLEDs achieve a maximum external quantum efficiency (EQE_max) of 9.0% with a small efficiency roll-off. Furthermore, doping the blue fluorescent emitter in a HLCT material 2-(4-(10-(3-(9H-carbazol-9-yl)phenyl)anthracen-9-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d] imidazole (PAC) is used as the emission layer, and the resulting blue OLEDs exhibit an EQE_max of 17.4%, realizing the efficiency breakthrough of blue fluorescence OLEDs. This work establishes a physical insight in the design of high-performance “hot exciton” molecules and the fabrication of high-performance blue fluorescence OLEDs.     

基于DriveWindows的穿孔机主传动系统的故障诊断

天津钢管公司168新型钢管厂的穿孔机主传动采用ACS6000SD中压变频传动系统驱动,通过DriveWindows软件对传动系统进行监视、调试和故障诊断,能大大提高效率。本文介绍了DriveWindows的基本功能,重点通过实际故障分析与解决的实例,讲述基于DriveWindows的ACS6000SD中压传动系统的故障诊断。实践表明,使用DriveWindows,能大大提升ACS6000系统的故障分析与解决的效率,使得传动系统能有效安全的运行,具有较大的实用价值。     

Facilitation of Gene Transfection and Cell Adhesion by Gelatin‐Functionalized PCL Film Surfaces

Efficient local gene transfection on a tissue scaffold is of crucial importance in facilitating tissue repair and regeneration. In this work, the gelatin‐functionalized polycaprolactone (PCL) film surfaces are prepared via surface‐initiated atom transfer radical polymerization of glycidyl methacrylate. The resultant covalent attachment of gelatin could enhance the cell‐adhesion and local gene transfection properties. The gelatin‐functionalized PCL film surfaces exhibit excellent cell‐adhesion ability to both adherent and suspension cells. The attached adherent cells demonstrate the characteristic elongated morphologies with good spreading capability, while the attached suspension cells can maintain the original status of the round morphologies without spreading. More importantly, the gelatin coupled on the PCL surface could be used to absorb the cationic vector/plasmid deoxyribonucleic acid (pDNA) complexes via electrostatic interaction. The local gene transfection property on the immobilized cells is dependent on both the density of the immobilized cells and the loading types of pDNA complexes. The transfection efficiency of different assemble methods of pDNA complex was compared. With the pre‐ and post‐loading sandwich‐like gene transfection, the gelatin‐functionalized PCL film surface can substantially enhance the transfection properties to different cell lines. The present study is very useful to spatially control local gene delivery within PCL‐based tissue scaffolds.     

Power‐efficient resource allocation with QoS guarantees for TDMA fading channels

This paper proposes two power‐efficient resource allocation policies with statistical delay Quality of Service (QoS) guarantees for uplink time‐division multiple access (TDMA) communication links. Specifically, the first policy aims at maximizing the system throughput while fulfilling the delay QoS and average power constraints, and the second policy is devised as an effort to minimize the total average power subject to individual delay QoS constraints. Convex optimization problems associated with the resource allocation policies are formulated based on a cross‐layer framework, where the queue at the data link layer is served by the resource allocation policy. By employing the Lagrangian duality theory and the dual decomposition theory, two subgradient iteration algorithms are developed to obtain the globally optimal solutions. The aforementioned resource allocation policies have been shown to be deterministic functions of delay QoS requirements and channel fading states. Moreover, numerical results are provided to demonstrate the performance of the proposed resource allocation policies. Copyright © 2010 John Wiley & Sons, Ltd.     

Bottom-contact small-molecule n-type organic field effect transistors achieved via simultaneous modification of electrode and dielectric surfaces

Low-voltage, n-type organic field effect transistors (OFETs) with simultaneously modified bottom-contact (BC) electrodes and dielectric were compared to their top-contact (TC) counterparts. The devices modified with 6-phenoxyhexylphosphonic acid (Ph6PA) self-assembled monolayer (SAM) showed similar performance, morphology, and contact resistance. Electron mobility of C₆₀ devices were 0.212 and 0.320 cm² V⁻¹ s⁻¹ and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PCBM) devices were 0.04 and 0.06 cm² V⁻¹ s⁻¹ for TC and BC devices, respectively. Low contact resistance between 11 and 45 kΩ cm was found regardless of device architecture or n-type semiconductor used. This work shows it is possible to fabricate solution processable low-voltage bottom-contact devices with performance that is similar or better than their top-contact counterparts without the addition of complex and time-consuming processing steps.     

TD-LTE网络PCI评估研究

TD-LTE系统设计了504个PCI,PCI规划要求不冲突、不混淆,本文重点介绍了一种针对规划的PCI评估的方法。该评估方法将TD-LTE网络覆盖进行栅格化,针对每个栅格进行统计PCI的模3干扰程度,将所有栅格的模3干扰程度进行累积以表征整个网络的PCI模3干扰程度,以期指导PCI前期规划及后期优化,避免了通过现场拉网测试进行的模3干扰判断的局部性及大量的时间和人力成本,本研究以全局整体的角度来进行PCI的评估呈现整个网络的PCI模3干扰情况。     

电信建筑在岩溶发育地区的地基基础设计

结合新密电信综合生产楼工程和贵阳第二长途电信枢纽楼工程的设计，介绍在岩溶发育场地上，对浅层岩溶地基的处理方法及基础类型的选择思路。     

石油钻机的变频改造

本文以大庆油田石油管理局井下作业分公司配备的风光JD-BP32-500型石油钻机变频器为例，介绍了石油钻机进行变频改造的意义、应用效果及使用价值。由于石油钻机的特殊的应用环境，在变频器的产品设计方面注意到了相关的技术难点，为该类广品的开发提供了相关的依据。