Selective removal of Cr(VI) ions from aqueous solutions including Cr(VI), Cu(II) and Cd(II) ions by 4-vinly pyridine/2-hydroxyethylmethacrylate monomer mixture grafted poly(ethylene terephthalate) fiber

In this study, a new reactively fibrous adsorbent was prepared by grafting 4-vinly pyridine (4-VP) and 2-hydroxyethylmethacrylate (HEMA) monomer mixture onto poly(ethylene terephthalate) (PET) fibers for removal of Cr(VI), Cu(II) and Cd(II) metal ions from aqueous solution by using batch adsorption method. The influence of various parameters such as graft yield (GY), pH, adsorption time, initial ion concentration and adsorption temperature was investigated. The selectivity of the reactive fiber was also examined. The results show that the adsorbed amount of metal ions followed as given in the order Cr(VI) > Cd(II) > Cu(II). At pH 3, Cr(VI) was removed by 99% while the initial concentration of ions was at 5 mg L⁻¹ and by 94% at 400 mg L⁻¹. It was found that the grafted fiber is more selective for Cr(VI) ions in the mixed solution of Cr(VI)–Cu(II), Cr(VI)–Cd(II) and Cr(VI)–Cu(II)–Cd(II) at pH 3 and it was observed that the grafted fibers are stable and regenerable by acid and base without losing their activity.     

Coupling of non‐conforming meshes in a component mode synthesis method

A common mesh refinement‐based coupling technique is embedded into a component mode synthesis method, Craig–Bampton. More specifically, a common mesh is generated between the non‐conforming interfaces of the coupled structures, and the compatibility constraints are enforced on that mesh via L2‐minimization. This new integrated method is suitable for structural dynamic analysis problems where the substructures may have non‐conforming curvilinear and/or surface interface meshes. That is, coupled substructures may have different element types such as shell, solid, and/or beam elements. The proposed method is implemented into a commercial finite element software, B2000++, and its demonstration is carried out using an academic and industry oriented test problems. Copyright © 2013 John Wiley & Sons, Ltd.     

The femoral sulcus angle in neonatal cadavers: a macroscopical and ultrasonographical study

A modification in the design of the pedicled latissimus dorsi musculocutaneous flap is described that aims to minimize the cosmetic morbidity of its donor site. The implications of this variation are discussed with particular reference to use of the flap in postmastectomy reconstruction.     

Hard iron boride (Fe2B) on 99.97 wt% pure iron

Some properties such as hardness and fracture toughness of boride formed on the 99.97 wt% pure iron were investigated. Boronizing was carried out in a solid medium, consisting of Ekabor powders of 5% B₄C as donor, 5% KBF₄ as an activator and 90% SiC as diluent at 800 °C for 2, 4 and 8 h. The dominant phase formed on the substrate was found to be Fe₂B that had a finger-like shape morphology. The hardness of boride on the 99.97% pure iron was over 1700HVN, while the hardness of pure iron was about 130HVN. It was found that the fracture toughness of boride formed on surfaces of 99.97% pure iron, depending on the process time, ranged from 3.59 to 3.83 MPa m^1/2. Depending on process time and temperature, the depth of the boride layer ranges from 22 to 43 μm, leading to a diffusion-controlled process.     

Single and multilayered a-SiOx:H (x < 1) thin film samples analyzed by optical absorption and small-angle X-ray scattering

Hydrogenated amorphous silicon oxygen alloy thin films (a-SiO_x:H) were prepared on glass and crystalline silicon substrates, with two different oxygen contents: x = 0.15 and x = 0.32. The deposition was realized in an RF-PECVD reactor by using the plasma of the gas mixture SiH₄ and CO₂ with tunable flow rates. The optical characterization data of the single layers were received from the optical transmittance experiments. Multilayered samples were designed upon the results of the single layers. In depositing the multilayers the repetition of the a-SiO_0.15:H/a-SiO_0.32:H kernel-pair was used. The samples were prepared as 25-pair of λ/4 layers, 3-pair of λ/4 layers and 3-pair of λ/2 layers. The inner morphologies and nanostructural contents of the films were investigated by Small-Angle X-ray Scattering (SAXS) method.     

Bio‐Hybrid Cell‐Based Actuators for Microsystems

As we move towards the miniaturization of devices to perform tasks at the nano and microscale, it has become increasingly important to develop new methods for actuation, sensing, and control. Over the past decade, bio‐hybrid methods have been investigated as a promising new approach to overcome the challenges of scaling down robotic and other functional devices. These methods integrate biological cells with artificial components and therefore, can take advantage of the intrinsic actuation and sensing functionalities of biological cells. Here, the recent advancements in bio‐hybrid actuation are reviewed, and the challenges associated with the design, fabrication, and control of bio‐hybrid microsystems are discussed. As a case study, focus is put on the development of bacteria‐driven microswimmers, which has been investigated as a targeted drug delivery carrier. Finally, a future outlook for the development of these systems is provided. The continued integration of biological and artificial components is envisioned to enable the performance of tasks at a smaller and smaller scale in the future, leading to the parallel and distributed operation of functional systems at the microscale.     

Ge-Si-O phase separation and Ge nanocrystal growth in Ge:SiO(x)/SiO(2) multilayers--a new dc magnetron approach

Ge:SiO(x)/SiO(2) multilayers are fabricated using a new reactive dc magnetron sputtering approach. The influence of the multilayer stoichiometry on the ternary Ge-Si-O phase separation and the subsequent size-controlled Ge nanocrystal formation is explored by means of x-ray absorption spectroscopy, x-ray diffraction, electron microscopy and Raman spectroscopy. The ternary system Ge-Si-O reveals complete Ge-O phase separation at 400?°C which does not differ significantly to the binary Ge-O system. Ge nanocrystals of < 5?nm size are generated after subsequent annealing below 700?°C. It is shown that Ge oxides contained in the as-deposited multilayers are reduced by a surrounding unsaturated silica matrix. A stoichiometric regime was found where almost no GeO(2) is present after annealing. Thus, the Ge nanocrystals become completely embedded in a stoichiometric silica matrix favouring the use for photovoltaic applications.     

3D Microstructures of Liquid Crystal Networks with Programmed Voxelated Director Fields

The shape-shifting behavior of liquid crystal networks (LCNs) and elastomers (LCEs) is a result of an interplay between their initial geometrical shape and their molecular alignment. For years, reliance on either one-step in situ or two-step film processing techniques has limited the shape-change transformations from 2D to 3D geometries. The combination of various fabrication techniques, alignment methods, and chemical formulations developed in recent years has introduced new opportunities to achieve 3D-to-3D shape-transformations in large scales, albeit the precise control of local molecular alignment in microscale 3D constructs remains a challenge. Here, the voxel-by-voxel encoding of nematic alignment in 3D microstructures of LCNs produced by two-photon polymerization using high-resolution topographical features is demonstrated. 3D LCN microstructures (suspended films, coils, and rings) with designable 2D and 3D director fields with a resolution of 5 µm are achieved. Different shape transformations of LCN microstructures with the same geometry but dissimilar molecular alignments upon actuation are elicited. This strategy offers higher freedom in the shape-change programming of 3D LCN microstructures and expands their applicability in emerging technologies, such as small-scale soft robots and devices and responsive surfaces.