Novel nanocomposites obtained by dispersion of LDH modified with N‐tetrabromophthaloyl‐glutamic in poly(amide‐imide) having N‐trimellitylimido‐l‐leucine and 4,4′‐diaminodiphenylether units

Layered double hydroxides (LDHs) have attracted much attention as nanofillers in polymer nanocomposites (NCs) due to their particular surface structural, positively charged layer and so on. In this study, a chiral diacid was synthesized by the reaction of tetrabromophthalic anhydride and glutamic acid. LDH was modified by co‐precipitation of aluminum nitrate, magnesium nitrate, and glutamic acid containing diacid. Chiral poly(amide‐imide) (PAI) was synthesized by direct polycondensation reaction of N‐trimellitylimido‐l ‐leucine and 4,4′‐diaminodiphenylether. Different NCs of the obtained modified LDHs and the chiral PAI were prepared in a short time using ultrasonic technique. The morphology and the structure of the obtained samples were characterized by Fourier transform infrared, thermogravimetric analysis (TGA), field emission scanning electron microscopy, transmission electron microscopy, and X‐ray diffraction analysis. TGA of the NCs showed a special order in thermal stability in compression with the neat PAI owing to the uniform distribution of the nanofillers. POLYM. COMPOS., 37:1323–1329, 2016. © 2014 Society of Plastics Engineers     

转速对6061-T6铝合金搅拌摩擦搭接焊接头力学性能的影响(英文)

采用场发射扫描电子显微镜(FE-SEM),研究转速对厚度为5 mm的6061-T6铝合金搅拌摩擦搭接焊接头的宏观和微观组织、硬度、搭接头剪切性能和失效模式的影响。结果表明:在最低的转速度下,上模板和下模板具有十分相似的硬度分布。采用EDX分析发现,焊核区的断裂面中含有Fe的化合物。     

Local enrichment of the finite cell method for problems with material interfaces

This paper proposes an efficient, hierarchical high-order enrichment approach for the finite cell method applied to problems of solid mechanics involving discontinuities and singularities. In contrast to the standard extended finite element method, where new degrees of freedom are introduced for all finite elements located in the enrichment zone, we define the enrichment on a so-called overlay mesh which is superimposed over the base mesh. The approximation on the base mesh is obtained by means of the finite cell method where the hp-d method is employed to introduce the hierarchical extension on the overlay mesh. We present two different strategies for defining the enrichment on the superimposed overlay mesh. In the first approach, the enrichment is based on a local h-, p- or hp-refinement utilizing the finite element method on the overlay mesh. Alternatively, the enrichment is constructed by means of the partition of unity method introducing carefully selected enrichment functions suitable for the problem at hand. Our results reveal that the proposed method improves the accuracy of the finite cell method significantly with only a minimum number of additional degrees of freedom. In this paper we will focus on examples with material interfaces although the method can also be applied to problems involving strong discontinuities and singularities. Accurate stress distribution and an exponential rate of convergence are the two striking characteristics of the proposed method. Due to the hierarchical approach it paves the way to using different approaches for the approximation on the base and the overlay mesh and accordingly allows multiscale problems to be addressed as well.     

Finite and spectral cell method for wave propagation in heterogeneous materials

In the current paper we present a fast, reliable technique for simulating wave propagation in complex structures made of heterogeneous materials. The proposed approach, the spectral cell method, is a combination of the finite cell method and the spectral element method that significantly lowers preprocessing and computational expenditure. The spectral cell method takes advantage of explicit time-integration schemes coupled with a diagonal mass matrix to reduce the time spent on solving the equation system. By employing a fictitious domain approach, this method also helps to eliminate some of the difficulties associated with mesh generation. Besides introducing a proper, specific mass lumping technique, we also study the performance of the low-order and high-order versions of this approach based on several numerical examples. Our results show that the high-order version of the spectral cell method together requires less memory storage and less CPU time than other possible versions, when combined simultaneously with explicit time-integration algorithms. Moreover, as the implementation of the proposed method in available finite element programs is straightforward, these properties turn the method into a viable tool for practical applications such as structural health monitoring [1–3], quantitative ultrasound applications [4], or the active control of vibrations and noise [5, 6].     

Investigation and Simulation of a Two-Channel Drop Filter with Tunable Double Optical Resonators

In this paper, a photonic crystal (PhC) two-channel drop filter based on two 2×2 & 2×3 ring resonators is proposed. This structure is made of Germanium rods in an air background at a two-dimensional (2D) square lattice. Refractive index is chosen in a way in which that device can be easily fabricated. The photonic crystal two-channel drop filter is composed using a horizontal waveguide and two ring resonators, which are placed symmetrically about the horizontal axis. These ring resonators operate as energy coupling and capture the electromagnetic energy propagated in bus waveguide at their resonance frequencies. The filter characteristics are calculated using 2D finite-difference time-domain (FDTD) and plane wave expansion (PWE) methods. We show a two-channel drop filter with two resonators, based on studied basic structures and achieving optimal modes for channel drop filters with one resonator. We have done this through choosing the proper radii for all rods of lattice, setting radii of coupling rods, lattice constant, and studying basic structures having different refractive indexes. Finally, we show 84 % and 100 % dropping efficiencies can be achieved at D and C ports in the communication window and 100 % in direct port. The size of this device is 14.56 μm (length)×11.96 μm (width). This small size makes it possible to use the device in multiplexer applications in future communication systems and in all-optical integrated circuits.     

An experimental investigation of cylindrical wire electrical discharge turning process

The cylindrical wire electrical discharge turning (CWEDT) process was developed to generate precise cylindrical forms on hard, difficult to machine materials. A precise, flexible, and corrosion-resistant submerged rotary spindle was designed and added to a conventional five-axis CNC wire electrical discharge machine (EDM) to enable the generation of free-form cylindrical geometries. The hardness and strength of the work material are no longer the dominating factors that affect the tool wear and hinder the machining process. In this study, the effect of machining parameters on surface roughness (R _a) and roundness in cylindrical CWEDT of a AISI D3 tool steel is investigated. The selection of this material was made taking into account its wide range of applications in tools, dies, and molds and in industries such as punching, tapping, reaming, and so on in cylindrical forms. Surface roughness and roundness are chosen as two of the machining performances to verify the process. In addition, power, pulse off-time, voltage, and spindle rotational speed are adopted for evaluation by full factorial design of experiments. In this case, a 2²?×?3² mixed full factorial design has been selected considering the number of factors used in the present study. The main effects of factors and interactions were considered in this paper, and regression equations were derived using response surface methodology. Finally, the surfaces of the CWEDT parts were examined using scanning electron microscopy (SEM) to identify the macro-ridges and craters on the surface. Cross sections of the EDM parts were examined using the SEM and microhardness tests to quantify the sub-surface recast layers and heat-affected zones under specific process parameters.     

Optimizing the Optoelectronic Properties of Face-On Oriented Poly(3,4-Ethylenedioxythiophene) via Water-Assisted Oxidative Chemical Vapor Deposition

Engineering the texture and nanostructure to improve the electrical conductivity of semicrystalline conjugated polymers must address the rate-limiting step for charge carrier transport. In highly face-on orientation, the charge transport between chains within a crystallite becomes rate-limiting, which is highly sensitive to the π–π stacking distance and interchain charge transfer integral. Here, face-on oriented semicrystalline poly(3,4-ethylenedioxythiophene) (PEDOT) thin films are grown via water-assisted (W-A) oxidative chemical vapor deposition (oCVD). Combining W-A with the volatile oxidant, antimony pentachloride, yields an optimized electrical conductivity of 7520  ±  240 S cm⁻¹, a record for PEDOT thin films. Systematic control of π–π stacking distance from 3.50 Å down to 3.43 Å yields an electrical conductivity enhancement of ≈ 1140%. The highest electrical conductivity also corresponds to minimum in Urbach energy of 205 meV, indicating superior morphological order. The figure of merit for transparent conductors, σ_dc/σ_op, reaches a maximum value of 94, which is 1.9 × and 6.7 × higher than oCVD PEDOT grown without W-A and utilizing vanadium oxytrichloride and iron chloride oxidizing agents, respectively. The W-A oCVD is single-step all-dry process and provides conformal coverage, allowing direct growth on mechanical flexible, rough, and structured surfaces without the need for complex and costly transfer steps.     

Phase Transformation Kinetics During Annealing of Cold-Rolled AISI 309Si Stainless Steel

Metallurgical and Materials Transactions A - The effects of cold rolling and the subsequent annealing were studied for the AISI 309Si stainless steel. During annealing of cold-rolled sheets, the...     

Weighted label propagation based on Local Edge Betweenness

The Journal of Supercomputing - In complex networks, especially social networks, networks could be divided into disjoint partitions. However, nodes could be partitioned such that the number of...     

From 2D to 3D geodesic-based garment matching

Multimedia Tools and Applications - A new approach for 2D to 3D garment retexturing is proposed based on Gaussian mixture models and thin plate splines (TPS). An automatically segmented garment of...