Room-Temperature Metal-Catalyzed Ultrafast Gasification of Ultrathin Boron Flakes

The trivalent outer shell of boron renders this element electron-poor but chemically rich, exhibiting more than one dozen allotropes. Its 2D polymorph has been recently synthesized on metal substrates under ultrahigh vacuum and has attracted intense interest. However, probing its properties ex situ has been challenging due to the quality degradation—surface oxidation—that occurs upon exposure to ambient environments. Herein, this surface chemistry is investigated in regard to the air stability of ultrathin boron flakes on metals prepared by atmospheric-pressure chemical vapor deposition. The characteristic Volmer–Weber growth is recognized by the stacking of polygon-shaped, thin flakes as isolated islands. Significantly, the metal-catalyzed, ultrafast gasification of boron flakes at room temperature, exemplified by the complete, spontaneous vanishment of 200 nm-thick boron islands in 3 h is observed. A two-step mechanism, first oxygen-involved surface oxidation and then subsequent reactions with water forming a highly volatile boric acid layer, is unambiguously revealed by combined surface characterizations. The catalysis by metal substrates, corroborated by theoretical calculations, is attributed as the crucial cause of the unprecedented gasification. The concept of oxygen-free growth is thereby proposed for air-sensitive material growth by introducing in situ oxygen scavengers. These findings significantly expand the fundamental understanding of the surface chemistry of boron and pave the way for the chemical vapor deposition growth of hydrophobic materials.     

Improved Hydrogen Capping Effect in n-Type Crystalline Silicon Solar Cells by SiN(Si-Rich)/SiN(N-Rich) Stacked Passivation

The effect of hydrogen capping of SiN(Si-rich)/SiN(N-rich) stacks for n-type c-Si solar cells was investigated. Use of a passivation layer consisting of Si-rich SiN with a refractive index (n) of 2.7 and N-rich SiN with a refractive index of 2.1 improved the thermal stability. A single SiN passivation layer with a refractive index of 2.05 resulted in an initial lifetime of 200 μs whereas the layer with a refractive index of 2.7 resulted in a high initial lifetime of 2 ms, but the layer degraded rapidly after firing. A stacked passivation layer with refractive indices of 2.1 and 2.7 had a stable lifetime of 1.5 ms with an implied open-circuit voltage (iV _oc) of 720 mV after firing. The thermally stable passivation mechanism with changing amounts of Si–N and Si–H bonding was analyzed by Fourier-transform infrared (FTIR) spectroscopy. Incorporation of the SiN _x stack layer (2.7 + 2.1) into the passivated rear of n-type Cz silicon screen-printed solar cells resulted in energy conversion efficiency of 19.69%. Improved internal quantum efficiency in the long-wavelength range above 900 nm, with V _oc of 630 mV, is mainly because of superior passivation of the rear surface compared with conventional solar cells.     

不同应变率下多壁碳纳米管/天然橡胶复合材料的抗冲击性能研究

研究多壁碳纳米管(MWNTs)/天然橡胶复合材料在不同应变率下的抗冲击性能。结果表明:随着MWNTs用量的增大,复合材料的压缩弹性模量和吸能率增大,抗冲击性能提高;在MWNTs的用量相同时,复合材料的吸能率随着应变率的增大而增大,且增幅随着MWNTs用量的增大而变大。     

基于MCU的可测试性设计

根据ＭＣＵ结构非常复杂且具有指令系统的特点,没有采用一般数字电路设计的从结构出发的ＤＦＴ技术,而是设定了ＭＣＵ的３种工作模式,提出了一种在ＭＣＵ中加入规模很小的模式选择电路,对部分电路作较小改动,就可以对芯片内的各块电路进行功能测试的方法。在完成了ＭＣＵ的可测性设计后进行了仿真,结果表明电路能正常工作在各种模式下。     

本地网计费帐务系统的实现

计费帐务系统是本地电话网中最主要的管理系统之一 ,文中从新型计费帐务系统的建设目标出发 ,阐述了本地网内计费信息的在线数据采集 ,实时、准实时计费 ,集中式帐务系统的建设原则、实现方案、软件设计与体系结构。     

海珊瑚在不同酸性条件处理下的微结构研究

本文利用扫描电镜（ＳＥＭ）观察了滨珊瑚和角孔现瑚及它们在不同酸性条件处理下的形貌和显微结构变化,并对角孔珊瑚进行了溶解失重分析。实验结果表明,为了保持珊瑚天然的微结构,以作为制备人工骨的材料,对其进行了处理环境的环境ｐＨ值不能小于３。     

Fast RSVP: Efficient RSVP Mobility Support for Mobile IPv6

In recent years, with the development of mobile communication technologies and the increase of available wireless transmission bandwidth, deploying multimedia services in next generation mobile IPv6 networks has become an inevitable trend. RSVP (resource reservation protocol) proposed by the IETF is designed for hardwired and fixed networks and can not be used in mobile environments. This paper proposes a protocol, called Fast RSVP, to reserve resources for mobile IPv6. The protocol adopts a cross-layer design approach where two modules (RSVP module and Mobile IPv6 module) at different layers cooperate with each other. Fast RSVP divides a handover process with QoS guarantees into two stages: (1) setup of the resource reservation neighbor tunnel and (2) resource reservation on the optimized route. It can help a mobile node realize fast handover with QoS guarantees as well as avoid resource wasting by triangular routes, advanced reservations and duplicate reservations. In addition, fast RSVP reserves “guard channels” for handover sessions, thus greatly reducing the handover session forced termination rate while maintaining high performance of the network. Based on extensive performance analysis and simulations, Fast RSVP, compared with existing methods of resource reservation in mobile environments, performs better in terms of packet delay and throughput during handover, QoS recovery time after handover, resource reservation cost, handover session forced termination rate and overall session completion rate.     

WDM PON中新型组播技术的研究

实现有效的组播传输是WDM PON实用化的关键技术之一,介绍了我们提出并实验验证了其可行性的几种WDM PON新型组播模式,为WDM PON技术的进一步发展和实际应用提供了参考与可选的业务组播方案.     

基于CC2430的低功耗智能家居数据采集系统

为解决家居环境中数据实时监测的问题,设计了以CC2430作为控制核心的超低功耗智能家居数据采集系统。无线传感器采集家居环境中的温度、湿度、二氧化碳浓度、光照强度等数据,通过ZigBee协议组建星状无线局域网实现与上位机的通信,在上位机中实现图形化界面显示和数据入库存储。经实验证明,该系统可实现设计目标,数据准确接收率为100%,正常工作时间超过6个月,能够实时采集家居环境中的各项参数,为家居环境的智能化改造提供了一个切实可行的方法。