首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   46017篇
  免费   3736篇
  国内免费   1528篇
电工技术   2260篇
技术理论   5篇
综合类   2388篇
化学工业   7784篇
金属工艺   2094篇
机械仪表   2333篇
建筑科学   2632篇
矿业工程   1136篇
能源动力   1432篇
轻工业   3408篇
水利工程   698篇
石油天然气   1528篇
武器工业   261篇
无线电   6628篇
一般工业技术   6376篇
冶金工业   3147篇
原子能技术   511篇
自动化技术   6660篇
  2024年   137篇
  2023年   680篇
  2022年   1262篇
  2021年   1842篇
  2020年   1389篇
  2019年   1132篇
  2018年   1260篇
  2017年   1369篇
  2016年   1254篇
  2015年   1675篇
  2014年   2076篇
  2013年   2873篇
  2012年   2816篇
  2011年   3215篇
  2010年   2624篇
  2009年   2555篇
  2008年   2620篇
  2007年   2350篇
  2006年   2201篇
  2005年   1754篇
  2004年   1419篇
  2003年   1442篇
  2002年   1604篇
  2001年   1356篇
  2000年   997篇
  1999年   883篇
  1998年   1110篇
  1997年   796篇
  1996年   671篇
  1995年   546篇
  1994年   443篇
  1993年   377篇
  1992年   290篇
  1991年   243篇
  1990年   245篇
  1989年   211篇
  1988年   178篇
  1987年   160篇
  1986年   129篇
  1985年   131篇
  1984年   117篇
  1983年   76篇
  1982年   74篇
  1981年   61篇
  1980年   83篇
  1979年   50篇
  1978年   60篇
  1977年   58篇
  1976年   76篇
  1975年   43篇
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
91.
In this paper, we propose a new approach, appearance-guided particle filtering (AGPF), for high degree-of-freedom visual tracking from an image sequence. This method adopts some known attractors in the state space and integrates both appearance and motion-transition information for visual tracking. A probability propagation model based on these two types of information is derived from a Bayesian formulation, and a particle filtering framework is developed to realize it. Experimental results demonstrate that the proposed method is effective for high degree-of-freedom visual tracking problems, such as articulated hand tracking and lip-contour tracking.  相似文献   
92.
Nanocomposites based on poly(butylene terephthalate) (PBT) and an organoclay (Cloisite 30B) were prepared by melt blending using a twin‐screw extruder. Two kinds of PBTs, ie PBT‐A and PBT‐B, with different inherent viscosities (ηinh), were used for this study (ηinh of PBT‐A and PBT‐B were 0.74 and 1.48, respectively). Dispersion of the clay layers in the PBT nanocomposites was characterized by using X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile and dynamic mechanical properties and non‐isothermal crystallization temperatures of the nanocomposites were also examined. Nanocomposites based on the higher‐viscosity PBT (PBT‐B) showed a higher degree of exfoliation of the clay and a higher reinforcing effect when compared to the composites based on the lower‐viscosity PBT (PBT‐A). The clay nanolayers dispersed in PBT matrices lead to increases in the non‐isothermal crystallization temperatures of the PBTs, with such increases being more significant for the PBT‐B nanocomposites than for the PBT‐A nanoocomposites. Copyright © 2004 Society of Chemical Industry  相似文献   
93.
Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry  相似文献   
94.
In this paper, two algebraic decoders for the (103, 52, 19) and (113, 57, 15) quadratic residue codes, which have lengths greater than 100, are presented. The results have been verified by software simulation that programs in C++ language have been executed to check possible error patterns of both quadratic residue codes.  相似文献   
95.
高压脉冲放电处理含氰废水的影响因素探讨   总被引:6,自引:0,他引:6  
焦化废水中含有大量的氰化物,必须采取有效措施进行去除,传统去除方法运行成本高、操作复杂。提出了用高压毫微秒脉冲产生的非平衡等离子体处理含氰废水的方法,对其影响因素pH值、放电时间、气流量、放电条件等进行了大量的实验研究,结果表明:溶液初始pH值为9.09,放电2 h,放电电压46 kV时氰化物的去除率最高可达93.2%,氰化物质量浓度可降至0.26 mg/L。实验对比了放电与不放电氰化物的去除效果:相同条件下放电后氰化物的去除率大大提高,为焦化废水中氰化物的去除提出了一种新的方法。  相似文献   
96.
97.
Defect equilibria for binary semiconducting compound phases which exhibit ionized native donor and acceptor defects were considered, and equations describing the pressure-temperature-composition relationships for these compound phases were derived. These equations were used to analyze experimental data from the literature for tin telluride. Excellent agreement was obtained between calculated thermodynamic and phase boundary values and experimental data. The approach presented is readily extended to obtain equations for the thermodynamic properties of ternary and higher order semiconducting compound phases.  相似文献   
98.
This study used different metals to modify Rh/Al2O3 catalysts for NO reduction in a simulated waste incineration flue gas containing 6% O2. The characteristics of the modified catalysts were analyzed using BET, TEM and XRD. The results of the experiment reveal that Na addition can significantly affect the properties of Rh/Al2O3 catalysts on the BET surface area and Rh metal dispersion. Furthermore, Na addition was found to significantly enhance the NO conversion of Rh/Al2O3 at 250–350 °C. On the contrary, Cu, Ni, and Co addition was found to have slight suppression effects.  相似文献   
99.
When a horizontal homogeneous solid is melted from below, convection can be induced in a thermally unstable melt layer. In this study the onset of buoyancy-driven convection during time-dependent melting is investigated by using similarly transformed disturbance equations. The critical Rayleigh numbers based on the melt-layer thickness are found numerically for various conditions. For small superheats, the present predictions approach the well known results of classical Rayleigh-Bénard problems, that is, critical Rayleigh numbers are located between 1,296 and 1,708, regardless of the Prandtl number. However, for high superheats the critical Rayleigh number increases with an increase in phase change rate but with decrease in Prandtl number.  相似文献   
100.
Catalytic oxidation of naphthalene using a Pt/Al2O3 catalyst   总被引:1,自引:0,他引:1  
Polycylic aromatic hydrocarbons (PAHs) are listed as carcinogenic and mutagenic priority pollutants, belonging to the environmental endocrine disrupters. Most PAHs in the environment stem from the atmospheric deposition and diesel emission. Consequently, the elimination of PAHs in the off-gases is one of the priority and emerging challenges. Catalytic oxidation has been widely used in the destruction of organic compounds due to its high efficiency (or conversion of reactants), its economic benefits and good applicability.

This study investigates the application of the catalytic oxidation using Pt/γ-Al2O3 catalysts to decompose PAHs and taking naphthalene (the simplest and least toxic PAH) as a target compound. It studies the relationships between conversion, operating parameters and relevant factors such as treatment temperatures, catalyst sizes and space velocities. Also, a related reaction kinetic expression is proposed to provide a simplified expression of the relevant kinetic parameters.

The results indicate that the Pt/γ-Al2O3 catalyst used accelerates the reaction rate of the decomposition of naphthalene and decreases the reaction temperature. A high conversion (over 95%) can be achieved at a moderate reaction temperature of 480 K and space velocity below 35,000 h−1. Non-catalytic (thermal) oxidation achieves the same conversion at a temperature beyond 1000 K. The results also indicate that Rideal–Eley mechanism and Arrhenius equation can be reasonably applied to describe the data by using the pseudo-first-order reaction kinetic equation with activation energy of 149.97 kJ/mol and frequency factor equal to 3.26 × 1017 s−1.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号