全文获取类型
收费全文 | 9545篇 |
免费 | 830篇 |
国内免费 | 324篇 |
专业分类
电工技术 | 422篇 |
综合类 | 384篇 |
化学工业 | 1779篇 |
金属工艺 | 441篇 |
机械仪表 | 662篇 |
建筑科学 | 801篇 |
矿业工程 | 268篇 |
能源动力 | 269篇 |
轻工业 | 771篇 |
水利工程 | 126篇 |
石油天然气 | 558篇 |
武器工业 | 67篇 |
无线电 | 1130篇 |
一般工业技术 | 1397篇 |
冶金工业 | 460篇 |
原子能技术 | 104篇 |
自动化技术 | 1060篇 |
出版年
2024年 | 47篇 |
2023年 | 214篇 |
2022年 | 376篇 |
2021年 | 461篇 |
2020年 | 370篇 |
2019年 | 312篇 |
2018年 | 323篇 |
2017年 | 362篇 |
2016年 | 349篇 |
2015年 | 358篇 |
2014年 | 525篇 |
2013年 | 595篇 |
2012年 | 596篇 |
2011年 | 733篇 |
2010年 | 568篇 |
2009年 | 533篇 |
2008年 | 513篇 |
2007年 | 442篇 |
2006年 | 425篇 |
2005年 | 366篇 |
2004年 | 259篇 |
2003年 | 226篇 |
2002年 | 185篇 |
2001年 | 174篇 |
2000年 | 166篇 |
1999年 | 255篇 |
1998年 | 181篇 |
1997年 | 175篇 |
1996年 | 124篇 |
1995年 | 100篇 |
1994年 | 84篇 |
1993年 | 58篇 |
1992年 | 41篇 |
1991年 | 43篇 |
1990年 | 28篇 |
1989年 | 25篇 |
1988年 | 18篇 |
1987年 | 21篇 |
1986年 | 12篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1977年 | 2篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1972年 | 2篇 |
1968年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
High‐Performance Integrated Perovskite and Organic Solar Cells with Enhanced Fill Factors and Near‐Infrared Harvesting 下载免费PDF全文
63.
Highly Conductive,Air‐Stable Silver Nanowire@Iongel Composite Films toward Flexible Transparent Electrodes 下载免费PDF全文
64.
65.
66.
Xiaojian?Liu Zhen?Zheng Chunqing?WangEmail author Wei?Liu Lingchao?Kong 《Journal of Materials Science: Materials in Electronics》2016,27(10):10065-10069
Ultrafine Ag–Cu nanoparticles (NPs) have been synthesized by a rapid one-step reduction within only 10 min. Effects of temperature and dispersants on the phases and morphology of Ag–Cu NPs were investigated. Results showed that citric acid exhibited an advantageous nature to avoid the formation of Cu2O and form uniform morphology over PVP. The average particle size of the Ag–Cu NPs synthesized simply in ice-cubes bath could be controlled in 8.6 nm about a quarter of that synthesized at room temperature. The synthesized Ag–Cu NPs presented alloy states near the eutectic composition of 72:28. Due to the lower Ostwald ripening rate and citric acid protection, smaller Ag–Cu NPs were achieved in ice-cube bath. Results also showed that the ultrafine Ag–Cu NPs could be expected to sinter at about 330 °C which was much lower than the eutectic temperature (779 °C) of bulk Ag–Cu alloy. The ultrafine Ag–Cu NPs could be applied as potential die attach materials for SiC power devices. 相似文献
67.
Yuxia Kong Jigong Hao Dan Xu 《Journal of Materials Science: Materials in Electronics》2016,27(11):11256-11261
High aspect ratio patelike NaNbO3 particles with pure perovskite structure have been successfully synthesized by topochemical microcrystal conversion (TMC) from plate-like precursor particles of the layer-structured Bi2.5Na3.5Nb5O18. By changing the Bi2.5Na3.5Nb5O18/Na2CO3 ratio, large and thin NaNbO3 particles with a thickness of approximately 0.5 μm and a width of approximately 20 μm were obtained. The obtained NaNbO3 particles is quite suitable for fabricating textured (K0.5Na0.5)NbO3-based ceramics. Using the fine platelike NaNbO3 particles as templates, dense <001> -oriented (K0.5Na0.5)NbO3-0.5 mol %MnO2 ceramics with high texture quality (Lotgering factor F 001 = 87 %) and excellent piezoelectric properties were produced by templated grain growth. Compared with randomly oriented ceramics, textured samples show greatly enhanced properties. The room-temperature strain S, the piezoelectric coefficient d 33 * and d 33 reach up to 0.093 %, 233 pm/V and 195pC/N, respectively, which are all about 1.5 times larger than those of non-textured ceramics. 相似文献
68.
为了研究不同烤燃条件下复合推进剂(PBT/HMX/Al/AP/BU)的响应特性,采用DSC研究了复合推进剂及单组分的热分解特性。复合推进剂的初始分解温度为187.27℃,单组分中BU初始分解温度最低,为192.95℃,表明复合推进剂的热分解过程是从BU开始;分别测量了在快/慢烤试验中,复合推进剂内部温度的变化。结果表明:1)快烤试验中,样品内部温度分布极不均匀。点火90 s后,样品发生反应,此时样品中心的温度为85℃,钢管端盖破裂,样品发生燃烧反应。2)慢烤试验中,样品内部温度分布均匀,几乎无温度差,样品发生反应时,样品内部温度与环境温度均为133℃,试验后样品钢管完全破碎,样品发生了爆轰。由此可见,慢烤试验中,由于样品内部温度分布均匀,发生反应时,大部分样品都处于临界反应温度,一旦激发,破坏效应比快烤试验更严重。 相似文献
69.
Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions 下载免费PDF全文
Jing Guo Jie Pan Shuai Chang Xuewen Wang Na Kong Wenrong Yang Jin He 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(15)
The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction. 相似文献
70.
Imparting Designer Biorecognition Functionality to Metal–Organic Frameworks by a DNA‐Mediated Surface Engineering Strategy 下载免费PDF全文
Weiyu Ning Zhenghan Di Yingjie Yu Pingmei Zeng Chunzhi Di Daquan Chen Xueqian Kong Guangjun Nie Yuliang Zhao Lele Li 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(11)
Surface functionality is an essential component for processing and application of metal–organic frameworks (MOFs). A simple and cost‐effective strategy for DNA‐mediated surface engineering of zirconium‐based nanoscale MOFs (NMOFs) is presented, capable of endowing them with specific molecular recognition properties and thus expanding their potential for applications in nanotechnology and biotechnology. It is shown that efficient immobilization of functional DNA on NMOFs can be achieved via surface coordination chemistry. With this strategy, it is demonstrated that such porphyrin‐based NMOFs can be modified with a DNA aptamer for targeting specific cancer cells. Furthermore, the DNA–NMOFs can facilitate the delivery of therapeutic DNA (e.g., CpG) into cells for efficient recognition of endosomal Toll‐like receptor 9 and subsequent enhanced immunostimulatory activity in vitro and in vivo. No apparent toxicity is observed with systemic delivery of the DNA–NMOFs in vivo. Overall, these results suggest that the strategy allows for surface functionalization of MOFs with different functional DNAs, extending the use of these materials to diverse applications in biosensor, bioimaging, and nanomedicine. 相似文献