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71.
72.
Nasanjargal Purev Ladislav Burgert Petr Prichystal Radim Hrdina Jiri Kühn Michal Cerny Jamyan Oyuntulkhuur 《Coloration Technology》2013,129(6):412-417
CI Acid Black 210 was microencapsulated into liposomic systems, and the effects of the microencapsulation on dyebath exhaustion, depth of shade, colour fastness properties and through‐dyeing of chrome‐tanned leather were studied. In comparison with the original dyestuff form, the microencapsulated dye showed a deeper shade and a greater depth of through‐dyeing. Exhaustion and colour fastness values were the same. 相似文献
73.
Michal Sypula Andreas Wilden Christian Schreinemachers Rikard Malmbeck Andreas Geist Robin Taylor 《溶剂提取与离子交换》2013,31(7):748-764
During the partitioning of trivalent actinides from High Active Raffinate (HAR) solutions, most processes have to cope with an undesirable co-extraction of some of the fission products. Four hydrophilic complexing agents of the group of polyaminocarboxylic acids, namely EDTA, HEDTA, DTPA, and CTDA were tested and compared for their ability to complex fission products in a simulated PUREX raffinate solution, thereby preventing their extraction into an organic solvent. Several solvents, based on TODGA and the DIAMEX reference molecule DMDOHEMA, that are commonly known to show quite high Zr and Pd co-extraction, were studied. Our investigations ultimately resulted in a substitution of oxalic acid and HEDTA by cyclohexanediaminetetraacetic acid (CDTA). A small addition of this hydrophilic complexing agent to the feed decreased the distribution ratios of Zr from 100 to <0.01. The suppression of Pd was also very effective, resulting in >90% of the metal retained in the feed solution. The extraction of trivalent actinides and lanthanides was not negatively affected by the presence of CDTA. Furthermore, experiments with high concentrations of Zr proved the applicability of this new masking agent. The suppression of Zr and Pd extraction was also verified at a high Pu loading which makes CDTA as a masking agent attractive for grouped actinide extraction processes (GANEX) as well as DIAMEX-SANEX type separations. 相似文献
74.
Traveling-wave Phenomena in a Model of Autocrine Signaling Coupled with Dynamics of the MAPK Cascade
Recently we have revealed a minimal reaction subnetwork in the MAPK (mitogen-activated protein kinase) cascade that is responsible for the emergence of bistable and oscillatory behavior. Here we examine a possible mechanism that provides for the propagation of increased MAPK activity in cell populations by interconnecting the intracellular MAPK subnetwork with the ligand-receptor signaling machinery. Such approach allows for significant reduction of the dimensionality of the parameter space on one hand and the conservation of dynamical complexity of the system on the other hand. The coupled model predicts coexistence of one, two or three different stable steady states, or the coexistence of a stable steady state and periodic solution. We found two robust and physiologically relevant characteristics of the proposed model: (i) There is a very large region of coexistence of at least one stable steady state with non-zero MAPK activity and one steady state with zero MAPK activity in the parameter space. (ii) Spontaneous traveling front waves always switching originally inactive cells into ligand releasing cells emerge in adjacent cell populations, e. g. in healthy and injured tissues. Moreover, the formation of composite traveling front waves and spatial oscillatory patterns of MAPK activity are predicted and discussed. 相似文献
75.
Object orientation and formal methods are widely regarded as two fields with significant potential for new software engineering techniques. This paper discusses the relations between these two approaches. We present various specification techniques which incorporate object-oriented paradigms, discuss their place in software development process, and analyse possible benefits from their applications. 相似文献
76.
Ondřej Jankovský Filip Antončík Tomáš Hlásek Vladimír Plecháček David Sedmidubský Štěpán Huber Michal Lojka Vilém Bartůněk 《Journal of the European Ceramic Society》2018,38(6):2541-2546
YBa2Cu3O7-δ (YBCO) is a well-known high-temperature superconductor. However, its critical current density and thus maximum trapped magnetic field can be improved significantly by introducing the secondary phases (artificial pinning centers). In this contribution, we successfully prepared YBCO single-grain bulks with Y2Ba4CuWO10.8 phase serving as a source of pinning centers. This phase was prepared by solid-state reaction and further refined by milling. In the next step single-grain YBCO bulks with homogeneously distributed Y2Ba4CuWO10.8 were prepared by top-seeded melt growth. Precursors as well as the final product were characterized by XRD, SEM and EDS. The phase composition of YBCO bulks containing Y2Ba4CuWO10.8 was analyzed using Rietveld analysis. Thermal stability of YBCO bulk was studied by STA. Furthermore, PPMS was used to study electrical resistivity and critical current density. Bulk superconducting properties such as levitation force and trapped field ability were also measured. 相似文献
77.
In this paper, we present AutoMed, an automated mediator for multi-issue bilateral negotiation under time constraints. AutoMed
elicits the negotiators preferences and analyzes them. It monitors the negotiations and proposes possible solutions for resolving
the conflict. We conducted experiments in a simulated environment. The results show that negotiations mediated by AutoMed
are concluded significantly faster than non-mediated ones and without any of the negotiators opting out. Furthermore, the
subjects in the mediated negotiations are more satisfied with the resolutions than the subjects in the non-mediated negotiations. 相似文献
78.
The analysis addresses a typical failure development pattern in thin films consisting of a system of multiple surface cracks leading to and branching along or near the interface between the film and the base material. The process is driven by thermal residual stresses and/or mechanical loading. Due to the high temperature gradients during the fabrication process, usually a net of surface cracks develops, which gives the appearance of a granular structure of the surface. A periodic array of parallel surface cracks is assumed. A “unit cell” or single cracked segment attached to the substrate is analyzed instead by assuming the channel cracks are spaced more or less uniformly and perfectly aligned in parallel in the transverse direction of the coating. The analysis is specialized to orthotropic and transversally isotropic materials. The problem is solved using FEM combined with the reciprocal theorem. Matched asymptotic procedure [Leguillon D, Sanchez-Palencia E. Computation of singular solutions in elliptic problems and elasticity. Paris: Masson; 1987; Vu-Quoc L, Tran VX. Singularity analysis and fracture energy-release rate for composites: piecewise homogenous-anisotropic materials. Comput Methods Appl Mech Engng 2006;195:5162-97] is used to derive the change of potential energy. Higher-order terms in the asymptotics are considered. The competition between penetration and debond for periodically distributed edge cracks especially near the critical value of the ratio of fracture spacing to the layer thickness is examined. 相似文献
79.
Michal Soreni‐Harari David Mocatta Marina Zimin Yair Gannot Uri Banin Nir Tessler 《Advanced functional materials》2010,20(6):1005-1010
InAs nanocrystals field‐effect transistors with an ON/OFF ratio of 105 are reported. By tailoring the interface regions in the active layer step‐by‐step, the evolution of the ON/OFF ratio can be followed from approximately 5 all the way to around 105. The formation of a semiconducting solid from colloidal nanocrystals is achieved through targeted design of the nanocrystal–nanocrystal interaction. The manipulation characteristics of the nanocrystal interfaces include the matrix surrounding the inorganic core, the interparticle distance, and the order of nanocrystals in the 3D array. Through careful analysis of device characteristics following each treatment, the effect of each on the physical properties of the films are able to be verified. The enhanced performance is related to interparticle spacing, reduction in sub‐gap states, and better electronic order (lower σ parameter). Films with enhanced charge transport qualities retain their quantum‐confined characteristics throughout the procedure, thus making them useful for optoelectronic applications. 相似文献
80.
New sulfated zirconias covering a wide range of pore diameters from micropores to macropores have been prepared by a combined use of two different structure-directing templates. The catalytic performance of these sulfated zirconias for the n-butane isomerization could be improved significantly compared to a standard displaying a maximum rate of isomerization of 1490 μmol/g h at 423 K. The materials remained their high activity even at 348 K. Moreover, deactivated materials could be reactivated to the original activity in an air-flow at 673 K several times. The newly designed materials were fully characterized by XRD, XPS, TPD of ammonia, IR spectroscopy and N2 adsorption to describe the formation of active surface centres and their morphology. The formation of active pyrosulfates with sulfate bands above 1400 cm?1 was followed by DRIFTS. An increased ratio of Brønsted-to-Lewis centres could be detected which can be accounted for the unexpected high activity. 相似文献