The use of CO stripping for in situ fuel cell catalyst characterization

An important parameter in normalizing activities of porous electrocatalysts is real surface area of the catalyst. In this study CO stripping voltammetry was applied for the determination of the surface area of PtRu catalysts in a membrane electrode assembly. The difficulties in applying this method are summarized and a practical solution for the “accurate” voltammetric CO charge determination is suggested. The influence of adsorption time, potential, sweeping range and sweep rate on voltammetric CO charge determination is studied. It is shown that the CO charge determined in this way is independent on the sweep rate applied.     

Rational emotive behavior therapy versus cognitive therapy versus pharmacotherapy in the treatment of major depressive disorder: Mechanisms of change analysis.

Cognitive-behavioral psychotherapies (CBT) are among the first-line interventions for major depressive disorder (MDD), and a significant number of studies indicate their efficacy in the treatment of this disorder. However, differential effects of various forms of CBT have seldom been analyzed in the same experimental design. On the basis of data collected in a randomized clinical trial comparing the efficacy of rational-emotive behavior therapy (REBT), cognitive therapy (CT), and pharmacotherapy (SSRI) in the treatment of MDD, the present article investigates the theory of change advanced by REBT and CT. Measures included to test the two theories of change assess three classes of cognitions: (a) automatic thoughts, (b) dysfunctional attitudes, and (c) irrational beliefs. The results indicate that REBT and CT (and also pharmacotherapy) indiscriminately affect the three classes of cognitions. On the long term (follow-up), a change in implicit demandingness seems more strongly associated with reduced depression and relapse prevention. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An exploratory analysis of the interactions between the determinants of migratory flows

More than often, studies explaining migration causes centre on economic explanations and minimize other factors' explanatory power. This research aims at creating a comprehensive model of migration determinants taking into account four dimensions: economic, social, cultural, and digital. A path model consisting of these dimensions was created and estimated through partial least squares structural equation modelling (PLS-SEM). The PLS-path model was applied to Romanian migration flows to 21 EU member states during 2007–2017. The findings indicate that social and technological developments have significant impacts on migration flows and that digital distance has a full mediation effect on the relationship between cultural distance and migration flows.     

New Potential Antitumor Pyrazole Derivatives: Synthesis and Cytotoxic Evaluation

New pyrazole derivatives were designed and synthesized as potential protein kinase inhibitors in the view to develop specific antitumor therapies. The structures of the compounds were elucidated using spectral and elemental analyses. The antitumor potential was estimated using wheat seeds and the general toxicity was evaluated by alternative methods, using invertebrate animals. One 3-aminopyrazole derivative emerged as a potential candidate for the development of future cytotoxic compounds.     

Iron Powder Treated Gray Irons: Critical Shape Characteristics for Graphite Nuclei

A program was conducted to research how to characterize the size and shape of micro-particles. These can act as graphite nuclei, but are altered by adding a commercial iron powder, or after a similar treatment combined with inoculation. Resin sand mold (RSM) and metal mold (MM) solidified sample structures were subjected to automatic image analysis. In general, a higher cooling rate, typical for MM solidification, favors smaller size and more compact particles, even in RSM media. Iron powder treatment led to the largest particles with unusual morphologies, better defined by complex shape factors, which employ actual perimeters, rather than the simpler median size and aspect ratio method. Conventional inoculation employed after an iron powder treatment altered the particles (smaller and more compact), which benefited their effectiveness to act as graphite nuclei, especially at slower solidification rates in RSMs. The results confirm that promoting more compact micro-inclusions, at smaller sizes, involved in graphite nucleation, reduces the sensitivity to chill and improves the eutectic cell characteristics in gray cast iron.     

The effects of organic additives on induction time and characteristics of precipitated calcium carbonate

The effects of an organic additive, polyoxyethylene sorbitan trioleate (Tween 85), on the induction time for the precipitation of calcium carbonate are experimentally and theoretically investigated. Calcium carbonate was precipitated from aqueous solutions of K₂CO₃ and Ca(NO)₃ at moderate supersaturations ranging between 5 and 16 with and without the organic additive. Experimentally it has been noticed that the induction period for CaCO₃ precipitation increases at low supersaturation and is also influenced by temperature. An increase of the induction time was noticed when Tween 85 was added in the system. The “cluster coagulation model” proposed by Qian and Botsaris (1997), which combines nucleation models and coagulation theory, was used to explain the effects of operating parameters on the induction time in terms of interfacial energy and cluster sizes.     

Hybrid nanostructured coating for increased resistance of prosthetic devices to staphylococcal colonization

Prosthetic medical device-associated infections are responsible for significant morbidity and mortality rates. Novel improved materials and surfaces exhibiting inappropriate conditions for microbial development are urgently required in the medical environment. This study reveals the benefit of using natural Mentha piperita essential oil, combined with a 5 nm core/shell nanosystem-improved surface exhibiting anti-adherence and antibiofilm properties. This strategy reveals a dual role of the nano-oil system; on one hand, inhibiting bacterial adherence and, on the other hand, exhibiting bactericidal effect, the core/shell nanosystem is acting as a controlled releasing machine for the essential oil. Our results demonstrate that this dual nanobiosystem is very efficient also for inhibiting biofilm formation, being a good candidate for the design of novel material surfaces used for prosthetic devices.     

Instruction Set Extensions for Matrix Decompositions on Software Defined Radio Architectures

Emerging wireless applications consistently demand higher data rates. Unfortunately, it is challenging to achieve high data rates within the limited amount of available frequency spectrum. Hence, enhanced spectral efficiency and link reliability within the available frequency spectrum are of the utmost importance in current and next generation wireless protocols. To attain high spectral efficiency and link reliability, wireless protocols employ increasingly complex 2-dimensional techniques that involve computationally-intensive matrix operations. Multiple-Input Multiple-Output (MIMO) communication is an example of a promising technique employed by wireless protocols to deliver higher data rates at the cost of increased algorithmic complexity. Application Specific Integrated Circuits (ASICs) have traditionally been used to implement compute-intensive wireless protocols. The wireless industry has been gradually moving towards an alternative programmable platform called Software Defined Radio (SDR) due to its significant benefits, such as reduced development costs, and accelerated time-to-market. The computationally-intensive matrix operations used in current and next generation wireless protocols are extremely expensive to implement in SDR platforms with conventional Digital Signal Processor (DSP) instruction sets. Hence there is a need for novel instructions, hardware designs and algorithm enhancements to enable higher spectral efficiency on SDR platforms. In this paper, we propose Single Instruction Multiple Data (SIMD) CoOrdinate Rotation DIgital Computer (CORDIC) instruction set extensions with CORDIC hardware support to speedup computationally-intensive matrix decomposition algorithms. The CORDIC instruction set extensions have been implemented on the Sandbridge Sandblaster SB3000 SDR platform and evaluated on conventional algorithms used for decomposing a closed loop 4-by-4 Worldwide Interoperability for Microwave Access (WiMAX) MIMO channel into independent Single-Input Single-Output (SISO) channels. Our experimental results on the closed-loop MIMO channel decomposition using CORDIC instructions demonstrate more than 6x speedup over a Sandblaster baseline implementation that uses state-of-the-art SIMD DSP instructions. The CORDIC instructions also provide similar numerical accuracy when compared to the baseline implementation. The techniques we propose in this paper are also applicable to other SDR and embedded processor architectures.