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51.
The second-order nonlinear optical properties of aromatic polyureas are reported. From Maker fringe measurements, the nonlinear d/sub 33/ coefficient of poled polyurea films with and without pendant chromophores was found to be 20*10/sup -9/ esu and 12*10/sup -9/ esu, respectively, at 1.064 mu m. Aromatic polyurea having no pendant chromophores shows a cutoff wavelength of transmission at 307 nm which is the first example of organic NLO materials to be optically transparent at such low wavelengths.<> 相似文献
52.
When a benzene/cyclohexane mixture was permeated through poly(dimethyl acrylamide-random-methyl methacrylate) (DMAA-r-MMA)
and poly(dimethyl acrylamide)-graft-poly(methyl methacrylate) (DMAA-g-MMA) membranes by pervaporation, the benzene-permselectivity
of the DMAA-r-MMA membrane changed from the diffusivity selectivity to the solubility selectivity with increasing DMAA content
but DMAA-g-MMA membranes with a high DMAA content had the higher apparent diffusivity selectivity than the apparent solubility
selectivity. Furthermore, the apparent solubility selectivity for a benzene/cyclohexane mixture between the DMAA-r-MMA membrane
and the DMAA-g-MMA membrane with a high DMAA content was remarkably different. These results were attributed to the difference
of structure between the copolymers.
Received: 27 August 1997/Revised version: 22 October 1997/Accepted: 30 October 1997 相似文献
53.
Y Nakamura S Nakashima H Fujimiya T Kumada K Ojio H Miyata Y Nozawa 《Canadian Metallurgical Quarterly》1995,44(6):624-629
An anti-allergic drug, permirolast potassium (TBX), inhibited antigen (Ag)-induced phospholipase D (PLD) activation in rat basophilic leukemia (RBL-2H3) cells. The concentration-dependent inhibitory profile for Ag-induced PLD activation was parallel to those for secretory response and inositol phosphate formation. In contrast, TBX had no effect on PLD activation caused by calcium ionophore A23187 or phorbol myristate acetate. These results suggest that TBX inhibits Ag-induced PLD activation by interfering with the signal transduction pathway upstream of Ca2+ mobilization and protein kinase C activation. 相似文献
54.
A. Miyata T. Matsushima H. Ohki Y. Unuma Y. Higashigaki 《Advanced functional materials》1995,5(1):37-43
Spiropyran SP1822 J-aggregate LB films show a non-linear photochromic response with a threshold against the incident light intensity of a CW dye laser. Using two laser beams operating below the threshold level intensity, the logic ‘AND’ function was found to be optically stored as an overlapping region of two incident patterns. We proposed the adoption of an LB film of spiropyran J-aggregates to store the memory matrix Tijkl as an overlapping region of learning input pattern Vij and multi-image input pattern Vkl in order to construct an optical neural network system based on Hopfield model. 相似文献
55.
56.
Jun-ichi Nomoto Tomoyasu Hirano Toshihiro Miyata Tadatsugu Minami 《Thin solid films》2011,520(5):1400
In order to determine the influence of different types of magnetron sputtering (MS) depositions on the characteristics of Al-doped ZnO (AZO) thin films appropriate for applications as transparent electrodes in thin-film solar cells, transparent conducting AZO thin films were prepared on glass substrates at 200 °C by direct current (dc) magnetron sputtering (dc-MS), radio frequency (rf)-MS and rf power superimposed dc-MS (rf + dc-MS) depositions using an MS apparatus with the same AZO target. AZO thin films prepared by an rf + dc-MS deposition exhibited both a higher deposition rate than that found with rf-MS depositions and a lower resistivity or higher Hall mobility than those found with dc-MS. The lower dc sputter voltage featured in rf-MS and rf ± dc-MS depositions, producing smoother surface morphology and better crystallinity than obtained with dc-MS depositions. The light scattering characteristics of surface-textured AZO thin films prepared by various types of MS depositions were evaluated by observing the surface texture and measuring the optical transmittance and the diffusive component; wet-chemical etching of the thin film surface was performed in a 0.1% HCl solution. The obtainable haze property in the range from visible to near infrared in AZO films prepared by an rf + dc-MS deposition was markedly better than that obtained with dc-MS depositions. 相似文献
57.
Noriyuki Miyata Hiroyuki IshiiYuji Urabe Taro ItataniTetsuji Yasuda Hisashi YamadaNoboru Fukuhara Masahiko HataMomoko Deura Masakazu SugiyamaMitsuru Takenaka Shinichi Takagi 《Microelectronic Engineering》2011,88(12):3459-3461
Electrical and physical characteristics of the Al2O3/InGaAs interfaces with (1 1 1)A and (1 0 0) orientations were investigated in an attempt to understand the origin of electron mobility enhancement in the (1 1 1)A-channel metal-insulator-semiconductor field-effect-transistor. The (1 1 1)A interface has less As atoms of high oxidation states as probed by X-ray photoelectron spectroscopy. The electrical measurements showed that energy distribution of the interface traps for the (1 1 1)A interface is shifted toward the conduction band as compared to that for the (1 0 0) interface. Laterally-compressed cross-section transmission electron microscopy images showed that the characteristic lengths of the interface roughness are different between the (1 1 1)A and (1 0 0) interfaces. The contributions of the Coulomb and roughness scattering mechanisms are discussed based on the experimental results. 相似文献
58.
The present paper examines the accuracy of two models used to predict the capacity of single square plate anchors used in multi-anchor wall (MAW) systems constructed in Japan. Measured anchor plate capacities from full-scale in situ load tests reported in the literature are compared to predicted values using the analytical model recommended in Japan. A modified anchor capacity model is proposed that preserves the general form of the PWRC equation, but introduces correction factors to improve accuracy. The correction factors are empirically-based and are selected by back-fitting measured loads to achieve a resistance bias mean equal to one and a low coefficient of variation (COV) in bias values. The results of a large number of small-scale anchor capacity tests carried out in pullout boxes were used to guide the selection of back-fitted parameters. The correction factors account for the influence of the confining pressure (anchor depth), the plate size and the anchor rod length on the anchor plate capacity. New Nc and Nq factors are also presented as part of the new model. The bias statistics for the two models comprise an important contribution to future reliability-based calibrations of the ultimate anchor capacity limit state for MAW systems in Japan. 相似文献
59.
T Miyata S Taneda R Kawai Y Ueda S Horiuchi M Hara K Maeda VM Monnier 《Canadian Metallurgical Quarterly》1996,93(6):2353-2358
beta-2-Microglobulin (beta-2m) is a major constituent of amyloid fibrils in patients with dialysis-related amyloidosis (DRA). Recently, we found that the pigmented and fluorescent adducts formed nonenzymatically between sugar and protein, known as advanced glycation end products (AGEs), were present in beta-2m-containing amyloid fibrils, suggesting the possible involvement of AGE-modified beta-2m in bone and joint destruction in DRA. As an extension of our search for the native structure of AGEs in beta-2m of patients with DRA, the present study focused on pentosidine, a fluorescent cross-linked glycoxidation product. Determination by both HPLC assay and competitive ELISA demonstrated a significant amount of pentosidine in amyloid-fibril beta-2m from long-term hemodialysis patients with DRA, and the acidic isoform of beta-2m in the serum and urine of hemodialysis patients. A further immunohistochemical study revealed the positive immunostaining for pentosidine and immunoreactive AGEs and beta-2m in macrophage-infiltrated amyloid deposits of long-term hemodialysis patients with DRA. These findings implicate a potential link of glycoxidation products in long-lived beta-2m-containing amyloid fibrils to the pathogenesis of DRA. 相似文献
60.
Chapetti Kitano Tagawa Miyata 《Fatigue & Fracture of Engineering Materials & Structures》1998,21(12):1525-1536
The position and effective resistance of microstructural barriers and their relation to the fatigue strength of blunt-notched specimens are analysed and modelled for three low-carbon steel microstructures. A relationship for the notch size effect on the basis of the experimental evidence that the fatigue limit (both plain and notched) represents the threshold stress for the propagation of the nucleated microstructurally short cracks, was derived. The derived relationship characterizes the fatigue notch sensitivity by means of the parameter ktd defined as the stress concentration introduced by the notch at a distance d from the notch root surface equal to the distance between microstructural barriers, and was experimentally verified for two notch geometries in three microstructures: ferrite, ferrite–bainite and bainite–martensite. 相似文献