Quantitative determination of fluorine in spent grain and brewery yeast

Previously published studies have shown that fluorine could present a health risk for humans. In this context, legislative regulations define the fluorine limits in many commodities, including brewery by‐products, such as spent grain and brewery yeast used as a feed. A method for the determination of fluorine in these by‐products using gas chromatography with flame ionization detection is therefore proposed. The first step is based on extraction of fluorine with 1 mol/L hydrochloric acid solution simulating acidic stomach surroundings. Then, fluorine is derivatized by trimethylchlorosilane to form trimethylfluorosilane (TMFS), which is subsequently extracted in liquid–liquid mode. TMFS is then analysed by gas chromatography–flame ionization detection; n‐pentane is used as an internal standard for fluorine quantification. The recovery of the method was >96%. The results also showed a high correlation coefficient (R > 0.999) in the calibration range studied (0–2000 mg/kg). The precision of the method, expressed as the relative standard deviation, was 13%. The limit of quantification was 0.02 mg/kg. This method was used for pilot screening of fluorine in 16 grain and 12 yeast samples. The resulting concentrations of fluorine ranged between 1.5 and 20.0 mg/kg, levels far below the legislative limits. Copyright © 2015 The Institute of Brewing & Distilling     

Occurrence of enterotoxic Staphylococcus aureus in raw milk from yaks and cattle in Mongolia

Staphylococcal food poisoning is considered one of the leading foodborne illnesses in humans worldwide and is associated with contaminated foods of animal origin, such as milk and dairy products. In this study, we investigated the occurrence of staphylococci and the enterotoxigenic properties of Staphylococcus aureus isolated from raw milk from yaks (Bos mutus) and cattle in Mongolia. Staphylococci were isolated from 72 (74%) of the 97 raw milk samples. Of the samples containing staphylococci, 69% (50 of 72) were from yaks and 30.5% (22 of 72) were from cattle. S. aureus was detected in 10% of yak (7 of 72) and 21% of cattle (15 of 72) milk samples. Staphylococcal enterotoxin C was detected in 23% (5 of 22) of the S. aureus strains investigated, based on the reverse passive latex agglutination technique. Three of the five enterotoxigenic strains were from yaks and two were from cattle. None of the S. aureus strains tested produced staphylococcal enterotoxins A, B, or D. To our knowledge, this is the first report of the occurrence of staphylococci and enterotoxigenic S. aureus in milk from yaks and cattle in Mongolia.     

Applying state diagrams to food processing and development

The physical state of food components affects their properties during processing, storage, and consumption. Removal of water by evaporation or by freezing often results in formation of an amorphous state (Parks et al., 1928; Troy and Sharp, 1930; Kauzmann, 1948; Bushill et al., 1965; White and Cakebread, 1966; Slade and Levine, 1991). Amorphous foods are also produced from carbohydrate melts by rapid cooling after extrusion or in the manufacturing of hard sugar candies and coatings (Herrington and Branfield, 1984). Formation of the amorphous state and its relation to equilibrium conditions are shown in Fig. 1 [see text]. The most important change, characteristic of the amorphous state, is noticed at the glass transition temperature (Tg), which involves transition from a solid "glassy" to a liquid-like "rubbery" state. The main consequence of glass transition is an increase of molecular mobility and free volume above Tg, which may result in physical and physico-chemical deteriorative changes (White and Cakebread, 1966; Slade and Levine, 1991). We have conducted studies on phase transitions of amorphous food materials and related Tg to composition, viscosity, stickiness, collapse, recrystallization, and ice formation. We have also proposed that some diffusion-limited deteriorative reactions are controlled by the physical state in the vicinity of Tg (Roos and Karel, 1990, 1991a, b, c). The results are summarized in this article, with state diagrams based on experimental and calculated data to characterize the relevant water content, temperature, and time-dependent phenomena of amorphous food components.     

Thermal analysis and phase transformation behaviour during additive manufacturing of Ti–6Al–4V alloy

Despite the fact that the additive manufacturing (AM) technique has been established for almost two decades, its optimisation is still performed by trial and error experimentation. In the present work, a finite element modelling approach was used to study both the temperature distribution and heat flux vector characteristics during multi-layer deposition of a Ti–6Al–4V alloy that take place in the AM process. The results revealed the difference between different powder deposition time intervals on thermal cycles, heat flux vectors and the resulting microstructures. Good agreement between the numerical and experimental results was found. The results obtained can be used for process optimisation.     

Speed maintenance under cognitive load - Implications for theories of driver behaviour

No theory of driver behaviour has yet managed to achieve widespread acceptance and use in the field of Traffic Psychology, partly due to the difficulty in testing many of the theories. However, one class of theories, the motivational theories, can be usefully split into two groups and the differences between them can then be examined. One group posits the constant monitoring and targeting of a certain subjective variable, often risk, as the controlling factor in driving. The other group however states that subjective variables such as risk are only relevant once a certain threshold has been passed.In this study we aimed to examine this difference by manipulating both speed of travel and the amount of cognitive load participants were under. Participants were asked to initially drive at their preferred speed for 1 min in a driving simulator. Participant's speed was then automatically increased or decreased by 10, 20 30 km/h or left unchanged. Participants were then required to maintain the new speed for 1 min. After this 1 min the speed was again automatically changed and had to be maintained for one more minute, but this time participants also carried out a secondary mental arithmetic task. Finally participants were asked to again drive for another 1 min at their preferred speed. This procedure was repeated seven times, once for each speed manipulation; −30, −20, −10, +0, +10, +20 and +30 km/h. After each 1 min interval verbal ratings of task difficulty, effort, feeling of risk and the typicality of the speed were collected.The results show a threshold effect in ratings of task difficulty, effort and feeling of risk, with no significant difference given between the ratings during the baseline period and the experimentally decreased speed periods until after participant's preferred speed of travel had been exceeded. Furthermore, even when under cognitive load the threshold relationship was still apparent, if diminished. Finally it appears that when under cognitive load drivers have difficulty maintaining a travelling speed which is lower than the speed at which they would prefer to drive. However, driving at a speed in excess of their preferred speed appears to be easier to maintain, at least in the short term.     

A New,Thorough Look on Unusual and Neglected Group III-VI Compounds Toward Novel Perusals

The attention on group III-VI compounds in the last decades has been centered on the optoelectronic properties of indium and gallium chalcogenides. These outstanding properties are leading to novel advancements in terms of fundamental and applied science. One of the advantages of these compounds is to present laminated structures, which can be exfoliated down to monolayers. Despite the large knowledge gathered toward indium and gallium chalcogenides, the family of the group III-VI compounds embraces several other noncommon compounds formed by the other group III elements. These compounds present various crystal lattices, among which a great deal is offered from layered structures. Studies on aluminium chalcogenides show interesting potential as anodes in batteries and as semiconductors. Thallium (Tl), which is commonly present in the +1 oxidation state, is one of the key components in ternary chalcogenides. However, binary Tl–Q (Q = S, Se, Te) systems and derived films are still studied for their semiconducting and thermoelectric properties. This review aims to summarize the biggest features of these unusual materials and to shed some new light on them with the perspective that in the future, novel studies can revive these compounds in order to give rise to a new generation of technology.     

Photoluminescence of rare-earth/transition metal-doped transparent/translucent polycrystalline Al2O3 ceramics: A review

Transparent alumina doped with rare-earth or transition metal oxides represents a group of materials suitable for optical applications. Because of the birefringence of alumina, their preparation is demanding on the quality of starting materials, their advanced shaping, and pressure-assisted sintering. Spark plasma sintering and hot isostatic pressing have proven at achieving pore-free fine microstructures exhibiting high in-line transmission and a sufficient intensity of emitted light. The present review aims to summarize the results published on this topic, to compare them and on this base to propose other possible and/or appropriate approaches to future.     

Pyrazinium Salts as Efficient Organocatalysts of Mild Oxidations with Hydrogen Peroxide

A series of 3‐substituted pyrazinium tetrafluoroborates was prepared as simple analogues of flavinium salts which are efficient organocatalysts for oxidations with hydrogen peroxide. It was shown that pyrazinium derivatives with an electron‐withdrawing substituent catalyze mild oxidations of sulfides to sulfoxides and Baeyer–Villiger oxidations in a similar way to flavinium catalysts. The most reactive catalyst, 3‐cyanopyrazinium tetrafluoroborate, was efficiently employed in preparative sulfoxidations of aromatic and aliphatic sulfides as well as in Baeyer–Villiger oxidations of cyclobutanones. A proposed mechanism for the catalysis is based on the formation of pyrazine hydroperoxide which is the agent oxidizing the substrate.     

Using Numerical Dissipation Rate and Viscosity to Assess Turbulence-Related Data Accuracy – Part 1: Experimental Setup

This is the first part of a two-part paper focusing on the assessment of accuracy of turbulence-related data from computational fluid dynamics (CFD) simulations using effective numerical dissipation rate and effective numerical viscosity. Setup of the CFD cases replicating a swirling pipe flow experiment from literature, for which turbulence-related data measured via laser Doppler anemometry (LDA) had been reported, is presented. The way effective numerical dissipation rate and effective numerical viscosity were obtained for each mesh cell is also discussed. The results of the study are presented in the second part of this series.     

Magneto-hydrodynamic mixing: A new technique for preparing carbomer hydrogels

Magnetohydrodynamic mixing was evaluated as an alternative to conventional high shear mixing (HSM) in the preparation of carbomer hydrogels containing 1.22 wt% Carbopol® 980 NF. Neutralization of the carbomer dispersion (pH = 2.74) with triethanolamine (TEA) enabled to adjust the pH of the mixture and tune the viscosity of the hydrogel. Using HSM, this approach was limited to 0.2 wt% TEA (pH = 3.83) as the gel became too viscous and the recirculation flow dropped from 12 to 0.3 m³/h. Magnetohydrodynamic mixing enabled to reach TEA concentrations up to 1.0 wt% (pH = 5.31). Apparent viscosity measurements on samples having 0.2 wt% TEA revealed lower viscosities for carbomer hydrogels prepared with HSM, that is, 6800 mPa s versus 8800 mPa for magneto-hydrodynamic mixing. Based on ¹H NMR evidence, this decrease in apparent viscosity was attributed to structural damage to the carbomer backbone in combination with mechanochemical degradation of the added TEA.