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排序方式: 共有909条查询结果,搜索用时 31 毫秒
11.
Milton E. Rose 《Journal of scientific computing》1990,5(2):169-185
A compact finite-difference scheme to solve one-phase Stefan problems in one dimension is described. Numerical experiments indicate that the moving interface is obtained withO(t) accuracy when 3–4 iterations per time step are used to solve the nonlinear implicit scheme. The scheme can be adapted to ADI methods in higher dimensions. 相似文献
12.
Chengyun Yue J. Milton Harris Per-Erik Hellberg Karin Bergstrom 《Journal of the American Oil Chemists' Society》1996,73(7):841-845
A series of noncyclic acetal-linked cleavable surfactants were simply prepared by condensation of aldehydes with poly(ethylene
glycol) monomethyl ethers. All of the products were characterized by1H nuclear magnetic resonance. Their hydrophile-lipophile balance, surface tension, cloud point, critical micelle concentration,
and foam height were determined. Hydrolysis kinetic studies, followed by gas chromatography, showed that they had higher hydrolytic
reactivity in acidic solution than cyclic acetal-linked cleavable surfactants. 相似文献
13.
Milton J. Rosen 《Journal of the American Oil Chemists' Society》1972,49(5):293-297
Changes in the various structural units present in surfactants strongly affect the interfacial properties shown by these materials.
Such properties as surface tension reduction, micelle formation, wetting, foaming and defoaming, detergency, and dispersion
of solids all show marked changes with variations in both the hydrophilic and hydrophobic portions of the surfactant molecule,
reflecting the processes occurring on a molecular level. Changes in these properties caused by such factors as the length
and nature of the hydrophobic group, branching or unsaturation in the hydrophobic group, the nature of the hydrophilic group
and its position in the molecule, and the presence or absence of an ionic charge are described and explained in terms of the
molecular processes involved.
Presented at the AOCS Short Course, “Update on Detergents and Raw Materials,” Lake Placid, New York, June 1971. 相似文献
14.
Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates 总被引:1,自引:0,他引:1
Milton J. Rosen Zhen Huo Zhu Xi Yuan Hua 《Journal of the American Oil Chemists' Society》1992,69(1):30-33
The properties of some well-characterized sodium linear decyldiphenylether (C10DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical
micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique,
foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to
a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities
of < 0.01 g/dm3 in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 ×
10−5 mol dm−3) in aqueous 0.1 N Na+ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger
area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher
surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ1s and γeq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS
> MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy
is most pronounced with the disulfonates. 相似文献
15.
Milton Jimenez-Francisco Jose Gonzalo Carrillo Luis Alfonso Garcia-Cerda 《应用聚合物科学杂志》2021,138(1):49628
Mechanochemical degradation by planetary ball milling (PM) is used for postpolymerization modification of styrene homopolymers (PS). A complete factorial design was chosen to study the effect of radical scavengers, milling time, initial molecular weight, and revolution radius (Rp), on the shape of molecular weight distributions (MWDs) of PS. Size-exclusion chromatography analysis shows the feasibility of fine-tuning MWD of PS at up to 40% conversion. Distributions ranged from unimodal to bimodal in a PM with Rp = 150 mm at different stage of milling, whereas in a PM with Rp of 60.8 mm the adjustment of unimodal distributions is achieved. Initial polydispersity is more important to develop bimodal distributions when compared with initial molecular weight. Fourier transform infrared and X-ray electron spectrometry analysis show some suppression of PS degradation and complete oxidation inhibition of macromolecular radicals with the incorporation of radical scavengers, which we considered as additional aids when adjusting the MWDs. 相似文献
16.
Azevedo Dde O Matiello-Guss CP Rönnau M Zanuncio JC Serrão JE 《Microscopy research and technique》2008,71(3):196-200
The sensilla are sensory organs formed by cuticular and cellular structures specialized in reception of chemical and physical stimuli from the environment and transmission to the insect's central nervous system. In function of the great concentration of sensilla, the antennae are the main organs for interaction between bees and with the environment. This work studied the presence of antennal sensilla in the different phases of pupal development of the stingless bee Melipona quadrifasciata anthidioides by means of scanning electron microscopy and light microscopy. The results showed that antennal sensilla begin their development in the transition of the prepupae to the white-eyed pupae and finish it in the pigmented-body pupae phase. The antennal sensilla were exposed to the environment in the black-eyed pupae when the old cuticle is completely digested, suggesting that only in the final pupal phases can these bees perceive the environmental stimuli. 相似文献
17.
The
4
He wetting transition on a Cs surface is for the first time studied by Path Integral Monte Carlo simulation. Numerical results for a system of 64
4
He atoms are qualitatively consistent with a wetting transition at a temperature T 2 K. 相似文献
18.
Milton García-Borroto Author Vitae José Fco. Martínez-Trinidad Author Vitae 《Pattern recognition》2010,43(9):3025-3034
In this paper, we introduce an efficient algorithm for mining discriminative regularities on databases with mixed and incomplete data. Unlike previous methods, our algorithm does not apply an a priori discretization on numerical features; it extracts regularities from a set of diverse decision trees, induced with a special procedure. Experimental results show that a classifier based on the regularities obtained by our algorithm attains higher classification accuracy, using fewer discriminative regularities than those obtained by previous pattern-based classifiers. Additionally, we show that our classifier is competitive with traditional and state-of-the-art classifiers. 相似文献
19.
20.
Feehrer John Rotker Paul Shih Milton Gingras Paul Yakutis Peter Phillips Stephen Heath John 《Micro, IEEE》2009,29(4):36-47
CoHub, a coherency hub ASIC, provides a cost-effective way to extend a glueless two-node chip-multithreading system to a four-node system without changes to the processor. The four-node, 256-thread system achieves near-linear scaling of performance with thread count on transaction-processing workloads. Time-to-market pressure, 800-MHz operation, and a six-stage pipeline were among the constraints that shaped CoHub's design. 相似文献