CuInSe2 Formation from CuSe/In2Se3 and Cu2Se/In2Se3 Powders: Reaction Kinetics and Mechanisms

CuInSe₂ (CIS) powders were synthesized using CuSe, Cu₂Se, and In₂Se₃ as the raw materials. The formation mechanisms and reaction kinetics from CuSe/In₂Se₃ and Cu₂Se/In₂Se₃ powders in a selenium atmosphere were investigated. It was observed that the formation temperature of α‐CIS powders synthesized using Cu₂Se/In₂Se₃ as the raw materials was higher than that using CuSe/In₂Se₃. Both reactions for Cu₂Se/In₂Se₃ and CuSe/In₂Se₃ mixtures follow one‐dimensional diffusion‐controlled reactions with apparent activation energies of 124.3 and 73.2 kJ/mol, respectively. For both mixtures the indium‐rich β‐CIS phase resulting from Cu⁺ ion diffusion toward the In₂Se₃ phase was observed. The particle size and morphology of the newly formed CIS was similar to In₂Se₃, which indicated that the CIS formation kinetics may be dominated by the diffusion of Cu⁺ ions. The Cu–Se liquid phase resulting from the peritectic decomposition of CuSe₂ and CuSe at a relatively low temperature may promote Cu⁺ diffusion into the In₂Se₃ surface, assisting CIS formation.     

Direct Bonding of Aluminum to Alumina for Thermal Dissipation Purposes

In this study, aluminum foil was bonded directly to alumina substrate at a temperature higher than 1000°C in an inert atmosphere. A platinum marker was used to locate the original interface after bonding. With the help of the Pt marker, the microstructure analysis revealed that the aluminum foil oxidized first, and the newly formed alumina was subsequently bonded to the alumina substrate. The bonding strength increased with increases in bonding temperature until 1100°C. The strong interface also led to high thermal conductivity.     

Price and capacity competition of application services duopoly

In this paper, we study the price and capacity competition of two application service providers (ASPs). The customers realize an intrinsic time-independent value from transactions processed by the ASP. The cost to the customers includes both the price charged by the ASP and the delay cost due to turnaround time of the ASP service system. Customers will choose to join the ASP who delivers a higher net value of the service. This paper examines the competition between two ASPs and the impact of customers' delay cost on ASP's pricing and capacity decisions. We find that the ASP with higher capacity will charge a higher price and enjoy a larger market share and, surprisingly, that customers' delay cost has no direct impact on the arrival rates to the ASPs but affects the ASPs' pricing decisions. The ASPs will charge a higher price premium to capitalize customers' higher delay cost. For the long-run problem, we find that in the presence of higher customer's delay cost, both ASPs' optimal profits suffer, in contrast to the short-run problem where a higher customer's delay cost leads to a higher profitability for both ASPs.     

Linguistic frequent pattern mining using a compressed structure

Traditional association-rule mining (ARM) considers only the frequency of items in a binary database, which provides insufficient knowledge for making efficient decisions and strategies. The mining of useful information from quantitative databases is not a trivial task compared to conventional algorithms in ARM. Fuzzy-set theory was invented to represent a more valuable form of knowledge for human reasoning, which can also be applied and utilized for quantitative databases. Many approaches have adopted fuzzy-set theory to transform the quantitative value into linguistic terms with its corresponding degree based on defined membership functions for the discovery of FFIs, also known as fuzzy frequent itemsets. Only linguistic terms with maximal scalar cardinality are considered in traditional fuzzy frequent itemset mining, but the uncertainty factor is not involved in past approaches. In this paper, an efficient fuzzy mining (EFM) algorithm is presented to quickly discover multiple FFIs from quantitative databases under type-2 fuzzy-set theory. A compressed fuzzy-list (CFL)-structure is developed to maintain complete information for rule generation. Two pruning techniques are developed for reducing the search space and speeding up the mining process. Several experiments are carried out to verify the efficiency and effectiveness of the designed approach in terms of runtime, the number of examined nodes, memory usage, and scalability under different minimum support thresholds and different linguistic terms used in the membership functions.

     

Reduction of charge injection into PECVD SiNxHy by control of deposition chemistry

The high rate of charge trapping in thin-film silicon nitride causes its electrical properties to change with stressing level and time. The rate of shift of the high-frequency CV curves of Al/SiN_xH_y/cSi capacitors was used here to measure nitride charging rate and to compare PECVD nitrides deposited under various conditions of plasma power and gas mixture in the same parallel-plate reactor. By operating the plasma under high power to activate the NH₃ or N₂ and under low SiH₄ flow to ensure that all of the SiH4 reacts with N, it is possible to deposit N-rich nitride that has no detectable Si—H bonding, which bonding others have correlated with charge trapping. Nitride deposited under these conditions using NH₃ and 13 MHz rf power had charging rates for both gate polarities that were 20 times lower than those of nitride that had a “stoichiometric” N/Si ratio of 4/3 and that had its H distributed among Si—H and N—H bonds. MIS capacitors made with the latter nitride also had a high negative initial flat-bond voltage, indicating the presence of grown-in positive charge. This charge was large enough to invert the surface ofp-Si substrates. N-rich nitride free of Si—H that was deposited either using N₂ or using low-frequency rf power (≤400 kHz) had higher charging rates than did that deposited from NH₃ at 13 MHz. Also, the low-frequency material contained grown-in positive charge that is attributed to H⁺ implanted by the high ion bombardment energy of the low-frequency plasma.     

Micromechanics-Based Predictions on the Overall Stress-Strain Relations of Cement-Matrix Composites

A micromechanics-based model is proposed to determine the nonlinear stress-strain relations of cement-matrix composites at different concentrations of inclusions (aggregates). We first conducted some experiments to uncover the stress-strain behavior of the cement paste with a water-to-cement ratio of 0.45, and those of the mortar with the same cement paste but at three different volume concentrations of aggregates. The behavior of the cement paste is then simulated by Burgers’ rheological model. In the development of the composite model, we extend the linear elastic response to the nonlinear one through the replacement of elastic moduli by the corresponding secant moduli. The nonlinear stress-strain curves of the cement-matrix composite are then determined from those of the cement paste and inclusions. It is shown that the predicted stress-strain curves of the mortar are in close agreement with the experimental curves up to an aggregate volume fraction of 49% or 60?wt?%.     

Study of the solvent effect on miscibility between poly(vinyl chloride) and poly(methyl methacrylate) in the solution state – viscometric measurements

In this work, the solvent effect on the miscibility between poly(vinyl chloride) (PVC) and poly(methyl methacrylate) (PMMA) in ternary polymer solutions was examined by the viscometric method. In these systems, we could understand that the used solvents, tetrahydrofuran (THF) or N,N‐dimethylformamide (DMF), mainly affect the interaction between PVC and PMMA, while prompting various miscible properties. In PVC/PMMA/THF solution, THF is a near θ‐solvent and a poor solvent for PVC and PMMA, respectively. The mixing of the tighter PMMA coils and more extended PVC coils in THF may cause the sea–island heterogeneous structure below the weight fraction of PMMA in the polymer mixture w_PMMA = 0.7, resulting in immiscible PVC/PMMA mixtures. At w_PMMA ≥ 0.7, the PVC/PMMA mixtures are relatively miscible, giving homogeneous polymer solutions. It means that the miscibility between PVC and PMMA depends on the composition of polymer mixture. However, due to the similar affinity of DMF to PVC and PMMA, PVC/PMMA/DMF solutions exhibit high miscibility between PVC and PMMA at about w_PMMA = 0.5. © 2000 Society of Chemical Industry     

CHARACTERIZATION AMD POTENTIAL UTILIZATION OF WHITEROCKS (DTAB) TAR SAND BITUMEN II. PYROLYSIS MASS SPECTROMETRY AND NUCLEAR MAGNETIC RESONANCE ANALYSES

The proton and carbon-13 nuclear magnetic resonance characteristics of the native Whiterocks bitumen were determined by comparing the spectra of the samples to literature assignments. The tentative structural assignments of pyrolysis products were also obtained from the spectra of Curie-point low voltage mass spectrometric analysis. The results obtained from proton and carbon-13 nuclear magnetic resonance and pyrolysis-mass spectrometry analysis suggested that the native bitumen consists mostly of short- and long-chain (i.e., normal and isoprenoid chains) alkylsubstituents attached to polycyclic naphthenic, naphtheno-aromatic and/or aromatic moieties.     

Effects of solvent adsorption on solution properties of poly(vinyl alcohol)/dimethylsulfoxide/water ternary systems

In this study, the solvent adsorption phenomena of poly(vinyl alcohol) (PVA) in cosolvent mixtures of dimethylsulfoxide (DMSO; solvent 1) and water (solvent 2) were investigated. Typically, this cosolvent mixture could form hydrogen‐bonded DMSO/(water)₂ complexes, involving one DMSO and two water molecules. Because of the complex formation in the cosolvent mixtures, PVA chains preferentially adsorb water molecules at DMSO mole fraction X₁ < 0.33, but preferentially adsorb DMSO molecules at X₁ > 0.33. The preferential adsorption of DMSO (a good solvent for PVA) could cause the relatively extended conformation of PVA chains in solutions because of the increase in excluded volume effect. Because of various interactions between PVA chains and cosolvent mixtures, the aggregation and gelation behaviors of PVA solutions were significantly affected by the composition of cosolvent mixture. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3211–3217, 2004