4-溴-1-溴甲基-2-对氯苯基-5-三氟甲基吡咯-3-腈的合成

以2 对氯苯基1 甲基5 三氟甲基2 吡咯啉3 腈为原料,经三步反应合成了4 溴1溴甲基2 对氯苯基5 三氟甲基吡咯3 腈,合成总收率为29.8%。     

Fabrication of polysulfone asymmetric hollow‐fiber membranes by coextrusion through a triple‐orifice spinneret

Polysulfone (PSf) asymmetric hollow‐fiber membranes, which have a dense outer layer but a loose inner layer, were tentatively fabricated by coextrusion through a triple‐orifice spinneret and a dry/wet‐phase inversion process. Two simple polymer dopes were tailored, respectively, for the dense outer layer and the porous inner layer according to the principles of the phase‐inversion process. By adjusting the ratio of the inner/outer extrusion rate, the hollow‐fiber membranes with various thicknesses of outer layers were achieved. The morphology of the hollow‐fiber membranes was exhibited and the processing conditions and the water permeability of the membrane were investigated. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 259–266, 2004     

Structure and properties of nitrile rubber (NBR)–clay nanocomposites by co‐coagulating NBR latex and clay aqueous suspension

Nitrile rubber (NBR)–clay nanocomposites were prepared by co‐coagulating the NBR latex and clay aqueous suspension. Transmission electron microscopy showed that the silicate layers of clay were dispersed in the NBR matrix at the nano level and had a planar orientation. X‐ray diffraction indicated that there were some nonexfoliated silicate layers in the NBR–clay nanocomposites. Stress–strain curves showed that the silicate layers generated evident reinforcement, modulus, and tensile strength of the NBR–clay nanocomposites, which were significantly improved with an increase in the amount of clay, and strain‐at‐break was higher than that of the gum NBR vulcanizate when the amount of clay was more than 5 phr. The NBR–clay nanocomposites exhibited an excellent gas barrier property; the reduction in gas permeability in the NBR–clay nanocomposites can be described by Nielsen's model. Compared with gum NBR vulcanizate, the oxygen index of the NBR–clay nanocomposites increased slightly. The feasibility of controlling rubber flammability via the nanocomposite approach needs to be evaluated further. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3855–3858, 2003     

Preparation of V doped lanthanum silicate electrolyte ceramics by combustion method and study on conductance mechanism

Vanadium doped La_9.33Si_6−xV_xO_26+0.5x (x = 0.5, 1.0, 1.5) (LSVO) electrolyte powder was prepared by combustion method at 600°C for 5-7 min. The powder was sintered at 1500°C for 3 hours to prepare LSVO ceramics. XPS, IR, XRD, and EIS analysis show that V⁵⁺ doping replaces Si⁴⁺ in [SiO₄] to form [Si(V)O₄] tetrahedron. With the increase in x, the lattice volume increase. When x = 2.0, the LaVO₄ phase was formed, indicating that the limit doping amount of V⁵⁺ replacing Si⁴⁺ is x ≤ 1.5. The conductivity of LSVO increases significantly with the increase in x (x ≤ 1.0), which attributed to the defect reaction caused by V⁵⁺ doping. The addition of the interstitial oxygen Oi* in 6₃ channels and the increase of lattice volume leads to increased conductivity. When x = 1.0, the highest conductivity is 1.46 × 10⁻² S·cm⁻¹ (800°C). The doping enhancement conductivity mechanism is the Interstitial oxygen defect-Lattice volume composite enhancement mechanism.     

基于测井资料和地震属性分析地震相分布

地震相是特定沉积相或地质体在地震剖面图上所反映的主要特征的总和,是沉积和地震之间联系的枢纽。利用不同相带的井在地震剖面上的标定结果和声波时差统计,在常规地震剖面和瞬时相位剖面初步得到相带划分图。根据地震反射层的外形结构、频率、振幅及连续性等特征,建立三种沉积相对应的地震相模式,分析沿目标地层顶界地震属性切片,筛选对相带边界表征清晰的属性,确定出地震相的分布区域,这对以后的储层预测和生物礁的发现提供技术支持。     

水平井产出剖面测井技术在塔河油田的应用

由于水平井中流体的流动相态和施工工艺的复杂性,造成常规的产出剖面测井技术难以适应于水平井,因此水平井产出剖面测井技术是一项技术含量高、研究难度大、生产迫切需求的工作。本文简单介绍了水平井产出剖面测井技术及爬行器施工工艺,应用该技术成功完成了塔河油田TK109H等三口水平井产出剖面测井,并总结了施工经验与存在的问题,为进一步应用该技术评价生产层段产出状况提供帮助。     

"花牛苹果"农产品地理标志保护问题调研

针对地理标志农产品保护中存在的问题开展调研,从完善立法,协调地方政府部门职责利益,解决农产品地理标志管理体制中存在的问题,使地方名优特色农产品真正成长为品牌产品,在农业产业化、标准化、现代化过程中发挥真正的作用,带来和其品牌相适应的经济效益,服务地方经济,服务“三农”。     

厦门海沧保税港区建设思路探析

厦门海沧保税港区的建设,对于厦门港口经济的发展具有巨大的推动作用,而且可进一步加强两岸的经济交流与互动。介绍了我国保税港区的政策功能及厦门海沧保税港区的建设规划,分析了海沧保税港区发展具有的优势、面临的机遇和需要面对的挑战,提出了海沧保税港区的建设措施。     

我国电子信息产业发展环境分析

受全球金融危机的影响,电子信息产业作为知识密集、产业关联度高的产业受到冲击最大,如何从金融危机中走出困境.提升电子信息产业的综合竞争力,各国政府实施了各自的应对措施.电子信息产业作为我国国民经济的支柱产业,其发展方向应从电子信息产业大国向电子信息产业强国转变,在政府政策的引导下,通过优化产业结构,培育高技术人才、技术创新来提升我国电子信息产业的竞争力.     

祭厉信仰习俗的传承与发展空间

非正常死亡或无子嗣不能享受后人祭祀的鬼魂称之为"厉".在中国古代国家祭祀中,"厉"被列为祭祀对象,历朝沿袭.在民间祭祀中,祭厉信仰习俗一直绵延不绝,现代社会仍在传承与发展.拓展祭"厉"信仰习俗发展空间,既体现了普世人文关怀,又能在一定程度上促进社会和谐.