2D Model-Following Servo System

This paper gives, in view of the feature of practical 2D (2-dimensional) systems, a formulation of the 2D model-following servo problem for the case where one of the independent variables of the considered 2D systems is unbounded and the other one is bounded. That is, to determine a control input such that the outputs of a given 2D plant asymptotically track, with tracking error as small as possible, the (step) response of a given 2D model system as the unbounded variable approaches infinite. It is shown that this problem under a specified quadratic performance index can be transformed into a 1D LQR problem, and thus can be solved by the well-known 1D approaches. The relation between the solvability condition obtained for the equivalent 1D LQR problem and the practical stabilizability and detectability of the original 2D plant is clarified. Its application to the design of non-unit memory linear multipass processes is also shown. Finally, a numerical example for metal rolling process is given to verify the effectiveness.     

Antioxidant activity of Japanese pepper (Zanthoxylum piperitum DC.) fruit

Antioxidants were extracted from Japanese pepper (Zanthoxylum piperitum DC.) fruit and characterized. The antioxidant activity of the methanol extract from Japanese pepper fruit was found to be equal to that of α-tocopherol and stable under heat treatment. The main compounds that gave a significant antioxidant activity from the methanol extract were identified to be hyperoside (quercetin-3-O-galactoside) and quercitrin (quercetin-3-O-rhamnoside) as determined by HPLC, mass spectrometry, UV/Vis spectroscopy, and TLC. Radical-scavenging activities of hyperoside and quercitrin from Japanese pepper fruit were evaluated using the 1,1-diphenyl-2-picrylhydrazyl (DPPH) method. As a result, hyperoside and quercitrin scavenged DPPH radical strongly with IC₅₀ values of 16 and 18 μM, respectively. These observations show the presence of strong antioxidants, namely hyperoside and quercitrin in Japanese pepper fruit.     

Design study of PbBi- and NaK-cooled small deep sea fast reactors

The liquid lead-bismuth eutectic (PbBi) has good compatibility with water, which is different from sodium. It is expected that the PbBi could be used as a coolant of the deep sea fast reactor (DSFR). Physics analysis of the PbBi-cooled small reactor cores with and without inner control rods performed using the computer program of a neutronics code system (SRAC95) shows that PbBi is suitable for the coolant of small reactors as well as NaK.     

Method to Estimate Thermal Shrinkage Behavior of Glasses

We present a method to estimate the effect of heat treatment on the shrinkage behavior of glasses. As a pre-requisite, sensitivity of the glass density as a function of glass fictive temperature is measured using the sink–float method and the slope of the relationship is used to determine the linear thermal strain proportionality factor. Evolution of the fictive temperature for different temperature–time history is measured using the infrared spectroscopy method and the results are used to estimate the structural relaxation parameters in the temperature range of interest. The overall shrinkage behavior is predicted using the linear thermal strain factor and estimated change in fictive temperature due to the thermal treatment. The predicted shrinkage behavior is observed to be in good agreement with the independent dimensional change measurements performed on large glass sheets that have undergone similar thermal treatments.     

Electropolymerization kinetic study of 3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine and its optical optimization for electrochromic window applications

Poly (3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine), PProDOT-Me₂, is one of the most promising conducting polymers in the alkylenedioxythiophene based family for electrochromic window applications. In the electropolymerization kinetic study of 3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine (ProDOT-Me₂), microgravimetry and chronoamperometry were used to determine the reaction orders with respect to the electrolyte and monomer, and the corresponding general kinetic equation of electropolymerization. This study presents that monomer concentration has a strong impact on electropolymerization mechanism. The relationship between film thickness and polymerization time was analyzed indicating that saturation of polymerization reduced the increase rate of film thickness with polymerization time. Also, the electropolymerization conditions were optimized to reach high contrast (Δ%T > 70%) with the minimum of transmittance (%T_min < 1) for electrochromic window applications.     

Theoretical considerations on the sensitivities of electron beam resists

A theoretical study has been carried out in order to explain the sensitivities of electron beam and X-ray resists. A preliminary investigation reveals that the behavior of these resists, on irradiation by high energy radiation, may be considered to be the electronically-excited species in the polymer. To elucidate the chemical reactions in the excited states the adiabatic potential curves are calculated by the INDO/S procedure, which considers all the valence electrons and all the singly excited electronic configurations. Polyethylene and polyisobutylene were chosen as representative of crosslinkable and degradable polymers, respectively, since there is a parallelism between the beam sensitivity of resists and the effects of high energy radiation on polymers. Polyisobutylene has many antibonding curves favorable for the main chain scission in the excited states and polyethylene does not except for one improbable state. It was concluded that degradability is explainable by the ease of bond fission in the excited states; the crosslinkability is considered to be nondegradable property.     

A large discrepancy between CPM and ESR defect densities in light-soaked a-Si:H

A large discrepancy between defect densities evaluated by constant photocurrent method (CPM) and electron spin resonance (ESR) is investigated for hydrogenated amorphous silicon (a-Si:H) with various thicknesses in the process of light soaking (LS). It is shown by a computer simulation that the inhomogeneous defect distribution across the film thickness caused by a rather small penetration depth of the white light in the thick film is one of the possible origins of the discrepancy. But various other causes should also bring about the discrepancy, and the problem is still a puzzling one.