Highly Stable Colloidal “Giant” Quantum Dots Sensitized Solar Cells

Colloidal quantum dots (QDs) are widely studied due to their promising optoelectronic properties. This study explores the application of specially designed and synthesized “giant” core/shell CdSe/(CdS)_x QDs with variable CdS shell thickness, while keeping the core size at 1.65 nm, as a highly efficient and stable light harvester for QD sensitized solar cells (QDSCs). The comparative study demonstrates that the photovoltaic performance of QDSCs can be significantly enhanced by optimizing the CdS shell thickness. The highest photoconversion efficiency (PCE) of 3.01% is obtained at optimum CdS shell thickness ≈1.96 nm. To further improve the PCE and fully highlight the effect of core/shell QDs interface engineering, a CdSe_x S_1?x interfacial alloyed layer is introduced between CdSe core and CdS shell. The resulting alloyed CdSe/(CdSe_x S_1?x )₅/(CdS)₁ core/shell QD‐based QDSCs yield a maximum PCE of 6.86%, thanks to favorable stepwise electronic band alignment and improved electron transfer rate with the incorporation of CdSe_x S_1?x interfacial layer with respect to CdSe/(CdS)₆ core/shell. In addition, QDSCs based on “giant” core/CdS‐shell or alloyed core/shell QDs exhibit excellent long‐term stability with respect to bare CdSe‐based QDSCs. The giant core/shell QDs interface engineering methodology offers a new path to improve PCE and the long‐term stability of liquid junction QDSCs.     

Inter‐annual variability,risk and confidence intervals associated with propagation statistics. Part II: parameterization and applications

This set of two companion papers aims at providing a model for the inter‐annual variability of earth‐space propagation statistics and for the inherent risk and CIs. In part I, it was proposed to model the yearly variance σ² of empirical complementary CDFs so that where is the variance of estimation, the inter‐annual climatic variance and p the long‐term probability. Particularly, an analytical formulation of was derived and parameterized from synthetic rain attenuation data. Considering the statistical framework developed in part I, this part II is specifically devoted to the parameterization of the variance of estimation from experimental data of rain attenuation and rainfall rate. Then, a methodology to model and parameterize worldwide the inter‐annual climatic variance is presented. The model of yearly variance of the empirical complementary CDFs is finally compared against yearly experimental variances derived from data collected worldwide. The knowledge of this variability is very useful for system design as it allows the risk on a required availability and associated with a given propagation margin to be quantified. Copyright © 2013 John Wiley & Sons, Ltd.     

System integration of high voltage electrostatic MEMS actuators

A system integration for High Voltage (HV) electrostatic MicroElectroMechanical Systems (MEMS) actuators is introduced on a micro-Printed Circuit Board. The system includes a programmable microcontroller, a programmable DC/DC converter, a multi output HV interface and electrostatic MEMS actuators. The system produces high output voltages (10–300 V) and can control a large variety of MEMS capacitive loads (1 to 50 pF) by combining diverse semiconductor technologies. This system proves that technologies, such as low voltage CMOS of different processes, high voltage DMOS and MEMS, can interact, communicate and even be integrated as a System In Package (SIP), providing significant size and cost reductions. The system was programmed to control electrostatic MEMS actuator. The DC/DC converter was made from components of different technologies and two addressable high voltage CMOS interfaces were fabricated with DALSA's 0.8 μm High Voltage process. A prototype of the global system has been built and tested.     

Public key cryptography based privacy preserving multi-context RFID infrastructure

In this paper, we propose a novel radio frequency identification (RFID) infrastructure enabling multi-purpose RFID tags realized by the use of privacy preserving public key cryptography (PKC) architecture. The infrastructure ensures that the access rights of the tags are preserved based on the spatial and temporal information collected from the RFID readers. We demonstrate that the proposed scheme is secure with respect to cryptanalytic, impersonation, tracking, replay, and relay attacks. We also analyze the feasibility of PKC implementation on passive class 2 RFID tags, and show that the requirements for PKC are comparable to those of other cryptographic implementations based on symmetric ciphers. Our numerical results indicate PKC based systems can outperform symmetric cipher based systems, since the back end servers can identify RFID tags with PKC based systems approximately 57 times faster than the best symmetric cipher based systems.     

Silicon‐Modified Rare‐Earth Transitions—A New Route to Near‐ and Mid‐IR Photonics

Silicon underpins microelectronics but lacks the photonic capability needed for next‐generation systems and currently relies on a highly undesirable hybridization of separate discrete devices using direct band gap semiconductors. Rare‐earth (RE) implantation is a promising approach to bestow photonic capability to silicon but is limited to internal RE transition wavelengths. Reported here is the first observation of direct optical transitions from the silicon band edge to internal f‐levels of implanted REs (Ce, Eu, and Yb); this overturns previously held assumptions about the alignment of RE levels to the silicon band gap. The photoluminescence lines are massively redshifted to several technologically useful wavelengths and modeling of their splitting indicates that they must originate from the REs. Eu‐implanted silicon devices display a greatly enhanced electroluminescence efficiency of 8%. Also observed is the first crystal field splitting in Ce luminescence. Mid‐IR silicon photodetectors with specific detectivities comparable to existing state‐of‐the‐art mid‐IR detectors are demonstrated.     

An Effective Approach for High‐Efficiency Photoelectrochemical Solar Cells by Using Bifunctional DNA Molecules Modified Photoanode

This paper firstly reports the effect of deoxyribonucleic acid (DNA) molecules extracted from chickpea and wheat plants on the injection/recombination of photogenerated electrons and sensitizing ability of dye‐sensitized solar cells (DSSCs). These high‐yield DNA molecules are applied as both linker bridging unit as well as thin tunneling barrier (TTB) at titanium dioxide (TiO₂ )/dye interface, to build up high‐efficient DSSCs. With its favorable energy levels, effective linker bridging role, and double helix structure, bifunctional DNA modifier shows an efficient electron injection, suppressed charge recombination, longer electron lifetime, and higher light harvesting efficiency, which leads to higher photovoltaic performance. In particular, a photoconversion efficiency (PCE) of 9.23% is achieved by the binary chickpea and wheat DNA‐modified TiO₂ (CW@TiO₂) photoanode. Furthermore, time‐resolved fluorescence spectroscopy measurements confirm a better electron transfer kinetics for DNA‐modified TiO₂ photoanodes, implying a higher electron transfer rate (k_ET). This work highlights a great contribution for the photoanodes that are linked with DNA molecule, which act as both bridging unit and TTB to control the charge recombination and injection dynamics, and hence, boost the photovoltaic performance in the DSSCs.     

An algorithm for formant tracking

A formant tracking algorithm than first forms strings of spectral peaks considering only the relative positions of the peaks and then assigns these strings to the formants according to the relative positions and lengths of the strings is presented. An example is also given.     

Speech synthesis using AM/FM sinusoids and band-pass noise

In the speech synthesis model presented in this paper, voiced speech is synthesized as the sum of sinusoidally modulated two FM sinusoids corresponding to the first and second formants. Each FM signal is generated such that its amplitude is equal to the formant amplitude, its carrier frequency to the formant frequency or its linear combination, its modulation frequency to the pitch, and its modulation index to one fifth of the carrier to modulation frequency ratio. Unvoiced speech is generated by shifting the center frequency of a low-pass noise with a bandwidth of 1 KHz, to the frequency where the energy of the unvoiced speech is concentrated. The drawbacks of this scheme are that the pitch and the formant frequencies of the FM signals may deviate up to 40% and 9%, respectively, and spurious formants may occur. A hardware implementation can be accomplished by driving a linear analog circuitry which can simply be integrated on a single chip, by a digital computer which supplies voltages at every T = 5 ms corresponding to seven parameter values. Examples of the signals and spectrograms of synthesized speech obtained by both synthesis by analysis and synthesis by rule are given along with a set of rules for text-to-speech synthesis of Turkish. It is observed that the speech synthesized by analysis loses the speaker's identity but it is highly intelligible, while understanding the speech synthesized by rules requires a training period.     

Incidence of different pork quality categories in a Portuguese slaughterhouse: A survey

This study was designed to evaluate the incidence of the PSE/DFD status in a Portuguese pig slaughterhouse, covering two seasons of the year (spring and summer) in order to find out if the proportions of those poor meat quality categories were sufficient to concern the meat industry. Meat quality classification was based on the measurements of the pH(60), pH(24), drip losses and colour (L, a, b) in the longissimus dorsi muscle (between the last third and fourth ribs) of 380 pigs randomly chosen from the line. The high global incidence of PSE and likely PSE (30%) as well as DFD (10%) carcasses and the enormous variation of the meat quality between the different days of analysis proves that the pig population presents a great variation of halothane genotype and that handling procedures have to be optimized in order to decrease stress and glycogen store depletion. The percentage of PSE carcasses during the summer season was double that found in the spring, probably due to a higher environmental temperature and relative humidity.     

Effects of pretreatment and various operating parameters on permeate flux and quality during ultrafiltration of apple juice

The central composite design with a quadratic model was used to investigate the effect of temperature (20–40 °C) and transmembrane pressure (TMP) (100–300 kPa) as well as pretreatment with gelatin and bentonite (0:0–300:1500 mg L^?1) on permeate flux and fouling resistance during ultrafiltration of apple juice. The changes in some physicochemical properties were also investigated. Pretreatment of apple juice with gelatin and bentonite and an increase in the temperature and TMP significantly improved the permeate flux. In general, physicochemical properties of apple juice other than polyphenolics were not affected by the applied parameters. Using 150 mg L^?1 of gelatin and 750 mg L^?1 of bentonite for fining significantly reduced the total phenolic content and so did the fouling resistance. Fouling resistance also decreased with increasing temperature, and increasing pressure increased the fouling resistance.