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排序方式: 共有780条查询结果,搜索用时 46 毫秒
41.
Kamil Musilek Dr. Ondrej Holas Jan Misik Miroslav Pohanka Dr. Ladislav Novotny Vlastimil Dohnal Dr. Veronika Opletalova Kamil Kuca Dr. 《ChemMedChem》2010,5(2):247-254
Acetylcholinesterase (AChE) reactivators are crucial antidotes to organophosphate intoxication. A new series of 26 monooxime‐monocarbamoyl xylene‐linked bispyridinium compounds was prepared and tested in vitro, along with known reactivators (pralidoxime, HI‐6, obidoxime, trimedoxime, methoxime, K107, K108 and K203), on a model of tabun‐ and paraoxon‐, methylparaoxon‐ and DFP‐inhibited human erythrocyte AChE. Although their ability to reactivate tabun‐inhibited AChE did not exceed that of the previously known compounds, some newly prepared compounds showed promising reactivation of pesticide‐inhibited AChE. The acute toxicity of the novel compounds was also determined. Docking studies using tabun‐inhibited AChE were performed for three compounds of interest. The structure–activity relationship (SAR) study confirmed the apparent influence of the xylene linkage and carbamoyl moiety on the reactivation ability and toxicity of the agents. 相似文献
42.
For the first time new type of liquid single crystal elastomers forming the chiral smectic A* (SmA*) phase has been prepared using chiral lactic acid derivative as a co-monomer. The synthesis and the basic characterization of the ferroelectric liquid crystalline co-monomer based on differential scanning calorimetry and small/wide-angle X-ray scattering are reported and discussed. The monomer possesses the paraelectric SmA* and the ferroelectric SmC* phases over a broad temperature range. The preparation of new smectic liquid crystalline elastomers together with characterization of their mesomorphic and structural properties is also reported. New elastomers possess the orthogonal paraelectric SmA* phase over 50 K broad temperature range. 相似文献
43.
The paper presents several sorting methods of γ-ray events which were implemented in the data acquisition, processing and visualization system, developed at the Institute of Physics of the Slovak Academy of Sciences. The sorting methods using various shapes of gates (conditions) are presented, including rectangular windows, polygons, gates defined by arithmetic functions, spherical, ellipsoidal and composed gates. The examples illustrating the use of these methods are presented as well. 相似文献
44.
The paper presents a simple but efficient new numerical scheme for the integration of nonlinear constitutive equations. Although it can be used for the integration of a system of algebraic and differential equations in general, the scheme is primarily developed for use with the direct solution methods for solving boundary value problems, e.g. explicit dynamic analysis in ABAQUS/Explicit. In the developed explicit scheme, where no iteration is required, the implementation simplicity of the forward-Euler scheme and the accuracy of the backward-Euler scheme are successfully combined. The properties of the proposed NICE scheme, which was also implemented into ABAQUS/Explicit via User Material Subroutine (VUMAT) interface platform, are compared with the properties of the classical forward-Euler scheme and backward-Euler scheme. For this purpose two highly nonlinear examples, with the von Mises and GTN material model considered, have been studied. The accuracy of the new scheme is demonstrated to be at least of the same level as experienced by the backward-Euler scheme, if we compare them on the condition of the same CPU time consumption. Besides, the simplicity of the NICE scheme, which is due to implementation similarity with the classical forward-Euler scheme, is its great Advantage. 相似文献
45.
The electrokinetic chromatographic separation of a series of inorganic and organic anions was achieved by utilizing an electrolyte system comprising a cationic soluble polymer (poly(diallydimethylammonium chloride, PDDAC) and a neutral beta-cyclodextrin (beta-CD) as pseudostationary phases. The separation mechanism was a combination of electrophoresis, ion-exchange (IE) interactions with PDDAC, and hydrophobic interactions with beta-CD. The extent of each chromatographic interaction was independently variable, allowing for control of the separation selectivity of the system. IE interactions could be varied by changing either the PDDAC concentration or the concentration of a competing ion (e.g., chloride) in the BGE, while the hydrophobic interactions could be varied by changing the concentration of beta-CD. The separation system was very robust, with the reproducibility of the migration times being <0.7% RSD. A mathematical model that predicted the mobilities of analytes under varying experimental conditions was derived and was shown to give good correlation (r2 = 0.9804) between predicted and experimental migration times. Parameters derived from the model were in good agreement with the ion-exchange and hydrophobic characteristics of the analytes. The model was also applied successfully to the optimization of conditions for the separation of a mixture of analytes or for conditions under which particular analytes migrated in a desired order. That is, the opportunity to tune the separation selectivity has been demonstrated. 相似文献
46.
Perturbed quantization steganography 总被引:3,自引:0,他引:3
In this paper, we use the recently proposed wet paper codes and introduce a new approach to passive-warden steganography called
perturbed quantization. In perturbed quantization, the sender hides data while processing the cover object with an information-reducing
operation that involves quantization, such as lossy compression, downsampling, or A/D conversion. The unquantized values of
the processed cover object are considered as side information to confine the embedding changes to those unquantized elements
whose values are close to the middle of quantization intervals. This choice of the selection channel calls for wet paper codes
as they enable communication with non-shared selection channel. Heuristic is presented that indicates that the proposed method
provides better steganographic security than current JPEG steganographic methods. This claim is further supported by blind
steganalysis of a specific case of perturbed quantization for recompressed JPEG images. 相似文献
47.
48.
The article introduces, as a result of further development of the first-order scheme NICE, a simple and efficient higher-order explicit numerical scheme for the integration of a system of ordinary differential equations which is constrained by an algebraic condition (DAE). The scheme is based on the truncated Taylor expansion of the constraint equation with order h of the scheme being determined by the highest exponent in the truncated Taylor series. The integration scheme thus conceived will be named NICE h , considering both principal premises of its construction. In conjunction with a direct solution technique used to solve the boundary value problem, the NICE h scheme is very convenient for integrating constitutive models in plasticity. The plasticity models are defined mostly by a system of algebraic and differential equations in which the yield criterion represents the constraint condition. To study the properties of the new integration scheme, which, like the forward-Euler scheme, is characterised by its implementation simplicity due to the explicitness of its formulations, a damage constitutive model (Gurson–Tvergaard–Needleman model) is considered. The general opinion that the implicit backward-Euler scheme is much more accurate than the thus-far known explicit schemes is challenged by the introduction of the NICE h scheme. The accuracy of the higher-order explicit scheme in the studied cases is significantly higher than the accuracy of the classical backward-Euler scheme, if we compare them under the condition of a similar CPU time consumption. 相似文献
49.
Miljan Vucetic Miroslav Hudec Mirko Vujošević 《Expert systems with applications》2013,40(7):2738-2745
In this paper, we present a new method for computing fuzzy functional dependencies between attributes in fuzzy relational database systems. The method is based on the use of fuzzy implications. A literature analysis has shown that there is no algorithm that would enable the identification of attribute relationships in fuzzy relational schemas. This fact was the motive for development a new methodology in the analysis of fuzzy functional dependencies over a given set of attributes. Solving this, not so new problem, is not only research challenge having theoretical importance, but it also has practical significance. Possible applications of the proposed methodology include GIS, data mining, information retrieval, reducing data redundancy in fuzzy relations through implementation of logical database model, estimation of missing values etc. 相似文献
50.
We provide a solution to the heretofore open problem of stabilization of systems with arbitrarily long delays at the input and output of a nonlinear system using output feedback only. The solution is global, employs the predictor approach over the period that combines the input and output delays, addresses nonlinear systems with sampled measurements and with control applied using a zero-order hold, and requires that the sampling/holding periods be sufficiently short, though not necessarily constant. Our approach considers a class of globally Lipschitz strict-feedback systems with disturbances and employs an appropriately constructed successive approximation of the predictor map, a high-gain sampled-data observer, and a linear stabilizing feedback for the delay-free system. The obtained results guarantee robustness to perturbations of the sampling schedule and different sampling and holding periods are considered. The approach is specialized to linear systems, where the predictor is available explicitly. 相似文献