Environmental factors in woodfuel production: Opportunities,risks, and criteria and indicators for sustainable practices

Bioenergy from sustainably managed forest ecosystems could provide a renewable, carbon-neutral source of energy in many nations and communities throughout the world. In order for forest bioenergy to be an ecologically sustainable fuel source, woodfuel procurement systems must not adversely impact forest ecosystems or the environment. Sustainable forest management (SFM) certification schemes are one mechanism for applying standards and monitoring regimes to forest management systems to ensure ecological sustainability. This paper provides a global review of the main environmental risks to forest ecosystems that can arise from household- to industrial-scale woodfuel production systems, including forest soil quality and site productivity, water resources, biodiversity and carbon budgets. A set of regionally adaptable principles, criteria, indicators and verifiers of sustainable forest management were developed, based on criteria and indicators from existing internationally recognized certification frameworks and scientific literature and tailored to address issues relevant to producing and harvesting forest bioenergy feedstocks. A variable monitoring approach and a three-tiered certification approach are proposed as two methods for enabling the adoption of certification and associated monitoring requirements across a wide range of forest operations in regions with widely differing levels of development. The importance of the Adaptive Forest Management framework inherent in certification systems to ensuring the efficacy and continual improvement in woodfuel sustainability is stressed. The proposed principles, criteria, indicators and verifiers can be adapted to local conditions and incorporated into existing sustainable forest management and green energy certification schemes, as well as other criteria and indicator frameworks, to ensure the environmental sustainability of woodfuel production systems.     

Composites from PMMA modified thermosets and chemically treated woodflour

The mechanical behavior of composites made from woodflour and a modified thermoset unsaturated polyester resin has been examined. Polymethylmethacrylate (PMMA), a common low profile additive (LPA), was used as the matrix modifier. Woodflour, the reinforcing filler, was used ‘as received’ and was also modified with a commercial alkenyl succinic anhydride (ASA), in order to enhance the compatibility with the resin. The composites exhibited higher flexural and compressive modulus and compressive yield stress than the neat resin, while flexural strength and ultimate strain were reduced. The addition of PMMA to the unfilled thermoset led to a LPA morphology and decreased the flexural modulus, but produced an increment in flexural strain at break, impact energy and toughness of the UP resin. No enhancement in the mechanical behavior of the composites was found when treated woodflour instead of unmodified woodflour was used.     

Size effect on the structure of nanocrystalline and cluster films of hafnium diboride

Hafnium diboride films have been obtained by the method of nonreactive hf magnetron sputtering in an argon atmosphere. It has been shown that the determining role in the processes of the formation of the structure of these films belongs to the size effect. The coatings with a highly pronounced texture were characterized by a clearly pronounced anisotropy of the sizes of coherent domains (the axial ratio of the crystal lattice c/a≈ 1.1, which is close to the tabulated value) and by high residual compressive macrostresses ∼8 GPa. As the degree of texture decreased, there formed structures with axial ratios c/a ≈ 1.05–1.07; simultaneously, there occurred a decrease in the sizes of coherent domains and a reduction of residual macrostresses. Upon the formation of amorphous cluster films with a grain size of ∼5 nm, close-packed structures with a structure close to cubic were formed.     

In hemodialysis, adiponectin, and pro-brain natriuretic peptide levels may be subjected to variations in body mass index

Adiponectin exerts cardiovascular protective actions, although some studies have shown the opposite. In hemodialysis, obese subjects display lower mortality rates despite hypoadiponectinemia, while higher adiponectin concentrations correlate with an elevated cardiovascular risk in nonobese subjects. The aim of the study is to suggest that adiponectin level variations are associated with differences in the body mass index (BMI). The interplay between adiponectin and pro-brain natriuretic peptide (Pro-BNP) levels may vary according to body fat mass. Fifty-two chronic hemodialysis patients were divided into three groups. Group A, BMI<25 (n=20); Group B, BMI 25 to 30 (n=21), and Group C, BMI>30 (n=11). Diabetics: Group A 10%; Group B 6 29%; Group C 55%, P=0.027. Determinations: Adiponectin, Pro-BNP, insulin, insulin resistance (HOMA), troponin T, nutritional status, ultrafiltration rates, C-reactive protein (CRP), vascular accesses, and echocardiography. Group A: adiponectinemia positively and significantly correlated with Pro-BNP, CRP, and troponin T. As BMI increased, adiponectin, Pro-BNP, and malnutrition significantly decreased, while insulin, HOMA, and ultrafiltration rates significantly increased. Cardiac restriction was significantly higher in obese patients. In all groups, Pro-BNP and troponin T displayed a strong positive correlation. In low-BMI subjects, high Pro-BNP and adiponectin, low myocardial restriction, and worse nutritional status were prevalent. In obesity, hypoadiponectinemia stimulates cardiac remodeling, cardiac hypertrophy, and decreased stretching, rendering Pro-BNP levels low despite high ultrafiltration rates. Thus, adiponectin correlates inversely with BMI, probably playing different cardiovascular roles as BMI changes.     

Chitosan interaction with iron from yoghurt using an in vitro digestive model: comparative study with plant dietary fibers

The objective of this work was to investigate the interaction of chitosan with iron from yoghurt by an in vitro gastrointestinal tract model. Taking into account that chitosan is a polysaccharide included in fiber definition by Codex Alimentarius; chitosan behavior was studied and compared with different plant fiber (wheat, bamboo, apple, psyllium and inulin) behaviors, in the same in vitro conditions. Ferrous sulfate was added to yoghurts with each type of fiber. The gastric environment was simulated with HCl (pH 1.0-2.0). The duodenal environment was simulated with NaHCO(3) (pH 6.8-7.2) and a dialysis tubing cellulose membrane. Results showed that chitosan had the highest iron retention percentages (53.2% at 30 min; 56.8% at 60 min) interacting in a more pronounced manner with iron than the plant fibers used in this work.     

Criteria and indicators for sustainable forest fuel production and harvesting: A review of current standards for sustainable forest management

Forest biomass is increasingly being considered as a source of sustainable energy. It is crucial, however, that this biomass be grown and harvested in a sustainable manner.International processes and certification systems have been developed to ensure sustainable forest management (SFM) in general, but it is important to consider if they adequately address specific impacts of intensified production and harvesting methods related to forest fuels. To explore how existing SFM frameworks address sustainable forest fuel production, criteria and indicators (C&I) from 10 different international processes and organizations and 157 international, national and sub-national forest management certification standards under the Forest Stewardship Council (FSC) and the Programme for the Endorsement of Forest Certification (PEFC) were reviewed. International processes include indicators that require identification or reporting of availability, harvested amounts, value, or share in energy consumption of forest fuels. Forest certification standards address several specific woodfuel issues, but not always in a consistent manner. It seems that developed countries more frequently address environmental consequences of harvesting residues or whole trees on soil fertility and biodiversity, while developing countries more frequently address social issues, such as local people’s access to firewood and working conditions in charcoal production. Based on findings, options to improve SFM standards for sustainable forest fuel production are discussed. These options include clarification of terminology, systematic inclusion of important management impacts unique to forest fuel production, coordination of efforts with other related governance processes, including tools promoting sustainability at more integrated levels, such as landscape, supply chain and global levels.     

Effect of bias voltage on the structure of thin tantalum boride films

The effect of applied voltage on the structure and composition of tantalum diboride films deposited by rf magnetron sputtering on steel substrates has been studied using x-ray diffraction and secondary ion mass spectrometry. It is established that, by varying the bias voltage, it is possible to obtain nanocrystalline textured and untextured deposits with various phase compositions.     

The Minimum Number of Errors in the N-Parity and its Solution with an Incremental Neural Network

The N-dimensional parity problem is frequently a difficult classification task for Neural Networks. We found an expression for the minimum number of errors f as function of N for this problem, performed by a perceptron. We verified this quantity experimentally for N=1,...,15 using an optimal train perceptron. With a constructive approach we solved the full N-dimensional parity problem using a minimal feedforward neural network with a single hidden layer of h=N units.     

Short-wavelength near-infrared spectra of sucrose, glucose, and fructose with respect to sugar concentration and temperature

Short-wavelength near-infrared (SW-NIR) (700-1100 nm) spectra of aqueous solutions of sucrose, D-glucose, and D-fructose were monitored with respect to change in temperature and sugar concentration. Sugar OH and CH related vibrations were identified by analysis of the spectra of sugar solutions in deuterium oxide (D2O), and of sucrose-d8 solutions in D2O. Absorption spectra were explained in terms of the second and third overtones of OH stretching vibrations and the third overtone of CH2 and CH stretchings. In deuterated solutions, CH and CH2 higher overtone vibration bands became apparent. The major spectral effect of decreased temperature or increased sugar concentration was a decrease in absorbance at 960 nm and an increase in absorbance at 984 nm, interpreted as an increase in the degree of H bonding. Partial least-squares (PLS) calibrations on sugar concentrations (with spectra collected at several sample temperatures) relied strongly on the 910 nm sugar CH related bands, whereas calibrations on temperature depended equally on all OH associated vibrations (750, 840, 960, and 985 nm).     

Curing kinetics of divinyl ester resins with styrene

The curing reaction of a divinyl ester resin with different proportions of styrene—4, 20, and 40% by weight—was investigated by differential scanning calorimetry (DSC) using isothermal and dynamic modes. The different constraints on the reaction rate was globally considered, taken the reaction as divided in two regimens: below the vitrification regimen and during the vitrification regimen. Below the vitrification regimen, the autocatalytic model developed by Kamal was used to perform the analysis of the curing kinetics of divinyl ester resin with styrene. Experimental data from dynamic and isothermic runs, at a fixed composition, were simultaneously considered, while the actual temperature records (measured during the DSC runs) were also taken into account. The adjusted kinetic parameters took into account the gel effect on the radicals' termination rate and the structure constraints on the reactivity of pendant vinyls groups, present during this stage. During the vitrification stage, the diffusion control due to the low mobility of the reactive groups and molecules was incorporated into the overall rate constant according to the Rabinowitch model, which considers the two regimen contributions to the overall reaction rate kinetic. The Vogel–Fulcher relationship was adopted to express the temperature dependence of the rate constant during the vitrification stage. The method presented here has been satisfactorily applied to dynamic and isothermal curing reactions, allowing a simple and general kinetic expression useful in the design, optimization, and control of the processing of composites based on these thermoset polymers to be obtained. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1044–1053, 1999